乙醇增强—电感耦合等离子体质谱法直接测定地质样品中碲

建立了HF—HN03密封酸溶以及Na2O2熔融处理样品，乙醇增强灵敏度，电感耦合等离子体质谱直接测定地质样品中微量和超痕量碲的方法。样品溶液中加入乙醇(φ＝4％)，在0．85L/min的载气流速下，碲信号可增强2．5倍以上。碲的方法检出限(100，DF＝1000)为0．02μg/g。用土壤和水系沉积物国家一级标准物质验证了方法的准确度，标准物质的绝大多数分析结果与标准值的误差在允许范围内。分析了大洋多金属结核样品及深海沉积物样品中的微量碲，结果与其他方法相符，精密度试验RSD(n＝3)＜10％。     

湖北黄土岭麻粒岩锆石拉曼光谱和等离子体质谱研究

对湖北黄土岭麻粒岩中锆石同时进行了激光拉曼探针、阴极发光 (CL)观察和U ,Th及Pb Pb年龄ICPMS测定 ,发现麻粒岩中部分锆石发生的不是固态重结晶作用 ,而是部分熔蚀 /沉淀再结晶过程。结合CL图像结构特征和2 0 7Pb/ 2 0 6Pb年龄初步推断 ,麻粒岩相事件发生在 2 0亿年之后。结构、化学和同位素组成的测定表明 ,大别地区广泛存在的燕山期热事件使锆石发生不同程度的变质重结晶作用 ,使锆石晶格愈合。     

电感耦合等离子体质谱(ICP-MS)技术在地学研究中的应用

简单介绍ICP MS技术应用最新进展。着重对该技术在中国地学研究和多目标地质调查中的应用作一回顾 ,包括ICP MS技术简介和地质样品分析需求 ,稀土稀散等痕量、超痕量多元素分析 ,铂族元素分析 ,卤素等非金属元素分析 ,同位素比值分析等内容。着重对最近几年国内地质样品分析的一些新方法加以介绍。     

中国大陆西部及邻区板内8级大地震活动过程和趋势预测初步研究

中国大陆西部及邻区是全球 8级大地震最为活跃的地区之一。自 180 0年以来该区板内 8级大地震共发生了 16次 ,2 0 0 1年昆仑山口西 8.1级大地震 (36 .1°N ,90 .9°E)是在 195 7年蒙古 8.3级大地震之后 4 4a发生的。研究表明该区 8级大地震的活动过程可能存在相对平静 (1812— 190 2年 )和相对活跃 (190 3— 195 7年 )交替的幕式或轮回过程的性质。 195 7年蒙古地震之后可能是一次新的轮回开始 ,2 0 0 1年昆仑山口西地震是新轮回的第二次地震 ,按照轮回过程中事件发生频度是时间的指数函数关系的假定 ,该区下一次 8级大地震可能约在 2 0 2 6年发生。如果假定该过程相当接近泊松过程。那么 ,在 2 0 0 5 ,2 0 10年和 2 0 15年前至少发生一次 8级大地震的泊松概率 ,分别是 0 .2 9,0 .5 3和 0 .70。     

Seismicity anomalies before the great earthquake of M_S=8.1 in the Kunlun Pass and its significance to earthquake prediction

Introduction The MS=8.1 earthquake occurred in west of the Kunlun Pass on November 14, 2001. It is the greatest earthquake occurred in China since the last half of the century and is an important event in recent seismic history of China. Some specialists consider that the earthquake occurred in the area where the earthquake monitoring capability is lowest in Chinese mainland; no striking precursory seismicity was found. The study on the precursory seismicity before the earthquake has not b…     

Rivers, chemical weathering and Earth's climate

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).     

