Percolation of diagenetic fluids in the Archaean basement of the Franceville basin

The Palaeoproterozoic Franceville basin, Gabon, is mainly known for its high-grade uranium deposits, which are the only ones known to act as natural nuclear fission reactors. Previous work in the Kiéné region investigated the nature of the fluids responsible for these natural nuclear reactors. The present work focuses on the top of the Archaean granitic basement, specifically, to identify and date the successive alteration events that affected this basement just below the unconformity separating it from the Palaeoproterozoic basin. Core from four drill holes crosscutting the basin–basement unconformity have been studied. Dating is based on U–Pb isotopic analyses performed on monazite. The origin of fluids is discussed from the study of fluid inclusion planes (FIP) in quartz from basement granitoids. From the deepest part of the drill holes to the unconformable boundary with the basin, propylitic alteration assemblages are progressively replaced by illite and locally by a phengite + Fe chlorite ± Fe oxide assemblage. Illitic alteration is particularly strong along the sediment–granitoid contact and is associated with quartz dissolution. It was followed by calcite and anhydrite precipitation as fracture fillings. U–Pb isotopic dating outlines three successive events: a 3.0–2.9-Ga primary magmatic event, a 2.6-Ga propylitic alteration and a late 1.9-Ga diagenetic event. Fluid inclusion microthermometry suggests the circulation of three types of fluids: (1) a Na–Ca-rich diagenetic brine, (2) a moderately saline (diagenetic + meteoric) fluid, and (3) a low-salinity fluid of probable meteoric origin. These fluids are similar to those previously identified within the overlying sedimentary rocks of the Franceville basin. Overall, the data collected in this study show that the Proterozoic–Archaean unconformity has operated as a major flow corridor for fluids circulation, around 1.9 Ga.     

Classical and quantum anisotropic wormholes in pure general relativity

In the homogeneous and isotropic Friedmann–Robertson–Walker minisuperspace model, it is known that there are no Euclidean wormhole solutions in the pure gravity system. Here it is demonstrated explicitly that in Taub cosmology, which is one of the simplest anisotropic cosmology models, wormhole solutions do exist in pure general relativity in both classical and quantum contexts. Indeed, it is realized that it is the nonvanishing momentum or the energy associated with the anisotropy change, that essentially renders the occurrence of both classical and quantum wormholes possible.     

A comparative analysis of some two-dimensional orderings

Abstract

Many spatial analysis algorithms for cellular representations and data structures are based on an ordering of cells or objects to transform a two-dimensional problem to a one-dimensional one. Several orderings are available and their differing properties influence the performance of the data structures and algorithms. The relative merits of five orderings (row, row prime, Hilbert, Morton and Gray code) are assessed empirically for four paradigmatic geographical data-processing tasks in spatial analysis and data management. It is concluded that the Hilbert ordering deserves further investigation.     

Space–time opportunities for multiple agents: a constraint‐based approach

Constraint‐based models and models constructing accessibility measures mainly focus on single agents having only one available transport mode. However, numerous cases exist where multiple agents or groups of individuals with different available transport modes want to participate in a joint activity at a certain location. The aim of this paper is to provide new insights into representing and reasoning about feasible space–time opportunities for multiple agents. Relying on concepts of time geography, we propose a conceptual framework in order to determine interaction spaces for groups of individuals. Besides availability of means of transport and the locations of each individual, minimum activity duration and opening hours of opportunities are taken into account. The reasoning about space and time is visualized in three dimensions using a hybrid (CAD/GIS) system.     

Choice set formation with multiple flexible activities under space–time constraints

In classical time geography, an individual travel path is composed of a chain of visits, with each visit being a flexible activity between two fixed activities at two known stations. In reality, individuals tend to carry out trips with much variation and complexity, with multipurpose trips being a prominent and pervasive phenomenon. There is limited research to date on multipurpose trips in time-geographic analysis by geographic information system (GIS) scientists, or more specifically, multiple flexible activities between two fixed stations. To fill this gap, this article proposes four models for identifying the choice set with multiple flexible activities under space–time constraints. The models are derived through set-theoretic formalism based on the concept of trip chaining. The structure of the four models establishes a theoretical framework for conceptualizing trip-chaining behaviour with respect to the fixity of activities and the number of fixed stations as destinations or origins. They provide fundamental and rigorous apparatus for studying complex individual activity–travel patterns in many applied contexts when multipurpose trips are involved. This article also describes implementation of the models with a real transportation network as a way of validation.     

