Gas and Particulate Products Distribution from the Photooxidation of α-Humulene in the Presence of NOx, Natural Atmospheric Air and Sunlight

The photooxidation of -humulene in the presence of NO_x, natural sunlight, and rural background air was investigated using a combination of gas chromatography-mass spectrometry (GC-MS) and high performance liquid chromatography (HPLC). Identification and quantification of gas and particulate reaction products were reported over the course of the reaction. The daytime photooxidation was carried out in a large outdoor smog chamber (190 m³). A wide range of ring retaining and ring opening products in the gas and particle phase are reported. On average, measured gas and particle phase products accounted for 44% of the reacted -humulene carbon. Measurements show that a number of reaction products with low vapor pressures (e.g. 3-seco--humulone aldehyde, 7-seco--humulone aldehyde, -humulal aldehyde, -humulene 3-oxide or -humulene 7-oxide, -humulaic/alic acid isomers, and 3-seco--14-hydroxyhumulone aldehyde) were found in the early stage of the reaction and may play an important role in the early formation of secondary organic aerosol. A detailed mechanism is proposed to account for most products observed in this investigation.     

农田生态系统温室气体排放研究进展

自1985年起,中国科学院大气物理研究所利用自行设计制造的自动观测仪器系统,历时十六年先后对我国四大类主要水稻产区的甲烷排放规律及其与土壤、气象条件和农业管理措施的关系进行了系统野外观测实验,并对稻田甲烷产生、转化和输送机理进行了理论研究,探讨了控制稻田甲烷排放的实用措施,建立了估算和预测稻田甲烷排放的数值模型.在甲烷排放的时空变化规律和转化率研究方面有一系列新的发现,在稻田甲烷产生率、排放率及其与环境条件的关系方面取得一系列新的成果,以充分证据改变了国际上关于全球和中国稻田甲烷排放总量的估算.在对稻田甲     

Köppen Climate Types in Observed and Simulated Climates

The Köppen climate classification was applied to the observed gridded climatological sets and the outputs of four general circulation models (GCMs) over the continents of the Earth. All data had been acquired via the Data Distribution Centre established by the Intergovernmental Panel on Climate Change. The ability of the GCMs to simulate the Köppen climate zones identified in the real data was explored and possible future (global warming) changes in the climate types' distribution for each GCM were assessed. Differences in the area distributions derived from the GCMs' recent climate simulations give evidence about uncertainties generally involved in climate models. As to the global warming simulations, all GCM projections of warming climate (horizon 2050) show that the zones representing tropical rain climates and dry climates become larger, and the zones identified with boreal forest and snow climates together with the polar climates are smaller.     

低质量X射线双星的毫秒级准周期信号——最近的进展

最近对低质量X射线双星中的千赫兹准周期振动的研究表明 ,是辐射压力 ,而不是盘和磁球的相互作用以及处于盘内边界的广义相对论效应在短时标的盘切断机制上起作用。本文给出了一些研究结果及讨论。     

Fluxes of CO<Subscript>2</Subscript>, CH<Subscript>4</Subscript> and N<Subscript>2</Subscript>O from alpine grassland in the Tibetan Plateau

Using static chamber technique,fluxes of CO2,CH4 and N2O were measured in the alpine grassland area from July 2000 to July 2001,determinations of mean fluxes showed that CO2 and N2O were generally released from the soil,while the alpine grassland accounted for a weak CH4 sink.Fluxes of CO2,CH4 and N2O ranged widely.The highest CO2 emission occurred in August,whereas almost 90?of the whole year emission occurred in the growing season.But the variations of CH4 and N2O fluxes did not show any clear patterns over the one-year-experiment.During a daily variation,the maximum CO2 emission occurred at 16:00,and then decreased to the minimum emission in the early morning.Daily pattern analyses indicated that the variation in CO2 fluxes was positively related to air temperatures(R^2=0.73)and soil temperatures at a depth of 5 cm(R^2=0.86),whereas daily variations in CH4 and N2O fluxes were poorly explained by soil temperatures and climatic variables.CO2 emissions in this area were much lower than other grasslands in plain areas.     

The Non-Linear Stability of L4 in the Restricted Three-Body Problem when the Bigger Primary is a Triaxial Rigid Body

The non-linear stability of L ₄ in the restricted three-body problem has been studied when the bigger primary is a triaxial rigid body with its equatorial plane coincident with the plane of motion. It is found that L ₄ is stable in the range of linear stability except for three mass ratios:

1-（4-硝基苯基）-3-（3，5-二溴吡啶）三氮烯的合成及其与镍的显色反应

合成了1-(4-硝基苯基)-3-(3,5-二溴吡啶)三氮烯(NPDBPDT),并研究了NPD-BPDT与镍的显色反应。在pH 10.0的Na2B4O7-NaOH缓冲溶液介质中,表面活性剂Triton X-100存在下,镍与试剂生成摩尔比为1∶4的络合物在470 nm处有最大正吸收峰,表观摩尔吸光系数为1.02×105L.mol-1.cm-1;在540 nm处有最大负吸收峰,表观摩尔吸光系数为1.15×105L.mol-1.cm-1;以540 nm为参比波长、470 nm为测量波长进行双波长测定,表观摩尔吸光系数为2.17×105L.mol-1.cm-1。镍含量在0~480μg/L内符合比尔定律。方法用于合金样品中镍的测定,结果与原子吸收法相符,加标回收率为98.0%~102.0%;精密度小于5%(RSD,n=6)。     

山西洪洞ML5.0地震前后临潼台流体异常特征

采用滤波、拟合、去周期、五日均值等方法,对临潼台水氡、水温、水溶气资料进行了分析处理,得到以下认识:用提取异常方法对原始曲线进行处理后,地震前兆异常更加明显与突出,这些异常均属于短期和临震前兆异常;临潼台流体对2003年山西洪洞ML5.0地震有明显反映,其原因一方面由于此次地震距临潼台较近,另一方面也反映了临潼台所处构造位置比较特殊,位于映震的灵敏位置。     

华北平原冬麦田土壤CH4的吸收特征研究

利用静态箱/气相色谱(GC)法,对华北平原冬小麦拔节-成熟期间麦田土壤CH₄气体通量进行了测定,得出华北平原典型冬麦田土壤是大气CH₄的弱吸收汇。试验期间土壤CH₄通量存在明显的季节变化和日变化,麦田拔节-成熟期间土壤CH₄通量日平均值为-18.3μg·m^-2·h^-1,波动范围为-4.3-24.4μg·m^-2·h^-1;在土壤CH₄通量的日变化中,观测到麦田土壤在午间和夜间都有一个吸收峰,峰值出现的时间因生育期不同而有所不同。试验期间CH₄通量日平均值与土壤温度关系不明显,而与土壤水分呈负相关(α=0.01);日变化中土壤CH₄通量与地表温度的相关性较差,而与5cm地温相关密切。麦田拔节-成熟期间土壤CH₄通量日平均值随NH4+-N施用量的增加呈递减规律,农田秸秆还田后不利于土壤对CH₄的吸收。     

Carbon isotope ratios of C_4 plants in loess areas of North China

Recent stable carbon isotope studies have shown that the occurrence of C4 plants on the Earth was much later than that of C3 plants and there was a global ex-pansion of C4 biomass around 5―8 million years ago[1]. Although far fewer species use the C4 pat…