内湾沉积物生物硅化学测定法的实验条件探讨

对国内外已经建立的几种生物硅的测定方法进行简要的评述,并详细地对内湾沉积物中生物硅化学提取法的条件选取进行实验探讨,对低生物硅含量的内湾沉积物测定提出了较优的条件。     

闽江口入海悬沙输运的数值模拟

闽江河口位于福建省东部,本文利用欧拉-拉格朗日差分方法模拟闽江口及附近海域在不同径流下的潮流场,并建立拉格朗日水质点跟踪方法近似模拟了悬沙在海域中的迁移过程．水质点运动轨迹计算结果表明,闽江口悬沙在外海主要向南方或东南方输运,其轨迹呈现螺旋线．在洪峰流量下,悬沙运移距离较远．     

Benthic nitrate biogeochemistry affected by tidal modulation of Submarine Groundwater Discharge (SGD) through a sandy beach face, Ria Formosa, Southwestern Iberia

To investigate both the role of tides on the timing and magnitude of Submarine Groundwater Discharge (SGD), and the effect on benthic nitrogen biogeochemistry of nitrate-enriched brackish water percolating upwards at the seepage face, we conducted a study of SGD rates measured simultaneously with seepage meters and mini-piezometers, combined with sets (n = 39) of high resolution in-situ porewater profiles describing NH₄⁺, NO₃⁻, Si(OH)₄ and salinity distribution with depth (0–20 cm). Sampling took place during two consecutive spring tidal cycles in four different months (November 2005, March, April and August 2006) at a backbarrier beach face in the Ria Formosa lagoon, southern Portugal. Our results show that the tide is one of the major agents controlling the timing and magnitude of SGD into the Ria Formosa. Intermittent pumping of brackish, nitrate-bearing water at the beach face through surface sediments changed both the magnitudes and depth distributions of porewater NH₄⁺ and NO₃⁻ concentrations. The most significant changes in nitrate and ammonium concentrations were observed in near-surface sediment horizons coinciding with increased fraction of N in benthic organic matter, as shown by the organic C:N ratio. On the basis of mass balance calculations executed on available benthic profiles, providing ratios of net Ammonium Production Rate (APR) to Nitrate Reduction Rate (NRR), coupled to stoichiometric calculations based on the composition of organic matter, potential pathways of nitrogen transformation were speculated upon. Although the seepage face occasionally contributes to reduce the groundwater-borne DIN loading of the lagoon, mass balance analysis suggests that a relatively high proportion of the SGD-borne nitrogen flowing into the lagoon may be enhanced by nitrification at the shallow (1–3 cm) subsurface and modulated by dissimilatory nitrate reduction to ammonium (DNRA).     

海三菱藨草(Scirpus mariqueter)根际沉积物中重金属生物有效性的影响因素

采用野外连续调查和实验分析方法,连续3年研究了海三菱藨草根际沉积物重金属（Cu、Zn、Pb和Cd）生物有效性的主要影响因素（生长季节、pH、P、Eh和DO等）。结果表明,植物不同生长季节的变化影响根际沉积物生物有效性的季节变化。具体表现为：Cu和Pb均在春、夏季可交换态含量较高,生物有效性较高,而秋、冬季可交换态较低,生物有效性较低,但碳酸盐结合态和铁锰氧化态二者之和也比较高,具有一定的潜在生物有效性;Zn在任何季节的可交换态比例均不高,以有机结合态和残渣态的形态为主,生物有效性较低;Cd一般以残渣态为主,基本不具有生物有效性。pH值下降,春、夏季可交换态和铁锰氧化物结合态增加,而有机结合态和碳酸盐结合态减少,提高了生物有效性,而秋、冬季正好相反;磷对重金属生物有效具有直接影响的为无机磷,春、夏季随着无机磷的减少,pH值下降,提高了生物有效性。春、夏季根际Eh和溶解氧含量增加,降低了其生物有效性。     

辽河口沉积物中参与主要生物地化循环的微生物功能基因分析

辽河口区域丰富的生物多样性在生物地球化学循环和维持生态系统功能等方面发挥着极其重要的作用.研究辽河口表层沉积物中参与常见地球化学循环的功能基因及其关键影响因子,对揭示和预测辽河口沉积物微生物的功能代谢潜力和受环境变化的影响具有重要意义.应用功能基因芯片(GeoChip 4.0)技术开展微生物功能基因多样性研究.结果 表...     

