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11.
12.
YousifK. Kharaka Evangelos G. Kakouros James J. Thordsen David L. Naftz 《中国地球化学学报》2006,25(B08):100-101
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments. 相似文献
13.
Chunye LIN Mengchang HE Baixing YAN Xiangchun QUAN Yuxiang ZHOU Wei GUO Zhifeng YANG 《中国地球化学学报》2006,25(B08):118-119
The Second Songhua River was subjected to a large amount of untreated effluent from petrochemical industries in Jilin City in the 1960s to the 1970s. The objectives of this study were to investigate the mercury and other heavy metal contamination in the sediment of the river. The river bottom sediment was sampled from the river segment between Jilin City to Haerbin City in 2005. Total concentrations of Hg, Cd, Cu, Cr, Pb, Zn, Ni, As, Sc, and major cations (A1, Fe, Mg, Ca, K, Na) in the sediment were measured by atomic fluorescence spectrometer, ICP-MS, and ICP-OES, respectively, following digestion with various acids. We found the concentrations of most elements in the uncontaminated sediment were significantly correlated to those of Sc. 相似文献
14.
Karst groundwater protection in the Kupa River catchment area and sustainable development 总被引:1,自引:0,他引:1
One of the most significant water resources in the Republic of Croatia is the catchment area of the Kupa River, located in
the region bordering the Republic of Slovenia. About 88% of the total amount of water in this catchment originates in Croatia
and just 12% from Slovenia; therefore, the largest part of the catchment area (about 1000 km2) is on the Croatian side of the border. It is a typical karst area of the Dinarides with aquifers characterized by a relatively
rapid water exchange, high groundwater flow velocities and aquifers open to human impact from the surface. Consequently, the
aquifers are highly vulnerable and at risk. Due to the availability of large quantities of high-quality spring water (about
6 m3/s), the entire area has a strategic importance within the context of any future development strategy pertaining to the western
part of Croatia. The catchment area on the Croatian side was investigated using a wide range of research methods that included
a classical hydrogeological approach, the detailed hydrologic calculation of water balance to the hydrogeochemical analyses
and modelling. The objective was to determine protection zones and protection measures for the whole area. The difficulties
are increased due to the fact that the karst catchment area is crossed by major traffic corridors, oil pipelines and a railway
and that many settlements and a highly developed wood industry are present. The combination of protecting water resources
with adequate prevention measures and necessary remedial activities that should satisfy the very strict requirements necessary
for the protection of the karst aquifers while still allowing for present and future human activities is difficult – but not
impossible – to achieve. One good example is the present highway with a closed dewatering system and waste water treatment
before the water passes into the karst underground system. 相似文献
15.
Whereas certain linkages between stream channel morphology and stream ecology are fairly well-understood, how geomorphology influences trophic interactions remains largely unknown. As a first step, a simple, heuristic model is developed that couples reach-scale geomorphic morphology with trophic dynamics between vegetation, detritus, herbivores, and predators. Predation is assumed to increase with depth beyond a threshold depth, and herbivory is assumed to decrease with velocity beyond a threshold velocity. Results show that the modeled food chain is sensitive to channel geometry, particularly around the threshold conditions for predators and herbivores. Importantly, geomorphic influences are not isolated to a particular trophic level, but rather are transferred through the food chain via top-down and bottom-up effects. The modeled system is particularly sensitive to changes in the end-members of the food chain: vegetation and predators. Results illustrate that geomorphic disturbances, known to affect a single trophic level (e.g., fish), likely impact multiple trophic levels in the stream ecosystem via trophic interactions. Such impacts at the multiple trophic level are poorly understood. While limited by the lack of empirical long-term data for testing and calibration, this simple model provides a structure for generating hypotheses, collecting targeted data, and assessing the potential impacts of stream disturbance or restoration on entire stream ecosystems. Further, the model illustrates the potential for future coupled stream models to explore spatial and temporal linkages. 相似文献
16.
