成岩动力学分析与深部储层孔隙预测

国内外深部优质储层的不断发现大大拓宽了油气勘探的新领域,但孔隙流体自然排放的压实理论和有机无机反应的次生孔隙窗机理对深部高孔渗储层并不能作出圆满解释。深部储层孔隙保存状况除与储层物质组成及其内部结构有关外,与各成岩动力学过程间的耦合关系更为密切。压实作用、胶结作用、粘土矿物转化、有机质热演化、溶蚀作用、异常流体压力的积累与释放等动力学过程在时间和空间上的不同组合决定了深部储层孔隙的发育程度及其保存状况。     

中国南方东部震旦纪碎屑岩和泥质岩成岩作用

中国南方震旦纪碎屑岩的成岩作用主要有压实和压溶、胶结和固结、重结晶、交代作用及自生矿物形成等,泥质岩的成岩作用主要为压实作用和成岩过程中粘土矿物的转化。其成岩过程可分为同生、成岩、后生、表生四个成岩作用阶段。在沉积盆地演化的不同阶段和处在盆地的不同部位,出现了不同的岩石类型,往往呈现各自的成岩作用变化特点。     

Diagenesis and hydrocarbon emplacement in the Upper Triassic Yanchang Formation tight sandstones in the southern Ordos Basin,China

The Upper Triassic Yanchang Formation in the southern Ordos Basin is a tight sandstone but productive hydrocarbon exploration target. A variety of analyses, including thin-sections, cathodoluminescence (CL), scanning electron microscope (SEM), X-ray diffraction (XRD), fluorescence, isotope and fluid inclusion, have been used to analyse the reservoir petrology and diagenesis to understand the evolution of reservoir porosity. The sandstones are mostly feldspathic litharenites and lithic arkoses with low porosities (7.6% on average) and extremely low permeabilities (0.49 mD on average). A complex diagenetic alteration history of the reservoir caused different kinds of reduction in reservoir porosity. The carbonate cements are sourced from adjacent organic-rich mudstone and precipitated with a higher content near the edges of sandstone units and a lower content at the centres of sandstone units, resulting in two different diagenetic evolution paths. The analysis of porosity evolution history and hydrocarbon emplacement produced the following conclusions: (1) during the eodiagenesis period, mechanical compaction reduced the primary porosity dramatically from 40 to 19%; and (2) during the mesodiagenesis period, the first-phase oil charged the reservoir (porosity ranging from 14 to 19%) as bitumen along detrital grains forming a preferential pathway for subsequent oil emplacements. In the second-phase of oil charge, the reservoir porosity ranged from 9 to 14% limiting water–rock reactions. During the third-phase of oil charge, porosity of the reservoir remained at 9%. In general, the densification period (with a porosity close to 10%) of the reservoir occurs at the same time as the major oil emplacement and may be an explanation for the low oil saturation of the Chang 8 tight sandstone.     

山西临县紫金山碱性杂岩LA-ICP MS锆石U-Pb年龄、地球化学特征及其地质意义

本文对鄂尔多斯盆地东缘晋西挠褶带临县紫金山杂岩体进行了锆石LA-ICPMSU-Pb年代学及地球化学研究。锆石LA-ICPMSU-Pb测得紫金山碱性杂岩的结晶年龄为138.3±1.1Ma（MSWD=2.3,9个样品点）;地球化学研究表明该套火成岩富碱（K2O＋Na2O=8.60%～15.62%）,强烈富集大离子亲石元素和LREE、具有Eu正异常,亏损Nb、Ta、Ti等高场强元素,高Nb/Ta比值（16.85～18.19）,表明岩石起源于交代富集地幔的部分熔融。结合区域地质背景,文章提出紫金山碱性杂岩可能是早白垩世华北克拉通大规模伸展背景下由交代富集地幔部分熔融作用的产物,该期岩石圈深部的强烈岩浆—热活动是鄂尔多斯盆地燕山晚期构造热事件发生的主要原因。     

碳酸盐岩储层孔隙结构的影响因素与储层参数的定量评价

近几年,在海外区块遇到了大量的孔隙型碳酸盐岩储层。由于岩性复杂,孔隙类型多样,致使其孔隙结构十分复杂,储层参数难以准确计算,油气储量难以客观评价。文中针对研究靶区这一类型的碳酸盐岩储层,首先从沉积作用和成岩作用两个方面分析了孔隙结构的影响因素,得出在不同岩性之间,孔隙类型之间的差异是造成孔隙结构存在较大差异的主要原因。而在同种岩性之间,泥质含量的增加会降低孔隙结构的品质。另外,成岩作用对颗粒粒径较大的岩石的影响更大一些。其次,讨论了储层参数的定量评价,由于不同类型孔隙的共存,导致孔隙度相似,而渗透率、饱和度等储层参数却存在较大差异。针对这一问题,指出了可以采用核磁和成像等特殊测井资料来表征不同类型孔隙的数值分布,利用三维数字化成像技术来展示不同类型孔隙的空间分布,为储层参数的准确计算和油气储量的客观评价奠定基础。     

