赣南地区石雷石英闪长岩的成因:岩石化学、副矿物微量元素、锆石U-Pb年代学与Sr-Nd-Hf同位素制约

石雷石英闪长岩是赣南崇-余-犹地区比较特殊的闪长质侵入体。锆石的原位U-Pb定年表明,该岩体侵位于433.5±3.4Ma。全岩主量元素特征上显示出中偏酸性(SiO2=56.92%～64.70%),富Al(Al2O3=14.10%～14.83%),富碱(Alk=6.41%～7.40%)特别是富钾(K2O=3.86%～4.85%),镁、铁含量较高,MgO:3.47%～5.95%,FeOT:5.23%～8.14%以及低磷(P2O5=0.27%～0.4%)的特点;微量元素上主要富集K、Rb、Cs等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti、P等高场强元素。磷灰石微量元素特征上显示高度富集稀土元素特别是轻稀土元素的特征;具有Eu的负异常(δEu=0.37～0.45)。ISr位于0.7073～0.7132之间,εNd(t)变化于-8.41～-4.97之间,两阶段钕模式年龄介于1.58～1.86Ga之间,Hf同位素组成相对均一,εHf(t)主要集中变化于-8～-2之间,两阶段Hf模式年龄加权平均为1.77±0.09Ga,这些特征都暗示了该石英闪长质岩体的形成是强烈壳幔相互作用的产物,区内加里东晚期可能发生了局部的岩石圈的减薄。     

天水渭北地区变质花岗岩类岩石学特征及其地质时代

天水渭北地区地处祁连与北秦岭造山带结合部位。通过详细的岩石学特征、接触关系、形变及变质特征研究证实,尽管岩体有较强烈的变质和变形作用,但岩体内保留有清晰的原生岩浆组构,岩体与围岩有清楚的侵入关系,因而从变质地层中识别和解体出来众多的变质花岗岩类。主要成岩期及代表性岩类有:晚元古代为片麻状正长花岗岩—二长花岗岩—花岗闪长岩,同位素年龄为953.4～1 450 Ma;震旦纪为片理化石英二长岩—石英闪长岩,同位素年龄为547 Ma。识别和解体出的这些变质花岗岩类,为进一步研究祁连和北秦岭两大构造单元的岩浆事件和构造演化提供了十分重要的信息。     

Amphibole Ar/Ar Geochronology from the Okcheon Metamorphic Belt, South Korea and its Tectonic Implications

An understanding of the Okcheon Metamorphic Belt (OMB) in South Korea is central to unraveling the tectono-metamorphic evolution of East Asia. Amphibole-bearing rocks in the OMB occur as calcsilicate layers and lenses in psammitic rocks, in the psammitic rocks themselves, and in the mafic volcanic layers and intrusives. Most amphiboles fail to show ⁴⁰Ar/³⁹Ar plateau ages; those that do have ages ranging from 132 to 975 Ma. The disturbed age pattern and wide variation in ⁴⁰Ar/³⁹Ar ages can be related to metamorphic grade, retrograde chemical reactions, excess Ar and amphibole composition. The oldest age (975 Ma) can be interpreted either as an old igneous or metamorphic age predating sedimentation or a false age caused by excess Ar. The youngest age of 132 Ma and the disturbed age pattern found in amphiboles from rocks located close to Jurassic granitoids are the result of retrograde thermal metamorphic effects accompanying intrusion of the granitoids. Some medium- or coarse-grained amphiboles in the calcsilicates are aggregates of fine-grained crystals. As a result, they are heterogeneous and prove to be readily affected by excess Ar. A disturbed age pattern in amphiboles from the calcsilicates occurring in the high-grade metamorphic zone may also be the product of excess Ar. On the other hand, the disturbed pattern of amphiboles present in the calcsilicates from the low-grade metamorphic zone could arise from both excess Ar and mixed ages. However, amphiboles from psammitic rocks and some calcsilicates in the high-grade metamorphic zone and in intrusive metabasites display real plateau ages of 237 to 261 Ma. The temperature conditions in the high-grade metamorphic zone were higher than the argon closing temperature for amphibole, and the amphiboles in this zone give plateau ages only when they are homogeneous in composition, lack excess Ar, and have not been thermally affected by intrusion of the granitoids. The unmodified ⁴⁰Ar/³⁹Ar ages prove rather younger than the age of the Late Paleozoic metamorphic event of 280 to 300 Ma, but they are close to muscovite K-Ar ages of 263 to 277 Ma. These ⁴⁰Ar/³⁹Ar amphibole ages are interpreted as the time of cooling that followed the main regional, intermediate-P/T metamorphic climax. The results demonstrate that interpretation of ⁴⁰Ar/³⁹Ar amphibole ages in an area subjected to several metamorphic events can be accomplished only by undertaking a thorough tectono-metamorphic study, accompanied by detailed chemical analysis of the amphiboles.     