Early Cambrian alkaline volcanism on the southern margin of Laurentia: evidence in the volcaniclastic units from the Puerto Blanco Formation in the Caborca block,NW Mexico

ABSTRACT

Volcaniclastic units are exposed at the base of the Puerto Blanco Formation in the Caborca region, northwestern Mexico. The lower unit reveals the presence of Early Cambrian mafic volcanism in this region. It consists of a volcano-sedimentary sequence represented by tuffaceous conglomerates, agglomerates, lapillistones, tuffs, and altered mafic volcanic flows. Petrographic analysis classified the volcanic clasts as albite-sphene-calcite-actinolite granofels, with a moderate to intense hydrothermal alteration, precisely characterized by EPMA analysis. Albite-actinolite geothermometry indicates temperatures from 400 to 500°C, suggesting metamorphic conditions in the upper temperature greenschist facies. Geochemistry analysis shows a high TiO₂ basic–ultrabasic volcanism that originated the volcanic clasts. Rock protoliths were studied using immobile trace elements, which classified them as OIB-type alkaline basalts with the characteristic spider hump-shaped pattern, situated in an anorogenic intracontinental tectonic setting with enriched mantle signatures. ⁴⁰Ar/³⁹Ar geochronology shows metamorphic ages of 52.58 ± 2.0 and 91.67 ± 0.55 Ma, consistent with the emplacement of Laramidic granitoids identified in the region. Possible correlations of this alkaline volcanism include the Southern Oklahoma Aulacogen and the late stages of the rifting of north western Laurentia represented in western United States.     

Geochemical fingerprint of hyaloclasts in glassy fragmental rocks of Macquarie Island (Southern Ocean): implications for volcanogenic sedimentary processes at a waning mid-ocean ridge

Two main types of glassy fragmental rocks formed along the Proto-Macquarie Spreading Ridge: (i) hyaloclastite breccia; and (ii) pillow-fragment breccia. Examples now exposed on Macquarie Island, Southern Ocean, were largely sourced from proximal pillow lavas. In each of seven samples examined, hyaloclasts (basaltic glass grains) have a narrow major- and trace-element geochemical range, consistent with derivation of each sample from a single volcanic eruption event. Moreover, every sample analysed within the one stratigraphic section (at three sites) displays distinctive major- and trace-element geochemistry compared with the other two sections. This suggests that hyaloclasts at each site represent discrete magma batches. A single source for these glassy fragmental rocks contrasts with the dominant fault-scarp-derived polymict sedimentary rocks on Macquarie Island. We suggest that the hyaloclasts analysed in this study were deposited in small basins between the slopes of growing pillow cones along the mid-ocean ridge. The geochemical analyses presented here encompass (weakly) fractionated (e.g. Bauer Bay) to near-primitive (e.g. Pyramid Peak) compositions. All samples presented here lie within the range of the enriched- to normal-MORB suites previously reported for the island that include the least fractionated MORB melts known globally. The interpretation of geochemically distinct magma batches over the small area of the island suggests very limited magma mixing consistent with an immature or waning magmatic system. We relate these geochemical characteristics to: (i) volcanism near a very long offset transform; and (ii) genesis of magmas during the waning stages of slow seafloor spreading within a very narrow (<50 km-wide) spreading corridor.     

Shallow layer correction for Spectral Element like methods

Today's numerical methods like the Spectral Element Method (SEM) allow accurate simulation of the whole seismic field in complex 3-D geological media. However, the accuracy of such a method requires physical discontinuities to be matched by mesh interfaces. In many realistic earth models, the design of such a mesh is difficult and quite ineffective in terms of numerical cost. In this paper, we address a limited aspect of this problem: an earth model with a thin shallow layer below the free surface in which the elastic and density properties are different from the rest of the medium and in which rapid vertical variations are allowed. We only consider here smooth lateral variations of the thickness and elastic properties of the shallow layer. In the limit of a shallow layer thickness very small compared to the smallest wavelength of the wavefield, by resorting to a second order matching asymptotic approximation, the thin layer can be replaced by a vertically smooth effective medium without discontinuities together with a specific Dirichlet to Neumann (DtN) surface boundary condition. Such a formulation allows to accurately take into account complex thin shallow structures within the SEM without the classical mesh design and time step constraints. Corrections at receivers and source—when the source is located within the thin shallow layer—have been also derived. Accuracy and efficiency of this formulation are assessed on academic tests. The stability and limitations of this formulation are also discussed.