Tests for individual Sulfate－Containing Particles in Urban Atmosphere in Beijing

Thin film methods and X ray energy dispersive technique were applied to analyze sulfate-containing particles in Beijing in order to examine their features and sources. Atmospheric aerosol particles were collected on electron mi-croscope meshes according to two size ranges: coarse particles (r>0.5μm) and fine particles (0.5μm≥r≥0.1μm) by using a two-stage impactor. It was found fiat more than seventy percent of the fine particles and about twenty percent of the coarse particles were sulfate-containing particles. These particles were formed mainly through heterogeneous nucleation. The element composition analyses revealed that the atmospheric aerosol particles in Beijing were domi-nated by crustal particles and construction dust.     

Electron Probe Microanalysis of Bromine in Minerals and Glasses with Correction for Spectral Interference from Aluminium,and Comparison with Microbeam Synchrotron X‐Ray Fluorescence Spectrometry

The strong spectral interference between Br‐ and Al‐induced X‐ray lines hampers the utilisation of electron probe microanalysis (EPMA) for measuring Br mass fractions in Al‐bearing minerals and glasses. Through measuring Br‐free Al‐bearing materials, we established an EPMA method to quantify the overlap from AlKα on BrLβ, which can be expressed as a linear function of the Al₂O₃ content. The count rate of the BrLβ peak signal was enhanced by high beam currents and long measurement times. Application of this EPMA method to Al‐ and Br‐bearing materials, such as sodalite and scapolite, and to five experimental glasses yielded Br mass fractions (in the range of 250–4000 μg g^?1) that are consistent with those measured by microbeam synchrotron X‐ray fluorescence (μ‐SXRF) spectrometry. The EPMA method has an estimated detection limit of ~ 100–300 μg g^?1. We propose that this method is useful for measuring Br mass fractions (hundreds to thousands of μg g^?1) in Al‐bearing minerals and glasses, including those produced in Br‐doped experiments. In addition, the natural marialitic scapolite (ON70) from Mpwapwa (Tanzania) containing homogeneously distributed high mass fractions of Br (2058 ± 56 μg g^?1) and Cl (1.98 ± 0.03% m/m) is an ideal reference material for future in situ analyses.     

CygX—1硬态高能光子的时延

硬X射线和软射线光子的时延时研究主能辐射的一个重要方面，傅里叶交叉谱常常被用于教育处硬软光子之间的时延，但是交叉说示能在高于30Hz的傅里叶频率上从CygX-1测量到有统计意义的快速光变，由李惕培在时域上发展的交叉相关函方法能有效测量不同时间尺度上的时延，利用此交叉相关分析方法，讨论了不同观测时期CygX-1硬态高能光子时延 的性质，分析结果表明，CygX-1硬态在短的尺度（＜0．1秒）上存存在有意义的时间延迟，并将短时间尺度上的观测结果和各种CygX-1硬态模型进行了比较讨论。     

Comprehensive study of the drying behavior of Boom clay: Experimental investigation and numerical modeling

This paper presents a thermo‐hydro‐mechanical framework to model the drying behavior of Boom clay. First, the experimental campaign conducted Noémie Prime is briefly presented because it is used to validate the model. The data acquisition and processing is emphasized because of the use of X‐ray microtomography to be able to more accurately compare experimental and numerical strain fields. The different submodels are introduced. Numerical simulations are performed to illustrate the capability of the proposed model to reproduce the observed behavior. Finally, a comprehensive sensitivity study on several key model parameters associated with the water retention curve, and the permeability of the medium, is performed to get a better understanding of the physics behind the coupled model.     

Centrifuge model tests on sand specimen under extensional load

The appearance of shear banding in granular materials has been investigated intensively during the last decades and is still of ongoing importance in terms of understanding the stress–strain behaviour of the material, the localization phenomena and the interaction between soil and structure. Only less attention has been paid to the occurrence of systems of shear bands although such systems can be identified in geotechnical structures as well as in geological formations. In this paper we present results of experiments on sand specimens under extensional load in natural gravity as well as in increased gravity in the centrifuge where the influence of the stress level on the geometry of a shear band pattern, specified by the spacing of the shear bands and the angle between failure surfaces and minor stress direction, has been investigated. X‐ray technique has been used to visualize the failure zones inside the specimen, an optical measurement system called Digital Image Correlation has been applied to identify and observe the appearing deformation mechanism on the sides of the specimens in natural gravity as well as during the flight in the centrifuge. It can be shown that the geometry of the shear band pattern is sparsely influenced by the change of the stress level. Copyright © 2004 John Wiley & Sons, Ltd.     

