基于有机包裹体研究追索海拉尔盆地煤成油

有机包裹体在油气成因，运移研究中具有重要的意义，本文通过对海拉尔盆地砂岩样品中的有机包裹体进行显微荧光观察，包裹体均一测温，并对包裹体成分进行轻烃气相色谱及碳同位素分析，索了研究区油气的成因性质及油气运移期次,结果表明，海拉尔地区存在煤成油，并有两期以上的油气运移。     

松辽盆地地热资源的形成与远景评价

松辽平原在地貌和地质上都是一个盆地。盆地中心区域上地幔隆升形成地幔枕，使本地区成为地壳中的一个热点，具有较高的地热背景。盆地是汇水区，盆地中部地域自然就成为地下热水主要的分布区。松辽盆地地热资源开发远景大有希望。     

四川牦牛坪稀土矿床萤石REE配分模式的影响因素

四川牦牛坪稀土矿床萤石REE配分模式表现出明显变化的特征，本文从稀土离子半径和温度两个方面分析了影响矿区萤石配分模式的原因。结果表明：矿区萤石中LREE的配分模式主要受温度影响，而MREE、HREE主要受离子半径控制。     

含粘粒砂土抗液化性能的试验研究

通过对含粘粒砂土所作的试验研究, 包括: 粘粒矿物成分不同、粘粒含量不同的重塑土样所作的室内动三轴试验; X光衍射试验, 试验结果对比分析后, 得出了含粘粒砂土抗液化性能的特性。并得出以下结论: (1)粘粒矿物成分不同, 也引起砂土动力稳定性的变化; (2 )动剪应力强度与粘粒含量并非呈单调增加关系, 而呈抛物线型, 并给出回归方程; (3)含粘粒的砂土, 其抗液化能力最低点总是在粘粒含量 8.5～ 9.5 %之间。     

Self‐purification in Upland and Lowland Streams

Ecological investigations at four streams in Saxony‐Anhalt have shown that there are considerable differences between the self‐purification power of upland and lowland streams. This result is reflected in chemistry and in microbiology. The structure of the bottom substrate mainly influences the degree of self‐purification in connection with rate of flow and flow velocity. The results and differences are demonstrated using the example of Katzsohlbach in the landscape unit “Mittel‐ and Unterharz” and the stream Olbe in the landscape unit “Magdeburger Börde”.     

Inelastic buildings with tuned mass dampers under moderate ground motions from distant earthquakes

The effectiveness of tuned mass dampers (TMD) in vibration control of buildings was investigated under moderate ground shaking caused by long‐distance earthquakes with frequency contents resembling the 1985 Mexico City (SCT) or the 1995 Bangkok ground motion. The elastic–perfectly plastic material behaviour was assumed for the main structure, with linear TMDs employed by virtue of their simplicity and robustness. The accumulated hysteretic energy dissipation affected by TMD was examined, and the ratio of the hysteretic energy absorption in the structure with TMD to that without it is proposed to be used, in conjunction with the peak displacement ratio, as a supplementary TMD performance index since it gives an indication of the accumulated damage induced in the inelastic structures. For the ground motions considered, TMD would be effective in reducing the hysteretic energy absorption demand in the critical storeys for buildings in the 1.8–2.8 s range. The consequence is reduction in damage of the buildings which would otherwise suffer heavy damage in the absence of TMD, resulting in economical restorability in the damage control limit state. This is of practical significance in view of the current trend toward performance‐based design. Copyright © 2001 John Wiley & Sons, Ltd.     