青海都兰县阿斯哈金矿区花岗斑岩岩石地球化学、锆石U-Pb年代学与Hf同位素研究

阿斯哈金矿区钻孔中新发现的花岗斑岩,呈岩脉、岩株或舌状分布。岩石呈灰-灰白色,细-中粒斑状结构,块状构造。主要矿物为石英、斜长石、钾长石、黑云母及少量角闪石,副矿物有磁铁矿、钛铁矿、锆石、磷灰石和榍石等。全岩高硅(SiO_2=70.03%~72.83%),高钾(K_2O=3.96%~5.21%),低P_2O_5(0.09%~0.10%),低FeO~T/MgO(1.76~3.91),A/CNK值(1.04~1.29)多数小于1.1,为高钾钙碱性系列弱过铝质-过铝质花岗岩类岩石,具有I型花岗岩特征。样品具有轻稀土富集和中等负Eu异常(δEu=0.71~0.78)特征,且富集大离子亲石元素(LILE:K、Rb、Th、U等)、亏损高场强元素(HFSE:Nb、Ta、Ti等)。LA-ICP-MS锆石U-Pb定年结果显示,其结晶年龄为222.1±3.9 Ma(MSWD=5.4,n=15),形成于晚三叠世。锆石Hf同位素组成(ε_(Hf)(t)=-4.3~-1.4)和二阶段Hf模式年龄(t_(DM2)=1.34~1.53 Ga),表明新发现的花岗斑岩源于古老地壳物质的深熔或重熔,并可能有幔源物质的加入。上述特征表明,阿斯哈金矿区花岗斑岩形成于东昆仑晚古生代-早中生代构造-岩浆旋回的碰撞晚期-后碰撞阶段,可能是晚三叠世幔源岩浆底侵下地壳岩石部分熔融的产物,并在形成过程中有幔源物质的加入。此外,研究区花岗斑岩的侵位与沟里地区(包括阿斯哈)金多金属矿床的形成具有内在的联系。     

Mid–Late Triassic metamorphic event for Changhai meta-sedimentary rocks from the SE Jiao–Liao–Ji Belt,North China Craton: Evidence from monazite U–Th–Pb and muscovite Ar–Ar dating

The precise constraints on the timing of metamorphism of the Changhai metamorphic complex is of great importance considering the prolonged controversial issue of the north margin and the extension of the Sulu–Dabie HP–UHP Belt. While the monazite U–Th–Pb and muscovite ⁴⁰Ar/³⁹Ar techniques are widely accepted as two of the most powerful dating tools for revealing the thermal histories of medium–low grade metamorphic rocks and precisely constraining the timing of metamorphism. The Changhai metamorphic complex at the SE Jiao–Liao–Ji Belt, North China Craton consists of a variety of pelitic schist and Grt–Ky-bearing paragneiss, and minor quartzite and marble. Analyses of mineral inclusions and back-scattered electric (BSE) images of monazites, combined with LA–ICP–MS U–Th–Pb ages for monazites and ⁴⁰Ar/³⁹Ar ages for muscovites, provide evidence of the origin and metamorphic age of the Changhai metamorphic complex. Monazites separates from various Grt–Mus schists and Grt–Ky–St–Mus paragneisses exhibit homogeneous BSE images from cores to rims, and contain inclusion assemblages of Grt + Mus + Qtz ± Ctd ± Ky in schist, and Grt + Ky + St + Mus + Pl + Kfs + Qtz inclusions in paragneiss. These inclusion assemblages are very similar to matrix minerals of host rocks, indicating they are metamorphic rather than inherited or detrital in origin. LA–ICP–MS U–Th–Pb dating reveals that monazites of schist and paragneiss have consistent ²⁰⁶Pb/²³⁸U ages ranging from 228.1 ± 3.8 to 218.2 ± 3.7 Ma. In contrast, muscovites from various schists show slightly older ⁴⁰Ar/³⁹Ar plateau ages of 236.1 ± 1.5 to 230.2 ± 1.2 Ma. These geochronological and petrological data conclude that the pelitic sediments have experienced a metamorphic event at the Mid–Late Triassic (236.1–218.2 Ma) rather than the Paleoproterozoic (1950–1850 Ma), commonly regarded as the Precambrian basement for the Jiao–Liao–Ji Belt. Hence, the Changhai metamorphic complex should be considered as a discrete lithotectonic group.This newly recognized Mid–Late Triassic metamorphic event (236.1–218.2 Ma) for the Changhai metamorphic complex is coeval with the HP–UHP metamorphic event (235–220 Ma) for Sulu–Dabie rocks. This leads us to speculate that the metamorphism of the Changhai complex belt along the SE margin of the North China Craton was genetically related to the Mid–Late Triassic collision of the North China and South China cratons. By the same token, the Sulu–Dabie HP–UHP Belt may have extended through Yantai, and the southern Yellow Sea, and to the southern side of the Changhai metamorphic complex.     