A comparison of grain‐size analysis methods for sand‐dominated fluvial sediments

Grain‐size distribution is a fundamental tool for interpreting sedimentary units within depositional systems. The techniques assessed in this study are commonly used to determine grain‐size distributions for sand‐dominated sediments. However, the degree of consistency and differences in interpretation when using a combination of grain‐size methods have not yet been assessed systematically for sand‐dominated fluvial sediments. Results obtained from laser diffraction, X‐ray attenuation and scanning electron microscopy grain‐size analysis techniques were compared with those obtained from the traditional sieve/hydrometer method. Scanning electron microscopy was shown to provide an inaccurate quantitative analysis of grain‐size distributions because of difficulties in obtaining representative samples for examination. The X‐ray attenuation method is unsuitable for sand‐dominated sediments because of its upper size range of only 300 μm. The consistently strong correlation between the laser diffraction results and the sieve/hydrometer results shows that these methods are comparable for sand‐dominated fluvial sediments. Provided that sample preparation is consistent, the latter two methods can be used together within a study of such sediments while maintaining a high degree of accuracy. These results indicate that data for sand‐dominated fluvial sediments gained from the long‐established sieve/hydrometer method can be compared with confidence to those obtained by modern studies using laser diffraction techniques.     

A Ring Model for Limit Analysis of Spatial XX Tubular Joints

-A ring model is developed to investigate the ultimate strength of tubular X and XX joints in the case that the brace is compressed. In the present analysis, the tubular joint is made of elasto-perfectly-plastic material, and the arch element of the chord section intersecting with the brace is assumed to be rigid. It is found that when 6 plastic hinges for X joint and 8 plastic hinges Tor XX joint appear in the ring, the limit state is reached, and by means of the equivalent ring width Be formula proposed in a previous paper by the authors, the ultimate strength of tubular X and XX joints subjected to compression can be obtained.     

Textural properties vs. CEC and EGME retention of Na–X zeolite prepared from fly ash at room temperature

Zeolite Na–X (FAU type) was synthesized from F-class fly ash in simple and economical way. Several months of storage of fly ash in NaOH solution, at room temperature, without any prior treatment, results in the production of material with ca. 50% content of Na–X zeolite. The most efficient reaction takes place at (OH)⁻ activity of 0.1–0.15 mol (OH)⁻/g of ash and at S/L ratio of 33 to 67 g/dm³. Higher S/L value causes an accelerating dissolution–crystallization equilibrium attainment. Cl⁻ ion acts as the inhibitor of this reaction.     

X‐ray energy spectra of CAL87

We present X‐ray spectral analysis of the super‐soft source CAL87 using ASCA, Chandra, XMM‐Newton observations. Early ASCA CCD spectrum reported a strong oxygen absorption edge, which is considered to originate in the an optically thick white‐dwarf atmosphere. On the other hand, contemporaneous grating observations by Chandra and XMM‐Newton indicate emission line dominated spectra, which obviously indicate the optically thin origin. Fitting all the available CCD (ASCA and XMM‐Newton) and grating spectra (XMM‐Newton and Chandra) simultaneously, we show that the CAL87 X‐ray energy spectrum is in fact composed of both an optically thick component with deep absorption edges and an optically thin component with numerous emission lines. The current result supports the standard SSS model that the primary source of X‐ray emission is nuclear burning in the white dwarf atmosphere, surrounded by a highly photoionised, optically thin corona (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

江河源区生态环境范围的探讨

The Tibetan Plateau, as the origin of the Yangtze and Yellow rivers, is the region of climate variation and is very sensitive to climate change in China (Feng etal., 1998). The runoff in the upper reaches of the Yellow River has been decreasing at a rate of 9.8 m3/s per decade due to rapid climate warming in the Tibetan Plateau since the mid- and late 1980s (Zhang etal., 2000). Eco-environmental change is also extremely substantial in the source regions of the Yangtze and Yellow rivers. T…