海洋沉积物中铜含量测量不确定度评定 ——电热板加热消解法与微波消解法的比对

电热板加热消解法和微波消解法是目前海洋沉积物样品消解的常用方法。为了比较这两种处理方法对检测结果准确性的影响程度,文章依据《测量不确定度的评定与表示》技术规定中的相关要求对海洋沉积物中铜含量测定过程中采取的两种消解方法进行了不确定度评定与对比,建立了模型,并对各不确定度分量进行分析和量化,计算出两种消解方法测量沉积物中铜含量的相对合成不确定度分别为0.06721和0.04033,扩展不确定度分别为4.0mg/kg和2.4mg/kg。通过比较两种消解方法对测定结果不确定度的贡献,发现微波消解法明显优于电热板加热法。     

基于海底表层沉积物声速特征的南海地声模型

在由垂直声速梯度建立的地声模型基础上,通过引入沉积物与海水声速比和沉积物压缩波与切变波声速比两个表征沉积物声学特征参数得到更全面和有实际指导意义的地声模型。在沉积物声波传播FCMCM模型基础上,基于热作用和重力作用下沉积物两相介质的应力应变分析,建立TFCMCM和DFCFCM模型,运用模型校正表层沉积物声速特征来计算和解释地声模型。根据海底表层沉积物存在低声速和高声速两种类型,结合沉积物沿纵深孔隙度不变和变化两种类型,得到南海海底沉积物的两类四种典型地声模型:低声速孔隙度不变型、低声速孔隙度减小型、高声速不变型和高声速孔隙度减小型。运用这四种典型地声模型的组合解释了卢博提出的南海三种典型声速结构。认知声速结构将为南海声学探测海底、划分海底区域提供模型支持。     

基于时间平均的海底沉积物声速预测

在海底沉积物声速预测中,把不同海域的物理性质完全不同的沉积物试验数据拟合出一个统一的方程存在不足,不但数据过于离散,而且方程中参量的物理意义不明确。借鉴Wyllie等建立的时间平均方程的思路,基于声传播过程中路程、时间和声速之间的基本关系,引入了表征固液双相之间的堆垒方式和耦合状态对声传播路径影响的耦合系数,建立了沉积物声速预测模型。将鹿回头外海、南海南部和北部的沉积物测量数据进行线性回归分析,分别得出适用于不同海域的沉积物声速预测模型,拟合的复相关系数较大,偏差较小,证明该模型能够反映声速随孔隙度的变化规律,且各参数物理意义明确,具有一定的研究和理论探索意义。     

Distribution of major and trace elements in surface sediments of Hangzhou Bay in China

The Inductively Coupled Plasma Optical Emission Spectrometer was used to analyze sediment samples collected from the Hangzhou Bay to determine major and trace elemental concentrations. Based on these concentrations, the study area can be classified into three geochemical provinces. Province I covers the northern Hangzhou Bay area and contains high concentrations of Al₂ O₃ , Fe₂ O₃ , MgO, Na₂ O, K₂ O, MnO, Cr, Cu, Ni, Pb, V, Co and Zn. Province III is located in the western Hangzhou Bay, near the Qiantang River mouth, and contains high concentrations of SiO₂ , Na₂ O, P₂ O₅ , TiO₂ , Cr, Sr, Zr. Province II is located in the middle and eastern Hangzhou Bay, with the medium concentrations of major and trace elements. The results also demonstrate that the grain size is the dominating factor controlling the spatial variations of elemental concentrations, and the Changjiang River （Yangtze River） and Qiantang River sediments play an important role in the distribution of these elements. Anthropogenic impact on heavy metal concentrations （especially Cr, Sr and Zr） can be detected in the surface sediments near the Qiantang River mouth.     

海洋表层沉积物中金属镉的来源解析

利用2015年8月份对长江口及其邻近海域表层沉积物的监测数据,基于主成分分析/绝对主成分分数(PCA/APCS)受体模型定量解析了重金属元素镉(Cd)的可能来源,并结合地统计学插值了Cd的源贡献量的空间分布状况,结果表明沉积物中镉污染主要存在3个可能来源,源头及贡献率分别为工业污染(18.8%)、陆地径流输入(66.0%)、生物活动等自然因素(13.6%),并且各个源头贡献量具有不同的空间分布状况,其中工业污染的高值区主要集中在靠近陆地区域,陆地径流输入的分布呈现由近岸向外海逐减降低的特征,生物活动等自然因素的高值区主要集中在远离陆地的外海区域。