内蒙古孟恩陶勒盖银多金属矿床及其附近侵入岩的年代学

孟恩陶勒盖是内蒙古东部地区的一处大型银多金属矿床,铅锌银矿体呈脉状产出,受东西向断裂控制。对孟恩陶勒盖矿区及其外围主要侵入岩体开展了年代学和地球化学研究。LA-MC-ICP-MS锆石测年结果表明：孟恩陶勒盖岩基中黑云母斜长花岗岩的锆石年龄为（240.5±1.2） Ma,MSWD=0.48;白云母斜长花岗岩的锆石年龄为（234.3±3.2） Ma,MSWD=0.21;矿区外围杜尔基岩基中的黑云母正长花岗岩的锆石年龄为（154.5±0.5） Ma,MSWD=0.41;矿区外围的安山玢岩的锆石年龄为（127.5±0.7） Ma,MSWD=1.3;分别代表了中三叠世、晚侏罗世和早白垩世的3期岩浆活动。岩石地球化学分析结果表明：孟恩陶勒盖岩基的黑云母斜长花岗岩和白云母斜长花岗岩与杜尔基岩体的黑云母正长花岗岩均为富SiO₂、富碱、准铝的钙碱性岩石,具有轻稀土分异明显、富集大离子亲石元素（LILE）为特征,其中Ba、Nb、La、Sr、P、Ti相对亏损,而Rb、Th、K、Ta、Ce、Nd、Hf、Sm、Y 和Yb相对富集。岩体年代学和岩石地球化学特征表明,孟恩陶勒盖岩基和杜尔基岩基分别形成于印支期的碰撞造山和燕山期的伸展构造环境。根据获得的侵入岩的测年数据与前人获得的孟恩陶勒盖银铅锌矿与成矿有关的蚀变白云母的Ar-Ar年龄(179. 0士1. 5) Ma对比显示,这些侵入岩的侵位年龄与成矿年龄之间差别较大,说明这些岩体不太可能是孟恩陶勒盖银铅锌矿床的成矿母岩。成矿岩体可能在深部尚未出露,或者已被杜尔基岩体改造。     

北秦岭四方台基性-超基性杂岩锆石 LA-ICP-MS年代学研究

四方台杂岩体是北秦岭沿商-丹带出露的基性-超基性杂岩体中最大的一个,出露面积约40 km2,由超基性-基性-中性岩石组成,侵入到丹凤群中。对四方台杂岩体中辉长岩锆石进行LA-ICP-MS微区定年研究,获得岩体的成岩时代为460±29 Ma。获得的32个测点可明显地分为400~500 Ma、700~900 Ma、1 800~2 600 Ma和2 700~2 918 Ma这4个时段,可能分别代表了北秦岭造山带不同地质时期的构造-岩浆事件的时代信息。其中400~500Ma与北秦岭地区表现强烈的加里东运动时限一致,而700~900 Ma则可能与830~740 Ma中国中西部地区响应积极的、造成Rodinia超大陆裂解的地幔柱活动有关。     

江西冷水坑矿区构造-岩浆活动的年代学约束

江西省冷水坑矿区火成岩-构造演化一直缺少系统的年代学制约.作者运用LA-ICP-MS锆石U-Pb和40Ar/39Ar测年技术,对冷水坑矿区两套火山岩地层(打鼓顶组和鹅湖岭组)、含矿花岗斑岩和主推覆断层F2进行了年代学测试,结果表明,打鼓顶组流纹质含角砾熔结凝灰岩形成于160.8±1.9Ma,鹅湖岭组合角砾熔结凝灰岩则具有间歇性和多期喷发特点,其最初活动时间为159Ma,而主体形成于146.6±2.2Ma;矿区含矿花岗斑岩与打鼓顶组、鹅湖岭组几乎同期形成,年龄介于163.6 ±2.1Ma～154.3±3.0Ma之间;研究区构造活动起始时间不晚于加里东期,推覆断层F2中保留有40Ar/39Ar年龄为398.5±2.6Ma的构造活动痕迹,中生代重新复活,导致震旦系叠覆于鹅湖岭组之上,年龄晚于146.6Ma,可能对含矿斑岩体起破坏作用.     

