水资源优化利用中两类数学模型间的分析比较

近期全球气候变化及人类经济活动规模的扩大，对人类赖以生存的自然环境造成很大影响，其中维持生态平衡的主导因子之一──水资源时空分布的变化，引起了人们极大的关注。尤其是干旱地区水资源表现出的稀缺性，已严重影响到人们将来的生存和经济发展问题。针对这种情况，人们在开发和利用水资源的过程中，建立了各种模型，以期对水资源进行精确的定量化研究，达到对水资源优化利用和管理的目的。通过比较“连续寻优的优化模型”和“离散方案的多目标密切值模型”，分析其各自的原理和规化思想，对其各自的预测功能进行了讨论，进而说明了两类模型的应用范围。提出将两类模型加以综合，然后应用于同一研究地区、以期得到更为优良的结果，为研究地区的经济发展提供可靠的决策依据。     

Self‐purification in Upland and Lowland Streams

Ecological investigations at four streams in Saxony‐Anhalt have shown that there are considerable differences between the self‐purification power of upland and lowland streams. This result is reflected in chemistry and in microbiology. The structure of the bottom substrate mainly influences the degree of self‐purification in connection with rate of flow and flow velocity. The results and differences are demonstrated using the example of Katzsohlbach in the landscape unit “Mittel‐ and Unterharz” and the stream Olbe in the landscape unit “Magdeburger Börde”.     

Trace metals in acid sediments and waters, Pimpama catchment, southeast Queensland, Australia

The Pimpama River floodplain has developed over the last several thousand years as a result of sea-level fluctuations that shaped the lower catchment and enabled the formation of sedimentary pyrite. The subsequent production of sulfuric acid due to the oxidation of this pyrite enhances the breakdown of metal-bearing sediments and can lead to leaching of major and trace metals into the waters of the region. The seasonal pattern of rainfall and current land-use activities are important aspects that intensify the natural production of acid and influence the release and distribution of metals. To identify the source and migration of metals in the Pimpama catchment and to understand the impact of pyrite oxidation on the distribution of metals in sediments and waters, several components of the drainage system were analyzed: bedrock, sediments from river bed and bank, and water. The elements analyzed in this study (V, Cr, Co, Ni, Cu, Zn and Pb) are all present in the bedrock material which explains their occurrence in the unconsolidated sediments of the floodplain. These metals concentrate in the upper section of the sedimentary sequence and their presence is related to clay minerals such as smectite, organic matter and iron phases. However, Zn, Mo and Co occur in higher amounts than the local background and within standard shale. This comparison suggests that the diagenetic processes alone cannot explain the higher concentrations and it is concluded that these metals also have an anthropogenic source. The formation of sulfuric acid creates conditions for higher mobility of some metals, such as Cr, Co, Ni, Cu, Zn, but does not affect less mobile ones such as Mo and Pb. Over the longterm, the production of acid influences the breakdown of mineral phases and enhances the process of weathering. Over the short term, every rain event leaches acid from sediments and mobilizes metals resulting in a substantial reduction in the quality of river water. Received: 2 October 1998 · Accepted: 16 February 1999     

Controls on the nature and distribution of an alga in coal mine-waste environments and its potential impact on water quality

 A dominant non-bacterial microorganism that may strongly impact environmental conditions in acid mine drainage at several Indiana coal mine sites is a single-celled protozoan, Euglena mutabilis. Field data suggest E. mutabilis has high tolerance for elevated total dissolved solids (TDS), to 18 g/l, and acid conditions to pH 1.7. Distribution is restricted to unmixed effluent pH<4.6, with prolific growth between pH 3.0 and 3.5. Additional factors influencing E. mutabilis include preference for areas with lower mineral/colloidal precipitation rates and a stable substrate of iron-rich precipitates. Initial studies indicate that in areas of prolific growth it contributes to oversaturation of dissolved oxygen by up to 200%. The presence of small orange intracellular crystalline-like structures, similar in color to iron oxyhydroxides, suggests that E. mutabilis may be sequestering iron, and possibly other metals. Further work is needed to determine if E. mutabilis contributes to natural mitigation of poor water quality at these and other coal mine sites. Received: 13 January 2000 · Accepted: 2 May 2000     

湖南地热资源分布及远景区划

湖南中新生代地质构造背景特殊，因而发育了丰富的地下热水资源。初步总结了省内地下热水资源的分布规律、水化学特征及其与地质构造的关系，划分了湘西北慈利－桑植－吉首、湘中隆回－武岗－洞口、湘东娄底－株洲－衡阳及湘南郴州－宜章－汝城4个地热异常区，为地热远景开发区划提供了基础资料。     

高分辨区域输送模式中不同输送格式的对比试验

本文对两种输送格式在理论试验的基础上，引入19层高分辨区域输送模式EM3，由中尺度模式（MM4)提供实例输送风场，积分至13、18、30、50、70小时，作分析和对比数值试验。采用的两种格式是:二阶动量矩守恒的Prather格式（以下简称为SOM)及通量订正的Smolar格式。数值试验结果表明，高精度的SOM格式使数值扩散减小一个量级， 使输送物质（SO#-[2])中心浓度比Smolar格式增大3～4倍， 采用SOM格式还明显改进了浓度中心水平平均运动轨迹的模拟精度，选择高精度的平流格式是改进模拟结果的重要途径。     

浅地层剖面仪在水域工程勘察中的应用

扼要介绍了水上浅地层剖面仪的方法技术，列举了该法在浅海，内河和湖泊减种典型环境及相应的地质条件下勘测所得到的剖面记录及地质解释结果，指出了运用该方法所能解决的工程地质问题。     

高村井水位潮汐参数的动态特征及其对大同地震的前兆响应

介绍了高村（京１４）井１９８３－１９９０年的观测结果，分析该井水位及潮汐参数的动态特征、气压对观测结果的影响，讨论了Ｍ２波潮汐因子对１９８９年大同地震的前兆响应。     

An Approach for Classification of Groundwaters by Synchronous Fluorescence Spectroscopy and Discriminant Analysis

Monitoring and evaluation of groundwater quality in drinking water protectorates is of particular interest if the uncontrolled entry of pollutants, for example by infiltrating river water, cannot be excluded. A fluorescence spectroscopic method is presented as possible alternative to the conventional expensive hydrochemical investigations. This method uses the information yielded by synchronous fluorescence spectra. After a Fourier transformation of the original spectra and a following discriminant analysis, the samples can be classified in different groups corresponding to the different types of groundwater. The method was tested in the drinking water protectorate of a waterworks of a German metropolis (Halle, Sachsen-Anhalt). We found a prediction rate of about 90% in the investigated case.     

IR-spektroskopische und weitere Untersuchungen an neuen Weichspüler-Wirkstoffen

IR Spectroscopy and Further Analyses of New Fabric Rinse Agents Distearyldimethylammoniumchloride (DSDMAC) that dominated the fabric softener market in Germany in the past is now substituted by three new types of ester-based agents, i.e. imidazoline ester, ester quats, and diester quats what poses new challenges to surface water analytics. The IR spectra and the chromatographic behaviour of these three agents are more or less similar to those of naturally occuring fatty esters. The paper reports about the use of IR spectroscopy, its benefit in the sense of fingerprinting principle, the identification of substances by functional groups, and the analytical tracing of transformation products. The latter relates to the formation of salts with anions that are easily detectable, the clean up, and the final spectroscopic determination. While in 1994 DSDMAC was still determinable in concentrations of 10…20 mg/kg in suspended solids from the Middle Rhine River, the concentration of the substitutes was below the detection limit of 2 mg/kg and 1…2 μg/L in 1995.