岩石中铅和锌的分离与测定

以KHSO4作为沉淀济加入到小体积(1 mL)试液中,以K2SO4.PbSO4复盐形式沉淀分离Pb,用NaAc-HAc溶液热提取Pb,1 mg Pb的平均回收率为100.66%;滤液再蒸至1 mL小体积,NaCl-NaOH小体积两次沉淀分离Fe、Ti、Mn等干扰元素,存在于滤液中的Zn平均回收率为100.5%。分离所得的含Pb2 和Zn2 的溶液用EDTA分别进行滴定,测定下限由0.5%降至0.01%;测定结果与极谱法、原子吸收法相一致;方法的精密度(RSD,n=10)试验Pb为2.6%,Zn为1.4%。     

基于小波包变换的面波分离技术研究

依据面波视速度的分布范围,提出一种新的叠前面波分离技术,即把地震波场分成不受面波影响的波场和受面波影响的波场,然后利用小波包变换对受面波影响的波场进行时频分析,通过分解与重构,从中提取有效波,再将其与不受面波影响的波场合并,就可得到面波分离后的地震波场。该方法在成功分离面波的同时,可使有效波的能量(尤其是其低频能量)不受损失,既有效地保持信号的频宽不变,又提高了记录的信噪比。实际资料的处理结果表明:此方法在叠前面波分离方面具有有良好的效果。     

Extraction of rhyolitic component of Vedde microtephra from minerogenic lake sediments

A technique is described for the extraction of rhyolitic microtephra from inorganic Lateglacial lake sediments. This technique was successfully applied by Lowe and Turney (1996) and is an adaption of the method described by Pilcher & Hall (1992) for application to Holocene peat deposits. It uses a density separation procedure to concentrate any microtephra component in lake sediments and was applied to the investigation of a lake sediment succession from a small basin in NE Scotland. Using this approach is was possible to define quantitatively for the first time the presence of the Vedde Ash tephra layer on the British Isles.     

贵金属资源的应用及开发

将贵金属的应用,资源分布,生产和贵金属的分析化学结合在一起进行了综述,由于贵金属资源的短缺性及考虑可持续发展战略,特别介绍了贵金属资源的二次回收问题,并对其将来的发展作了一定的评价和展望。     

A Spectrum-Independent Procedure for Correcting Eddy Fluxes Measured with Separated Sensors

We investigate flux underestimates in eddy correlation measurements that are caused by horizontal separation of the sensors. A common eddy correlation setup consists of a sonic anemometer and a humidity sensor which, because of its bulk, must be placed some distance away from the sonic path, leading to a flux loss (of latent heat). Utilizing an additional fast temperature sensor placed near the humidity sensor, we develop a procedure for correcting for this loss. The procedure simultaneously corrects the sensible heat flux for the difference between true temperature and sonic temperature. Our correction procedure, which does not depend on the shape of the cospectrum, is then compared to the widely-used procedure following Moore (1986), which assumes a cospectral model ('Kansas Model). Both correction methods are applied to data collected within the internal boundary layer over a rice paddy, downwind of arid land. Under conditions of good fetch, they were found to agree well. Under poor fetch conditions, the model-based correction tended to be too small, while the spectrum-independent combined correction was robust. The latter is thus recommended for situations where the cospectral shape can be expected to deviate from the 'Kansas shape.     

On the galactic motion

A certain potential function is studied as a possible model for the galactic potential. Some solutions are obtained. Also the numerical study of some of the orbits and their stability is carried out.     

Salinograph trends as indicators of the recession characteristics of stream components

Compared to hydrograph recession analysis, which is widely applied in engineering hydrology, the quantitative assessment of stream salinity with time (i.e. the salinograph) has received significantly less attention. In particular, while in many previous hydrological studies an inverse relationship between hydrograph and salinograph responses is apparent, the concept of salinity accession (the inversely related salinity counterpart to hydrograph recession) has not been introduced nor quantitatively evaluated in previous literature. In this study, we conduct a mathematical analysis of salinograph accession, and determine new quantitative relationships between salinity accession and hydrograph recession parameters. An equation is formulated that reproduces the general trend in salinity accession. A salinity accession parameter k_c is then introduced and is shown to be the ratio of direct runoff to total stream flow recession parameters: k_r/k. The groundwater recession parameter k_g was estimated using a simple and rapid method that uses both salinograph and hydrograph data. Salinity accession type‐curves illustrate that under certain conditions, the relative steepness of individual salinographs is dependent upon the ratio of groundwater salinity to direct runoff salinity: C_g/C_r. The salinity accession algorithms are applied to two contrasting field settings: Scott Creek, South Australia and Sandy Creek, northern Queensland, Australia. It was found that k_g > k during periods of obvious stream flow recession, for the events analysed. Salinograph accession behaviour was fairly similar for both sites, despite contrasting environments. Using assumed end‐member salinities for groundwater and direct runoff based upon field observations, the behaviour of k_c from the Scott Creek site was approximately reproduced by varying the initial groundwater to runoff flow ratio: Q_g0/Q_r0, within reasonable parameter ranges. The use of salinograph information when used in addition to standard hydrograph analyses provided useful information on recession characteristics of stream components. Copyright © 2008 John Wiley & Sons, Ltd.     