昆仑山口西8.1级地震前青藏块体边界断层异常活动

系统分析了青藏块体边界断层的形变资料，研究了断层活动的动态过程及空间分布。结果表明，昆仑山口西8．1级地震前孕震影响范围达到青藏块体的周边地区；发震断层所在的构造带震前断层活动最为剧烈；加强对构造块体断层整体活动的宏观动态比较和分析，有助于判定未来强震发生的危险地段；震后应力将转移并集中到西秦岭构造带及其邻近地区。     

2001年11月14日昆仑山口西8.1级地震前地震活动性异常及其思考s

2001年11月14日在昆仑山口西发生了8.1级地震，震中位置为90.9E、36.2N．分析表明，8.1级地震前一些主要地震活动性异常都出现了，例如空区、条带、增强、平静和震群等，且与7级大震比较，这些前兆图象的演变具有类似的过程，所不同的是8.1级地震的前兆地震活动图象涉及的区域范围更大、地震震级更高，这为特大地震的前兆识别和预报提供了依据．最后回顾了对这次大震的粗略预测，并讨论了有关大震预测的某些问题．      

Comparison of source rock geochemistry of selected rocks from the Schei Point group and Ringnes formation, Sverdrup basin, arctic Canada

Organic-rich from the Schei Point group (middle to late Triassic in age) and the Ringnes formation (late Jurassic) from the Sverdrup basin of the Canadian arctic archipelago have been geochemically evaluated for source rock characterization. Most samples from the Schei Point group are organic-rich (> 2% TOC and are considered as immature to mature oil-prone source rocks [kerogen types I, I–II (IIA) and II (IIA)]. These kerogen types contain abundant AOM1, AOM2 and alginite (Tasmanales, Nostocopsis, Leiosphaeridia, acritarch and dinoflagellate) with variable amounts of vitrinite, inertinite and exinite. Samples from the Ringnes formation contain dominant vitrinite and inertinite with partially oxidized AOM2, alginite and exinite forming mostly immature to mature condensate- and gas-prone source rocks [kerogen type II–III (IIB), III and a few II (IIA)]. Schei Point samples contain higher bitumen extract, saturate hydrocarbons and saturate/ aromatic ratio than the Ringnes samples. Triterpane and sterane (dominant C₃₀) distribution patterns and stable carbon isotope of bitumen and kerogen suggest that the analyzed samples from the Schei Point group are at the onset of oil generation and contain a mixture of sapropelic (algal) and minor terrestrial humic organic matter. Sterane carbon number distributions in the Ringnes formation also suggest a mixed algal and terrestrial organic matter type. There are some variations in hopane carbon number distributions, but these are apparently a function of thermal maturity rather than significant genetic differences among samples. Pyrolysis-gas chromatography/mass spectrometry of the two samples with similar maturity shows that the Schei Point sample generates three times more pyrolyzate than the Ringnes sample. Both samples have a dominant aliphatic character, although the Ringnes sample contains phenol and an aromaticity that is higher than that of the Schei Point sample.     

铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究

在０３０ｍｏｌ／ＬＨＡｃ介质中，Ｐｂ（Ⅱ）与７＿碘＿８＿羟基喹啉＿５＿磺酸（试铁灵，Ｆｅｒｏｎ）的络合物于－０５４Ｖ（ｖｓ．ＳＣＥ）产生一尖锐的极谱波，加入溴化十六烷基三甲基铵（ＣＴＭＡＢ）显著增敏，可使极谱波增高约４倍。峰电流与Ｐｂ（Ⅱ）浓度在９６×１０－９～４８×１０－６ｍｏｌ／Ｌ呈良好的线性关系，检出限为４８×１０－９ｍｏｌ／Ｌ。用多种电化学方法研究了该极谱波的性质及电极反应机理表明，络合物组成比为ｎＰｂ（Ⅱ）∶ｎＦｅｒｏｎ＝１∶１，极谱波为吸附波，峰电流由中心离子Ｐｂ（Ⅱ）还原产生，电子转移数为２。试验了多种离子对峰电流的影响，拟定的方法用于矿样分析，结果与原结果相符。