大试管回流消解-等离子体发射光谱／质谱法测定植物样品中多元素

采用大试管和红外加热的多孔控温消解炉的简单装置消解植物样品，电感耦合等离子体发射光谱／质谱法测定其中的主量和痕量元素，对消解温度、消解时间、消解溶剂、样品取样量等条件进行考察。用植物国家一级标准物质进行前处理及测定，验证方法的可行性，测定值与标准值基本吻合。方法不仅能同时测定B、Ba、Ca、Cd、Cu、K、Mg、Mn、Na、Ni、P、S、Zn、CoSr、Pb、Cr等元素，还适用于Hg、As挥发性元素的消解测定。方法的精密度（RSD，n=10）≤10％。     

The Alleret maar (Massif Central, France): A new lacustrine sequence of the early Middle Pleistocene in western Europe

The Alleret maar (Massif Central, France) provides a long lacustrine sequence (40.6 m) attributed to the early Middle Pleistocene. Sediment, pollen and diatoms analysis of its upper part (AL2 core, 14.6 m) indicates two temperate phases marked by high lake levels, forest development and vegetation expansion. They are separated by a cold period during which lake level drops, coarse sediment input increases and steppic and xerophilous plants develop. Pollen data suggests that this sequence belongs to the upper part of the Cromerian complex. These results are in agreement with the 557 ± 3 ka (±12 ka, including all errors) ⁴⁰Ar/³⁹Ar age obtained from an interbedded tephra layer emitted by the Mont-Dore/Sancy strato-volcano and establish that this sequence probably covers the MIS 15 substages.     

Spectrophotometry of the planetary nebula KjPn 8

Flux-calibrated low-resolution spectra covering the optical wavelength range from 3400 to 7500 Å have been obtained over the central region and the surroundings of the extraordinary planetary nebula (PN) KjPn 8 (PNG 112.5-00.1). The spectrum from the core is of low excitation with T _e(N  II ) = 8000 K and n _e(S  II ) = 550 cm⁻³. KjPn 8 is found to be a Type I PN according to the original classification scheme of Peimbert & Torres-Peimbert, with enriched He/H and N/O ratios with respect to mean values for PN. Increased O/H, Ne/H and Ar/H ratios over those of average PN reflect the possible metal-rich environment from which the progenitor star formed, and also are similar to those found in the extreme Type I PN He 2-111. The N/H ratio is found to be only moderately high compared to the average PN and consequently, the large O abundance pulls the N/O ratio towards the lower limit of the criterion for Type I planetary nebulae (PNe) in this case. In addition, the spectra of some knots and faint regions in the KjPn 8 surroundings are presented, which show only a few spectral lines. Low electron densities ranging from 100 to 300 cm⁻³ have been derived in these outer regions.     

Analytical perspective on trace element species of interest in exploration

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.     

Characteristics of the Variation of Cross Fault Short-Baseline and Short-Range Leveling in Western Yunnan Earthquake Test Site Before Lijiang M_S7.0 Earthquake

Results of analysis of variation of cross fault short-baseline and short-range leveling in Western Yunnan Earthquake Test Site (WYETS), results show that among five observation stations of cross fault short-baseline and short-range leveling in WYETS before the Lijiang MS7.0 Earthquake occurred in February 1996 only Yongsheng observation station (epicentral distance 82 km) located at Chenghai fault shows great variation about one year before the earthquake. And the nearest observation station, Lijiang (epicentral distance 42 km); presents great coseismic variation, but does not show obvious anomalous variation before the earthquake. There are no significant variations related to the earthquake at the other three observation stations. Two methods are used in analysis of the observed data and some valuable results have been obtained.     

IMP 8 magnetosheath field comparisons with models

This study presents cross-sectional vector maps of the magnetic field derived from IMP 8 magnetometer in the magnetosheath at 30 R_e behind the Earth. In addition the vector patterns of the magnetosheath field for northward, southward, and east-west interplanetary magnetic field (IMF) directions are qualitatively compared with those obtained from the Spreiter-Stahara gas dynamic (GD) and Fedder-Lyon magnetohydrodynamic models (MHD). The main purpose is to display the cross-sectional differences in relation to the dayside merging with different IMF directions, allowing the reader to make direct visual comparisons of the vector patterns. It is seen that for east-west IMF directions, the data-based and MHD-based patterns differ noticeably in a similar way from the GD model, presumably reflecting the influence of dayside magnetic merging of the Earths magnetic field with the y-component of the interplanetary magnetic field. All three northward IMF cross sections show comparable field draping patterns as expected for a closed magnetosphere. For southward IMF case, on the other hand, differences between the three cross-sectional patterns are greater as seen in the field vector sizes and directions, especially closer to the magnetopause where more disturbed magneto-spheric conditions are known to be exist. The data comparisons with the MHD and GD models show that the differences result from the magnetic field-flow coupling and that the effects of dayside reconnection are present in IMP 8 magnetic field measurements.     

