基于气体吸附法和X射线Micro-CT三维成像技术定量解析天然和电化学处理绿松石孔隙特征

绿松石是一种多孔材料,其孔隙特征直接影响其颜色、光泽、硬度、耐久性等性质,进而影响其市场价值,电化学处理的主要目的是降低绿松石孔隙度从而使其耐久、保色。采用全自动比表面仪、X射线显微CT(Micro-CT)等测试分析手段,对电化学处理前后绿松石的孔隙特征进行了对比研究。比表面仪研究发现,电化学处理后的绿松石总孔隙度、总孔体积、平均孔径及比表面积均有一定程度的变化;吸附-脱附曲线高压区域天然绿松石吸附曲线斜率变大,而电化学处理绿松石吸附曲线斜率变小;天然绿松石孔径分布曲线为类抛物线,而电化学处理绿松石孔径分布曲线呈内凹曲线状。Micro-CT研究结果表明:天然绿松石中出现的由表面贯穿至内部的大孔洞,经电化学处理后孔洞被不完全充填;天然绿松石存在“流纹状”结构,孔隙沿“流纹”分布,而电化学处理绿松石的“流纹状”结构消失,孔隙分布杂乱无章。本研究首次从孔隙特征角度入手,发现天然绿松石与电化学处理绿松石在高压区域吸附曲线特征、50 nm孔径以上孔隙分布曲线、孔隙充填情况和内部结构等方面存在明显差异。通过检测绿松石的钾(K)含量,并结合孔隙特征差异,可以有效地对绿松石是否经过电化学处理进行检验判定。     

肺脂肪栓塞综合征的X线及螺旋CT诊断

目的:探讨肺脂肪栓塞综合征的X线及CT特点。方法:回顾性分析8例被诊断为肺脂肪栓塞患者的影像资料,由两位放射科医师对患者的胸部X线片及多层螺旋CT图像进行评价。结果:行X线片扫描5例表现为双肺弥漫性分布的片状密度增高影,2例表现为双肺中下野分布为主的片状阴影,1例仅表现为肺纹理增强。行CT检查5例表现为磨玻璃样改变(3例弥漫性分布、1例呈“地图样”片状分布、1例合并肺小叶间膈增厚呈现网状阴影),3例表现为多发实变影或结节影,2例合并有双侧胸腔积液。结论:X线平片仍是诊断肺脂肪栓塞比较可靠的影像学检查方法,螺旋CT能够提供更多特征性的影像信息。     

主动脉夹层撕裂内膜走行规律在真假腔识别中的应用

目的：探讨主动脉夹层（AD）撕裂内膜走行规律在AD真假腔识别中的临床价值。方法：回顾性分析63例AD患者的MSCTA资料,在降主动脉不同节段轴位图像上测量夹层动脉撕裂内膜与管壁两个结合点的角度,计算真腔所处夹角角平分线（TLIAB）的角度以确定其所在象限,观测在血管不同节段、不同象限内TLIAB的数量。结果：63例夹层患者降主动脉不同节段所得TLIAB最多为126层,不同节段间TLIAB数量的差异有统计学意义（χ²=63.87,P<0.05）。相同节段、不同AD类型间TLIAB数量的差异无统计学意义。TLIAB在右前象限最多,以主动脉弓降部最明显,主动脉弓降部位于右前象限和左前象限的管腔88.89%为真腔。结论：根据主动脉夹层撕裂内膜走行规律识别真假腔是一种简便、快速、有效的方法。     

Pressure-induced dehydration of dioptase: A single-crystal X-ray diffraction and Raman spectroscopy study

We present a synchrotron-based, single-crystal X-ray diffraction and Raman spectroscopy study of natural green dioptase (Cu₆Si₆O₁₈·6H₂O) up to ∼30 GPa at room temperature. The lattice parameters of dioptase exhibit continuous compression behavior up to ∼14.5 GPa, whereupon a structural transition is observed. Pressure–volume data below 14.5 GPa were fitted to a second-order Birch–Murnaghan equation of state with V₀ = 1440(2) ų and K₀ = 107(2) GPa, with K₀′ = 4(fixed). The low-pressure form of dioptase exhibits anisotropic compression with axial compressibility β_a > β_c in a ratio of 1.14:1.00. Based on the diffraction data and Raman spectroscopy, the new high-pressure phase could be regarded as a dehydrated form of dioptase in the same symmetry group. Pressure-induced dehydration of dioptase contributes broadly to our understanding of the high-pressure crystal chemistry of hydrous silicates containing molecular water groups.     