New theories to explain how tides and river flow determine estuarine bathymetries have been developed. The range of validity of these theories has been subsequently assessed against a recently available observational data set.Success in reproducing the evolution of estuarine bathymetries that has occurred over the last 10 000 years provides the basis for the translation, here, of these theories into new typologies. These then provide reference frameworks to enhance our perspective on existing morphologies and identify ‘anomalous’ estuaries. Further refinement of these new theories requires analyses of causal factors responsible for such anomalies drawing on classical morphological experience. These frameworks can also be used for calculating likely future bathymetric adjustments for prescribed changes in mean sea level, tidal amplitudes, river flow and sediment supply. 相似文献
17.
L.J. Hou M. Liu J.J. Lu S.Y. Xu D.N. Ou Y. Yang D.G. Zheng 《Environmental Geology》2006,49(7):937-945
The influences of exposure to the atmosphere on ammonium cycle in the intertidal surface sediments were in situ studied with
a geochemical approach at a typical station in the Yangtze Estuary during three tidal cycles in September 2003. During an
about 8-h emersion period of each diurnal tide, six high-resolution vertical profiles of adsorbed and dissolved ammonium were
measured. It was observed that both adsorbed and dissolved ammonium generally had an increasing trend in sediment cores during
the exposure. The rate of ammonium regeneration in sediments was estimated using the accumulation amount of ammonium including
adsorbed and soluble fractions during the daytime emersion. The calculation result showed that there was relatively high ammonification
rate (˜500 nmol N cm−3 day−1), which reflected that organic nitrogen in sediments was quickly decomposed with a residence time of ˜52.7 days. Due to the
dramatic temperature difference observed in sediment profiles, free convection was considered an important mechanism of regulating
the efflux of produced ammonium into overlying waters. The total estimated amount of regenerated ammonium was ˜1.35×105 t N year−1 in the intertidal flat of the Yangtze Estuary, which occupied 7.6% of the total inorganic nitrogen annually transported to
the estuarine ecosystem. 相似文献
18.
人类活动对黄河中游高含沙水流的影响 总被引:7,自引:2,他引:7
以黄河中游干流和渭河、无定河的资料研究了人类活动对黄土高原河流高含沙水流的发生频率的影响。人类破坏森林植被,大量拦截黄河上游清水来源区的清水基流,使得高含沙水流发生频率增大,大规模水土保持措施的实施则使高含沙水流发生频率迅速减小。近50年来黄河干流和一些支流的高含沙水流随时间的变化可以用一个三阶段模式来概括,即20世纪50-60年代,由于人类破坏植被,使高含水流频率增大;20世纪60年代末至80年代中期,大规模水土保持措施的实施使高含沙水流发生的频率减小;20世纪80年代末期以来,人类大量拦截利用清水资源,使高含沙水流的发生频率又复增大。 相似文献
19.
长江巨洪前期物理因子的配置 总被引:4,自引:4,他引:4
提出了长江巨洪前期物理因子配置的概念,在每一次巨洪发生之前,影响巨洪的主要物理因子之间一般都会表现出相似的特征,即出现一些固有的配置,这些配置正是长江发生巨洪的强信号,对长江巨洪的预测研究具有重要的指示作用。 相似文献
20.
马蔼乃 《地理与地理信息科学》2002,18(2):41-44
该文指出 :王化云的治黄思想 ,“上拦下排、两岸分滞、蓄水拦沙、宽河固堤、除害兴利、综合利用” ,实际上是治理黄河的系统工程 ,2 1世纪应该继承和发展黄河系统工程的方略。黄河地处中国腹地 ,是中华民族的摇篮 ,当今高新科技的发展 ,足以从更大的范围 ,以全国的水资源、土资源为核心来考虑黄河的建设。统一计算水资源中的大气水、地表水、地下水、壤中水、生态水、环境水、生产水、生活水 ;统一计算土资源中的土壤资源、沙资源、沙石资源 ,真正按照地理系统工程来建设黄河。 相似文献