攀枝花地区基性-碱性岩系Th、Ta、Hf地球化学特征

攀枝花地区的基性—碱性岩系,是一套与钒钛磁铁矿、稀土矿、铍、钪、镓等多种矿产有关的含矿岩浆岩系。该岩系的Th、Ta、Hf地球化学特征极为相似,其Th/Hf比值在0.3～1.0之间,Ta/Hf比值更为接近,在0.2～0.5之间。在Th/Hf-Ta/Hf双对数图上,该岩系的源区特征和演化特征非常明显。此结果与峨嵋山地区的玄武岩和会东地区的基性岩系对比,Th、Ta、Hf特征都十分相近,因此该区原来被认为是两个地质时期(华力西期与印支期)的岩系,实际上是同一地质时期(华力西晚期)同源但不同阶段的产物,均是与峨嵋地幔柱关系密切的峨嵋玄武岩浆演化的结果。     

Diagenesis impact on a deeply buried sandstone reservoir (Es1 Member) of the Shahejie Formation,Nanpu Sag,Bohai Bay Basin,East China

Diagenesis has a significant impact on reservoir quality in deeply buried formations. Sandstone units of the Shahejie Formation (Es₁ Member) of Nanpu Sag, Bohai Bay Basin, East China is a typical deeply buried sandstone with large hydrocarbon accumulations. The methodology includes core observations and thin section studies, using fluorescence, scanning electron microscope (SEM), cathodoluminescence (CL), fluid inclusion and isotope and electron probing analysis as well as the numerical determination of reservoir characteristics. The sandstones consist of medium to coarse-grained, slight to moderate sorted lithic arkose and feldspathic litharenite. Porosity and permeability values range from 0.5 to 30% and 0.006 to 7000 mD, respectively. The diagenetic history reveals mixed episodes of diagenesis and deep burial followed by uplift. The main diagenetic events include compaction, cementation alteration, dissolution of unstable minerals and grain fracturing. Compaction resulted in densification and significantly reduced the primary porosity. Quartz, calcite and clay are the dominant pore-occluding cement and occur as euhedral to subhedral crystals. Alteration and dissolution of volcanic lithic fragments and pressure solution of feldspar grains were the key sources of quartz cement whereas carbonate cement is derived from an external source. Clay minerals resulted from the alteration of feldspar and volcanic lithic fragments. Porosity and permeability data predict a good inverse relationship with cementation whereas leaching of metastable grains, dissolution of cement and in some places formation of pore-lining chlorite enhanced the reservoir quality. The best reservoir is thicker sandstone bodies that are medium to coarse-grained, well-sorted sandstone with low primary ductile grains with a minor amount of calcite cement. The present study shows several diagenetic stages in the Es₁ Member, but the overall reservoir quality is preserved.     

陕川丁家林-太阳坪金矿带成矿机理

丁家林-太阳坪金矿带与丁家林-太阳坪脆-韧性剪切带同位分布、同能源作用、同步生成，是脆-韧性剪切变形形成的石英脉型金矿，总体走向NE，主要由丁家林和太阳坪2个金矿床组成，分石英单脉、单脉密集带、复脉带3个亚型。丁家林以含Au石英复脉为主，太阳坪以含Au石英单脉为主；成矿物质来源于富含Si质的志留系黄坪组，成矿流体主要是构造水；内生成矿作用分脆．韧性剪切变形-构造分异热液期和韧-脆性剪切变形-构造分异热液期，与2期脆-韧性剪切变形相对应，第2期为主成矿期。其成矿机理是脆-韧性剪切变形动力成岩成矿。     

陕西岚皋－镇坪一带早古生代火山杂岩成岩构造环境及碱（钾）质煌斑岩含矿性探讨

对北大巴山地区岚皋－镇坪一带的区域地质构造演化及其与早古生代碱基性火山杂岩的成岩关系进行了综合分析，指出本区曾经历了裂陷－愈合一再裂陷－愈合的地质发展和演化。早古生代时期本区是一个在已固结愈合的中－晚元古代的裂陷的扬子地台北缘构造软弱带的基础上重新活化的大陆边缘陆内断陷构造带。它不仅控制了区内该时期碱基性火山杂岩的产出位置、岩浆脉动活动特征，而且还影响到岩浆物质来源的深度。在此基础上，笔者探讨了与杂岩密切相关的碱（钾）质煌斑岩的金刚石含矿性。     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.