宁镇地区下志留统高家边组富有机质页岩孔隙结构

通过氩离子抛光-场发射扫描电镜、小角X射线散射及低温氮气吸附实验,对宁镇地区下志留统仑山5井等高家边组底部富有机质泥页岩孔隙结构进行分析,为下扬子区下志留统富有机质泥页岩的储层评价提供依据。研究表明:高家边组富有机质泥页岩含有大量的纳米级孔隙,包括有机质孔、矿物粒间孔、矿物粒内孔、微裂缝等,孔径分布复杂;优势孔径分布为介孔段,孔隙直径主要为2~50 nm。影响孔径分布的主要因素是矿物组成,脆性矿物和黏土矿物对微孔和介孔都有一定的影响,而有机质含量对泥页岩总体孔隙特征的影响并不明显。     

成人多发胆管错构瘤的CT和MRI诊断?

目的：探讨成人多发胆管错构瘤的CT、MRI特点,以提高对该病的影像认识及诊断水平。方法：回顾性分析12例经穿刺活检病理证实的成人多发胆管错构瘤的临床及影像资料,总结其影像学特征。结果：胆管错构瘤的CT平扫表现为肝实质多发低密度灶,弥漫或散在分布,境界模糊,形态多样,病灶直径多小于15 mm,增强扫描无明显强化;MRI扫描T1WI序列病变信号低于正常肝实质,T2WI序列病灶显示更清晰,呈明显高信号,病变数量多于CT和T1WI平扫,增强扫描多数病灶无强化,少量病灶呈结节状或轻度环状强化;磁共振胰胆管造影（MRCP）图像显示肝内多发类囊状高信号灶,沿胆管树分布,与胆管树不相通。结论：成人多发胆管错构瘤的CT、MRI具备一定特征性,但仍需与Caroli病、肝脏囊性转移瘤、多发肝囊肿、多囊肝等肝脏囊性病变鉴别。     

南海海域珊瑚礁元素分析试验

由于珊瑚礁属于生物矿物,其组成成分并不固定,因此珊瑚礁成分变化往往对当地生态和矿产有一定的指示作用,其元素分析对于珊瑚礁生态修复和海底探矿等具有重要作用。文中样品采自中国南海珊瑚岛礁,采用能量色散X射线荧光光谱分析了南海海域的珊瑚礁样品,确定其无机成分除Ca外也包括Al,Fe,Sr等元素,其钙质含量占绝大多数,为97%左右,其次Sr的含量占2.25%～2.75%左右,S占比0.31%～0.40%,Al占比0.04%～0.13%,Fe占比0.08%～0.23%,剩余为其他元素。同时,分析了不同区域所取样品的元素组成,发现其中一处所取样品存在Co元素。本次实验对于全面认识南海地区珊瑚礁的组成与南海海底矿藏指示具有实际意义。     

on the role of nonthermal electrons in EUV and X-ray line emissions from solar flares

The energy and angular distribution of electrons as a function of column densities initially for monoenergetic and monodirectional electron beams and incidence angles of 0‡, 30‡ and 60‡ have been studied by combining small angle scattering using analytical treatment with large angle collisions using Monte Carlo calculations. Using these distributions, X-ray and EUV-line flux have been studied as a function of column density. It is observed that the line flux increases with the increase in column density, becoming significant at intermediate column densities where the electron energies and angular distributions have a non-Maxwellian nature.     

Pressure–volume–temperature equation of state of andradite and grossular, by high-pressure and -temperature powder diffraction

 The thermoelastic parameters of natural andradite and grossular have been investigated by high-pressure and -temperature synchrotron X-ray powder diffraction, at ESRF, on the ID30 beamline. The P–V–T data have been fitted by Birch-Murnaghan-like EOSs, using both the approximated and the general form. We have obtained for andradite K ₀=158.0(±1.5) GPa, (dK/dT )₀=−0.020(3) GPa K⁻¹ and α₀=31.6(2) 10⁻⁶ K⁻¹, and for grossular K ₀=168.2(±1.7) GPa, (dK/dT)₀=−0.016(3) GPa K⁻¹ and α₀=27.8(2) 10⁻⁶ K⁻¹. Comparisons between the present issues and thermoelastic properties of garnets earlier determined are carried out. Received: 7 July 2000 / Accepted: 20 October 2000