全谱直读等离子发射光谱法直接测定天然矿泉水中的SO2-4

采用全谱直读等离子发射光谱(ICP-AES)直接测定天然矿泉水中SO2-4的方法在优化工作条件下SO42-的测定下限为0.09mgL-1,方法简便,快速,适用于批量生产.     

Cathodoluminescence of authigenic albite

Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn²⁺- and Fe³⁺-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE).     

小波分析在声发射资料处理中的初步应用

针对声发射数据分析的一些难点，把最近20年发展起来的小波技术引入声发射资料处理中，分析证明结果可靠。它在本中的应用有：（1）提取有效信息。小波强大分解（细化0能力可用来从高口音中找出有效记录，分解合成时可以去掉不理想的通道，使声发射数据更加“规则化”，有望实现到时自动判读。（2）对相互叠加的事件进行有效分离。结合全波记录，可使事件尽可能少丢失，提高声发射数量统计及b值计算等的精度。（3）使成份复杂的声发射波形数据分离成具有单一特征的波，但分解后的波究竟属于P波还是S波，甚至面波，尚难确定。     

Simultaneous radio and optical observations of the mid-latitude atmospheric response to a major geomagnetic storm of 6–8 April 2000

Basic properties of the mid-latitude traveling ionospheric disturbances (TIDs) during the maximum phase of a major magnetic storm of 6–8 April 2000 are shown. Total electron content (TEC) variations were studied by using data from GPS receivers located in Russia and Central Asia. The nightglow response to this storm at mesopause and termospheric altitudes was also measured by optical instruments FENIX located at the observatory of the Institute of Solar-Terrestrial Physics (51.9°N,103.0°E), and MORTI located at the observatory of the Institute of Ionosphere (43.2°N, 77.0°E). Observations of the O (557.7 and 630.0 nm) emissions originating from atmospheric layers centered at altitudes of 90 and 250 km were carried out at Irkutsk and of the O₂(b¹∑_g⁺−X³∑_g⁻) (0-1) emission originating from an atmospheric layer centered at altitude of 94 km was carried out at Almaty. Our radio and optical measurement network observed a storm-induced solitary large-scale wave with duration of 1 h and a wave front width of no less than 5000 km, while it traveled equatorward with a velocity of 200 m/s from 62°N to 38°N geographic latitude. The TEC disturbance, basically displaying an electron content depression in the maximum of the F2 region, reveals a good correlation with growing nightglow emission, the temporal shift between the TEC and emission variation maxima being different for different altitudes. A comparison of the auroral oval parameters with dynamic spectra of TEC variations and optical 630 nm emissions in the frequency range 0.4–4 mHz (250–2500 s periods) showed that as the auroral oval expands into mid-latitudes, also does the region with a developed medium-sale and small-scale TEC structure.     

等离子体发射光谱法直接测定海洋沉积物中的微量稀土元素

应用全谱直读电感耦合等离子体发射光谱法对海洋沉积物中微量稀土元素的测定进行了研究，选择了最佳的仪器工作条件，采用多谱线拟合技术进行校正，样品的加标回收率为94．0％-110．0％。方法采用海底沉积物国家一级标准物质进行验证，测定结果与标准值较吻合，各元素10次测定的RSD≤11．3％。     

单道扫描电感耦合等离子体发射光谱法测定珊瑚礁中主量和微量元素

建立了用单道扫描电感耦合等离子体发射光谱法测定珊瑚礁中主量和微量元素的方法。珊瑚礁样品经酸溶解后,直接进行Ca、Mg、K、Na、V、Sr、Ba、Co、Ni、Pb、Li、Rb的测定,方法检出限为0.0004～0.1mg/L,精密度RSD<5%(n=6),样品的加标回收率为97%～105%。测定w(CaO)为50%的样品,结果与传统的EDTA容量法相符。方法经碳酸盐岩石国家一级标准物质验证可行,已用于大批量的珊瑚礁样品的测定。     

加卸载响应比(LURR)理论的实验研究

利用大尺度岩石试件破坏声发射实验，对加卸载响应比(Load/Unload Response Ratio)理论进行了实验研究。实验采用的加载条件力求能够模拟地下岩石的复杂受力过程。在加载过程中，岩石试件内部出现的损伤用声发射技术进行了记录。实验数据经过分析之后所得的结论与加卸载响应比理论预测的结果相符合。把加卸载响应比值Y的变化情况与声发射事件定位的过程相对比，也可以进一步看出岩石材料内部的损伤发展过程与加卸载响应比Y值的变化具有一致性。而高Y值的异常情况出现，又是在材料发生最终破坏之前，所以，可以用加卸载响应比理论定量地分析岩石试件损伤演化情况，从而对岩石材料的破坏及地震做出预测。实验结果再一次验证了加卸载响应比理论。     

ADV measurements of velocity distributions in a gravel‐bed flume

Velocity measurements carried out by an acoustic doppler velocimeter (ADV) in a rectangular laboratory ?ume having a gravel bed are presented. The velocity pro?les are measured in six verticals of the channel cross‐section having an increasing distance (from 4 to 38·5 cm) from the ?ume wall. The experimental runs are carried out for ?ve different bed arrangements, characterized by different concentrations of coarser elements, and for the two conditions of small‐ and large‐scale roughness. For both hydraulic conditions, the velocity measurements are ?rst used to test the applicability of the Dean pro?le and of the logarithmic pro?le corrected by a divergence function proposed in this paper. Then, for each value of the depth sediment ratio h/d₈₄, the non‐dimensional friction factor parameter is calculated by integration of the measured velocity distributions in the different verticals of the cross‐section. Finally a semi‐logarithmic ?ow resistance equation is empirically deduced. Copyright © 2003 John Wiley & Sons, Ltd.     

On Rhythmical Layering of Rocks Formed from Basaltic Magma

Formation of rhythmical layering in intrusive basic and ultrabasic rock bodies is explained in different ways, in particular, by the movement of microparticles (mineral clusters) of plagioclase and pyroxene within the basalt melt under the influence of thermal and gravitational forces. A model of cluster movement is proposed as a consequence of the forces appearing when ultrasonic elastic fluctuations pass through the melt. The model is based on fundamental dynamic equations. Depending on cluster density, wave parameters, and magmatic chamber size, in the melt there can form different combinations of rhythmically alternating layers of different composition.