Impact of wildfire on source water contributions in Devil Creek,CA: evidence from end‐member mixing analysis

A geochemical and end‐member mixing analysis (EMMA) is undertaken in Devil Canyon catchment, located in southern California, to further understanding of watershed behaviour and source water contributions after an acute and extensive wildfire. Physical and chemical transformations in post‐fire watersheds are known to increase overland flow and decrease infiltration, mainly due to formation of a hydrophobic layer at, or near, the soil surface. However, less is known about subsurface flow response in burned watersheds. The current study incorporates EMMA to evaluate and quantify source water contributions before, and after, a catchment affected by wildfires in southern California during the fall of 2003. Pre‐ and post‐fire stream water data were available at several sampling sites within the catchment, allowing the identification of contributing water sources at varying spatial scales. Proposed end‐member observations (groundwater, overland flow, shallow subsurface flow) were also collected to constrain and develop the catchment mixing model. Post‐fire source water changes are more evident in the smaller and faster responding sub‐basin (interior sampling point). Early post‐fire storm events are dominated by overland flow with no significant soil water or groundwater flow contribution. Inter‐storm streamwater in this smaller basin shows an increase in groundwater and a decrease in soil water. In the larger, baseflow‐dominated system, source water components appear less affected by fire. A slight increase in lateral flow is observed with only a slight decrease in baseflow. Changes in the post‐fire flow regimes affect nutrient loading and chemical response of the basin. Relatively rapid recovery of the chaparral ecosystem is evidenced, with active re‐growth and evapotranspiration evidenced by the fourth post‐fire rainy season. Copyright © 2008 John Wiley & Sons, Ltd.     

气溶胶对雷暴云起电以及闪电发生率影响的数值模拟

本文利用二维耦合气溶胶模块的雷暴云起电模式,结合一次南京雷暴个例,进行250 m分辨率雷暴云起电模拟实验,探讨了气溶胶浓度对雷暴云空间电荷分布以及闪电发生率的影响。在这个气溶胶模块中,假定一个三模态的气溶胶对数分布,考虑了气溶胶活化过程。结果显示:(1)随着气溶胶浓度增大,雷暴云电荷结构保持为三极型。(2)当气溶胶浓度从50 cm-3增加至1000 cm-3时,水成物粒子浓度上升,雷暴云电荷量和闪电发生率增加明显。(3)气溶胶浓度在1000~3000 cm-3范围时,云水竞争限制了冰晶的增长,导致雷暴云上部主正电荷堆电荷量降低。云滴和霰粒子浓度缓慢上升促进中部主负电荷堆和底部次正电荷堆电荷量继续增大。闪电发生率保持稳定。(4)当气溶胶浓度大于3000 cm-3时,水成物粒子浓度稳定,云内的电荷量以及闪电发生率保持为一定量级。     

Impact of the Vertical Velocity Field on Charging Processes and Charge Separation in a Simulated Thunderstorm

A three-dimensional(3D) charging-discharging cloud resolution model was used to investigate the impact of the vertical velocity field on the charging processes and the formation of charge structure in a strong thunderstorm. The distribution and evolution of ice particle content and charges on ice particles were analyzed in different vertical velocity fields. The results show that the ice particles in the vertical velocity range from 1 to 5 m s-1obtained the most charge through charging processes during the lifetime of the thunderstorm. The magnitude of the charges could reach 1014 n C. Before the beginning of lightning activity,the charges produced in updraft region 2(updraft speed 13 m s-1) and updraft region 1(updraft speed between 5 and 13 m s-1) were relatively significant. The magnitudes of charge reached 1013 n C, which clearly impacted upon the early lightning activity. The vertical velocity conditions in the quasi-steady region(updraft speed between –1 and 1 m s-1) were the most conducive for charge separation on ice particles on different scales. Accordingly, a net charge structure always appeared in the quasi-steady and adjacent regions. Based on the results, a conceptual model of ice particle charging, charge separation, and charge structure formation in the flow field was constructed. The model helps to explain observations of the"lightning hole" phenomenon.