西天山特克斯晚古生代辉长岩岩石地球化学

西天山特克斯县东北部的哈拉达拉岩体是西天山出露规模最大的层状基性-超基性侵入岩体,主要由橄长岩、橄榄辉长岩、角闪辉长岩和辉长岩组成。本文获得该辉长质岩体锆石SIMSU-Pb年龄为306.2±2.7Ma,属于晚石炭世。该岩体SiO2含量范围为44.49%～48.46%,K2O、Na2O含量低,Mg、Fe含量较高,Mg#平均值达71.4。岩体具有拉斑玄武岩系列特征,且有从低钾拉斑系列向钙碱性系列和高钾钙碱性系列演化的趋势。部分样品的MgO、Al2O3和CaO含量偏高,可能为橄榄石和斜长石的堆晶所致。岩体明显富集Rb、Ba、K、Pb、Sr等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,La/Nb比值大于1.4,与流体交代地幔楔熔融的弧火成岩浆特征类似。岩体具有Th负异常,暗示岩浆活动过程中可能混染了下地壳成分。岩体稀土元素总量较低,轻、重稀土元素分异较弱,由于斜长石堆晶作用,部分样品具有明显的正Eu异常。区域构造演化和岩石学资料等显示西天山在晚石炭世—早二叠世大地构造格架演化发生了转变,特克斯地区处于俯冲碰撞阶段向碰撞后伸展阶段变化的过渡环境中,特克斯晚古生代辉长岩体很可能是在这种构造体制的转变过程中形成的,指示了西天山大地构造演化从弧环境下的挤压碰撞到陆内伸展环境的转变。     

海南石碌铁矿独居石的成因类型、化学定年及地质意义

海南石碌铁矿是我国最大的富赤铁矿矿床,同时伴生有钴、铜等多金属矿产。轴向北西-南东向的复式向斜是石碌铁、钴铜矿体的主要控矿构造,富铁矿和钴铜矿的形成与该褶皱变形及伴随的韧性剪切和高温塑性流动有着密切的关系。为获得该构造变形的年代学信息和证实构造变形对成矿物质的富集影响,本文开展了石碌铁矿近矿围岩—石碌群第六层透辉石透闪石岩中独居石的显微结构观察和电子探针化学Th-U-Pb定年(CHIME法)。显微结构观察发现独居石往往沿岩石面理定向分布,且具典型的球冠结构,表现为围绕独居石核部向外依次出现磷灰石、褐帘石、绿帘石同心环。电子探针分析结果表明这些独居石为Ce-La-Nd磷酸盐[(Ce,La,Nd,Th)PO4],具富钍独居石端元组分。ThO 2含量范围(0.78%~4.61%)、稀土特征以及独居石的产出特征均暗示了其为同构造变质成因。电子探针CHIME化学定年结果表明独居石的年龄变化范围为614~397Ma,并具有两个峰值年龄:即主峰值ca.455Ma和次峰值ca.564Ma。低的ThO 2(0.78%~1.65%),PbO(0.02%~0.04%)和CaO(0.50%~0.97%)含量,以及高的Th/U比值(23.06~53.11)暗示了构成ca.564Ma的独居石是早期剪切变形事件的产物。而在随后剪切变形过程中独居石在低角闪岩相变质条件下以及碱性变质流体诱导下发生了溶解-再沉淀,形成了具ca.455Ma年龄的补丁状成分区。该过程引起了U-Pb体系的局部重置,形成的独居石具有变化较大的ThO 2(0.92%~4.61%)、PbO(0.01%~0.08%)和CaO(0.28%~1.58%)含量范围以及Th/U值(24.83~52.86)。在剪切变形之后,早期变质成因的独居石在绿片岩相退变质作用过程中及富Ca、Fe、Si、Al流体参与的条件下,经不平衡反应形成了磷灰石-褐帘石-绿帘石球冠物,反应机制以独居石和球冠矿物间的元素扩散动力学为主。该反应暗示了REE、Y、Th等元素发生了迁移,并可能引起边部独居石的部分Pb丢失。结合华南的构造演化,年龄谱主峰值455Ma代表了与华南加里东造山运动有关的区域变质和动力变质作用事件年龄,是加里东运动在海南岛的响应;次峰值年龄564Ma对应着冈瓦纳泛非事件,暗示了华南在晚新元古代-早古生代与冈瓦纳大陆具有亲缘性,华南加里东运动引起陆内造山过程可能与冈瓦纳大陆的聚合碰撞事件有关。因此,晚新元古代-早古生代造山事件对海南岛构造演化历史具重要影响。此外,该构造运动使石碌群发生褶皱变形,伴随产生的变质流体使铁、钴铜成矿元素进一步活化和富集,对石碌铁、钴铜矿的富集有着重要影响。