临震前地壳变形不动点现象与机制研究

在综合分析国内外地形变前兆研究现状的基础上,结合汶川8.0级地震前GPS、应变、重力等研究结果,提出临震前震源区域可能出现变形不动点现象。地壳变形过程中的不动点现象是临震前区域应力场进入临界状态的重要标志,是地震潜在危险区域划定的重要依据。借助不动点理论,给出汶川地震前变形不动点集合的演化,结合大区域地震活动空区与远场显著形变异常分布,探讨变形不动点现象发生的动力学背景,验证了汶川地震前地壳变形的不动点现象是大区域应力场有序运动的结果。     

基于光谱角匹配算法的水体信息提取研究

针对水体信息提取时,传统算法不能较好地解决山体阴影被误提为水体的问题,引入多用于高光谱数据处理的光谱角匹配算法,以Land-sat8 OLI(band1-band7)为数据源,以黄河小浪底水库周边区域为实验区,开展水体信息提取研究,结果显示:水体指数法和波段关系提取的结果中有大量的山体阴影信息,提取精度不超过30%,而光谱角匹配法提取结果受阴影的影响较小,提取精度在99%以上。     

Study of high temperature targets identification and temperature retrieval experimental model in SWIR remote sensing based Landsat8

For surface features in short-wave infrared (SWIR, 1.3–3.0 μm) in remote sensing imagery, pixel values depict the total energy including reflection and emission. For surface features at normal temperature in SWIR band, emission energy can be ignored. While for surface features at high temperature in SWIR band, emission energy is equal to or even higher than the reflection energy. So remote sensing imagery of SWIR band can be used to separate emission and reflection energy as well as to realize temperature retrieval of high temperature targets. In this study, the seventh band (SWIR band) of Landsat8 OLI remote sensing imagery is used to perform the theoretical model research for temperature retrieval of high temperature targets. In the meantime, it is also used with the corresponding observation experiment of synchronization satellite to check the theoretical model. The result shows that the radiant flux density for mixed pixels with high temperature targets is higher than adjacent pixels without high temperature targets. Thus, the high temperature pixels can be identified in SWIR band. The retrieval results of temperature and fractional area for high temperature targets are consistent with reality. In the study, the result illustrates that it is effective to identify high temperature targets in remote sensing imagery of SWIR band and the model is appropriate for temperature retrieval use.     

太原市地表热环境时空格局分析

针对鲜有资源型城市的地表热环境研究这一情况,该文基于Landsat8遥感数据,反演了太原市在2013—2015年间共3期的地表温度。提出一个考虑空间格局结构的城市热岛效应指数,在3期数据中,太原市区整体热岛效应指数分别为9.1%、9.8%和8.9%;同时,根据城市功能和路网结构将太原市区划分为6个分区,从分区级层面量化分析了地表热环境的时空分异特征规律,结果表明,太原市区地表温度整体呈现空间分散化特征,不同分区也呈现出不同的时空格局演变过程;最后,选取40个地表温度实测样本点验证反演精度,最大误差绝对值为1.1℃,最小误差绝对值为0.2℃,均方根误差为0.7℃。     

Landsat 8热红外数据定标参数的变化及其对地表温度反演的影响

Landsat系列卫星上的TIRS热红外传感器数据已被大量应用,针对TIRS数据的地表温度反演也相继开发出一些算法,并有一些研究对TIRS数据的定标及其地表温度反演算法的精度进行了对比。本文主要就TIRS热红外传感器定标参数的变化,结合这些定标参数变化的时间点对有关地表温度反演算法的适用性和有效性进行分析,特别是对劈窗算法是否适合当前的TIRS数据进行了讨论,以使用户能够对Landsat 8 TIRS热红外数据的正确使用有进一步的认识。总的看来,由于视域外杂散光的影响,TIRS数据的定标精度仍达不到设计目标,TIRS第11波段的不确定性仍成倍大于TIRS 10波段。因此,在Landsat团队未彻底解决这一问题之前,同时用TIRS第10、第11这两个差距较大的波段构成的劈窗算法来反演地表温度,其精度存在较大的不确定性,US6-S团队仍在致力于改进第11波段的精度,改进后的波段可以用劈窗策法。目前应以TIRS第10单波段的方式来反演地表温度为宜。     

Quantification of LST and CO2 levels using Landsat-8 thermal bands on urban environment

Land surface temperature (LST) is an important aspect in global to regional change studies, for control of climate change and balancing of high temperature. Urbanization is one of the influencing factors increasing land surface and atmospheric temperature, by the emission of greenhouse gases (e.g. CO₂, NO and methane). In the present study, LST was derived from Landsat-8 of multitemporal data sets to analyse the spatial structure of the urban thermal environment in relation to the urban surface characteristics and land use–land cover (LULC). LST is influenced by the greenhouse gases i.e. CO₂ plays an important role in increasing the earth’s surface temperature. In order to provide the evidence of influence of CO₂ on LST, the relationship between LST, air temperature and CO₂ was analysed. Landsat-8 satellite has two thermal bands, 10 and 11. These bands were used to accurately to calculate the temperature over the study area. Results showed that the strength of correlation between ground monitoring data and satellite data was high. Based on correlation values of each month April (R² = 0.994), May (R² = 0.297) and June (R² = 0.934), observed results show that band 10 was significantly correlating with air temperature. Relationship between LST and CO₂ levels were obtained from linear regression analysis. band 11 was correlating significantly with CO₂ values in each of the months April (R² = 0.217), May (R² = 0.914) and June, (R² = 0.934), because band 11 is closer to the 15-micron band of CO₂. From the results, it was observed that band 10 can be used for calculating air temperature and band 11 can be used for estimation of greenhouse gases.     

汶川地震断裂带多次地震活动新证据

虹口乡八角庙出露完整的映秀—北川断裂带剖面断层岩,高分辨率磁化率测试揭示出多个具有高磁化率特征的断层岩带。系统的岩石磁学分析证明一层褐色断层岩相对围岩具有最大的磁化率值,存在新生成的磁铁矿和拥有相似的天然剩磁(NRM)和非磁滞剩磁(ARM)强度衰减过程。高磁化率特征是含铁顺磁性矿物受到断层滑移过程产生摩擦生热作用生成磁铁矿所致。同时断层岩还获得了热剩磁,记录了地震活动磁学信息。结合汶川地震科学钻探项目1号孔(WFSD-1)磁化率和岩石磁学研究结果,说明映秀—北川断裂带包含多层具有高磁化率特征的断层岩,暗示了多次强震的发生。具有高磁化率特征的断层岩可以作为判定地震活动的标志之一。     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

Production and Certification of Synthetic Selenium Isotopic Reference Materials

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.