The globular cluster system of the Sagittarius dwarf spheroidal galaxy: the age of Terzan 8

We present deep V - and I -band CCD photometry of the globular cluster Terzan 8, recently found to be a member of the globular cluster system of the Sagittarius dwarf spheroidal galaxy. We accurately estimate the metallicity of Terzan 8, and provide the first direct determination of the colour excess toward this cluster. Our robust age estimate confirms that this cluster is indeed coeval with typical Galactic globulars of comparable metal content, and thus it is probably significantly older than at least two other Sagittarius clusters, Terzan 7 and Arp 2. The implications of this result on the star formation history of the Sagittarius galaxy are briefly discussed.     

Evolution of the near-infrared in rich galaxy clusters

We present the K -band (2.2 μm) luminosity functions (LFs) of the X-ray-luminous clusters MS1054–0321 ( z  = 0.823), MS0451–0305 ( z  = 0.55), Abell 963 ( z  = 0.206), Abell 665 ( z  = 0.182) and Abell 1795 ( z  = 0.063) down to absolute magnitudes M _K  = −20. Our measurements probe fainter absolute magnitudes than do any previous studies of the near-infrared LFs of clusters. All the clusters are found to have similar LFs within the errors, when the galaxy populations are evolved to redshift z  = 0. It is known that the most massive bound systems in the Universe at all redshifts are X-ray-luminous clusters. Therefore, assuming that the clusters in our sample correspond to a single population seen at different redshifts, the results here imply that not only had the stars in present-day ellipticals in rich clusters formed by z  = 0.8, but that they existed in as luminous galaxies then as they do today.   Additionally, the clusters have K -band LFs which appear to be consistent with the K -band field LF in the range −24 <  M _K  < −22, although the uncertainties in both the field and cluster samples are large.     

2021年5月云南漾濞MS 6.4地震序列发震构造及破裂过程初探

北京时间2021年5月21日21时48分36秒,云南省大理州漾濞县发生M_S 6.4地震。利用云南数字地震台网2021年5月18日至8月22日的震相报告,采用双差地震定位法,对漾濞M_S 6.4地震序列进行重新定位。重新定位结果显示序列呈NW向优势分布,破裂长约20 km,宽约7 km,对重新定位结果进行误差分析,水平方向定位误差约为0.8 km,垂直方向定位误差约为1.0 km,定位结果具有较好的稳定性。依据震中分布的走向将序列划分为NW向的主断层与NNW向的分支断层,主断层存在较为明显的分段现象,分支断层呈雁列状分布。根据小震丛集性发生在大震断层面及其附近的原则,利用重新定位后的小震震源位置反演得到漾濞M_S 6.4序列主断层走向约320°,倾角约89°,深度范围3～13 km。根据拟合得到的断层在地表的投影位置,推测本次地震的发震断层为维西-乔后断裂西侧的草坪断裂。基于断层滑动量分布识别出3个凹凸体,结合序列时空演化特征,分析了漾濞M_S 6.4地震序列的破裂过程,结果显示断层中段的凹凸体发生初始破裂...     

塔尔塔格铁矿床——新疆阿吾拉勒铁成矿带内首例IOA型铁矿床的厘定及意义

塔尔塔格铁矿是新疆西天山阿吾拉勒海相火山岩型铁成矿带内的一处中型铁矿床,其铁矿体呈透镜状产于粗安玢岩内顶部,在揭示海相火山岩中铁矿床与侵入岩关系方面具有重要意义。该铁矿床发育典型的磁铁矿 磷灰石组合,基本不含硫化物,矿石以似斑状、浸染状、球粒状和晶洞等构造类型为特色,磁铁矿内发育由条带状或叶片状钛铁矿和钛氧化物构成的出溶结构,并有少量的榍石、钍石、萤石等副矿物与之共生,矿床地质特征表明该矿床为典型的与富碱、中性侵入岩有关的IOA（iron oxide apatite）型铁矿床。该矿床围岩英安岩、赋矿粗安玢岩与成矿后正长花岗岩的锆石SHRIMP U Pb同位素加权平均年龄分别为311. 3±1. 4 Ma、304. 7±2. 9 Ma和301. 1±2. 8 Ma,铁矿石样品中与磁铁矿共生的榍石的LA ICP MS U Pb同位素加权平均年龄为302. 3±4. 0 Ma和303. 7±4. 2 Ma,成岩成矿年龄高度吻合,进一步确定其在晚石炭世晚期成矿。本文根据地质特征认为该矿床矿石是由粗安玢岩顶部富铁挥发分聚集而形成的,并初步提出“超浅成侵入岩顶部富挥发分囊体”成矿模型,即富碱、中性岩体超浅成侵位导致挥发分在岩体顶部迅速聚集形成多处富铁和挥发分的囊体,岩体冷凝固结的同时磁铁矿快速结晶成矿。塔尔塔格“IOA型”型铁矿的成因厘定,不仅表明海相火山岩型铁矿与IOA型铁矿可能存在成因联系,还暗示了海相火山岩型铁成矿带内具有寻找IOA型铁矿的潜力。