Trace metals in acid sediments and waters, Pimpama catchment, southeast Queensland, Australia

The Pimpama River floodplain has developed over the last several thousand years as a result of sea-level fluctuations that shaped the lower catchment and enabled the formation of sedimentary pyrite. The subsequent production of sulfuric acid due to the oxidation of this pyrite enhances the breakdown of metal-bearing sediments and can lead to leaching of major and trace metals into the waters of the region. The seasonal pattern of rainfall and current land-use activities are important aspects that intensify the natural production of acid and influence the release and distribution of metals. To identify the source and migration of metals in the Pimpama catchment and to understand the impact of pyrite oxidation on the distribution of metals in sediments and waters, several components of the drainage system were analyzed: bedrock, sediments from river bed and bank, and water. The elements analyzed in this study (V, Cr, Co, Ni, Cu, Zn and Pb) are all present in the bedrock material which explains their occurrence in the unconsolidated sediments of the floodplain. These metals concentrate in the upper section of the sedimentary sequence and their presence is related to clay minerals such as smectite, organic matter and iron phases. However, Zn, Mo and Co occur in higher amounts than the local background and within standard shale. This comparison suggests that the diagenetic processes alone cannot explain the higher concentrations and it is concluded that these metals also have an anthropogenic source. The formation of sulfuric acid creates conditions for higher mobility of some metals, such as Cr, Co, Ni, Cu, Zn, but does not affect less mobile ones such as Mo and Pb. Over the longterm, the production of acid influences the breakdown of mineral phases and enhances the process of weathering. Over the short term, every rain event leaches acid from sediments and mobilizes metals resulting in a substantial reduction in the quality of river water. Received: 2 October 1998 · Accepted: 16 February 1999     

Controls on the nature and distribution of an alga in coal mine-waste environments and its potential impact on water quality

 A dominant non-bacterial microorganism that may strongly impact environmental conditions in acid mine drainage at several Indiana coal mine sites is a single-celled protozoan, Euglena mutabilis. Field data suggest E. mutabilis has high tolerance for elevated total dissolved solids (TDS), to 18 g/l, and acid conditions to pH 1.7. Distribution is restricted to unmixed effluent pH<4.6, with prolific growth between pH 3.0 and 3.5. Additional factors influencing E. mutabilis include preference for areas with lower mineral/colloidal precipitation rates and a stable substrate of iron-rich precipitates. Initial studies indicate that in areas of prolific growth it contributes to oversaturation of dissolved oxygen by up to 200%. The presence of small orange intracellular crystalline-like structures, similar in color to iron oxyhydroxides, suggests that E. mutabilis may be sequestering iron, and possibly other metals. Further work is needed to determine if E. mutabilis contributes to natural mitigation of poor water quality at these and other coal mine sites. Received: 13 January 2000 · Accepted: 2 May 2000     

Electric conductivity of Fe2SiO4–Fe3O4 spinel solid solutions

 The spinel solid solution was found to exist in the whole range between Fe₃O₄ and γ-Fe₂SiO₄ at over 10 GPa. The resistivity of Fe_{3− x} Si _x O₄ (0.0<x<0.288) was measured in the temperature range of 80∼300 K by the AC impedance method. Electron hopping between Fe³⁺ and Fe²⁺ in the octahedral site of iron-rich phases gives a large electric conductivity at room temperature. The activation energy of the electron hopping becomes larger with increasing γ-Fe₂SiO₄ component. A nonlinear change in electric conductivity is not simply caused by the statistical probability of Fe³⁺–Fe²⁺ electron hopping with increasing the total Si content. This is probably because a large number of Si⁴⁺ ions occupies the octahedral site and the adjacent Fe²⁺ keeping the local electric neutrality around Si⁴⁺ makes a cluster, which generates a local deformation by Si substitution. The temperature dependence of the conductivity of solid solutions indicates the Verwey transition temperature, which decreases from 124(±2) K at x=0 (Fe₃O₄) to 102(±5) K at x=0.288, and the electric conductivity gap at the transition temperature decreases with Si⁴⁺ substitution. Received: 15 March 2000 / Accepted: 4 September 2000     

Structure and compressibility of synthetic ZnAl2O4 (gahnite) under high-pressure conditions, from synchrotron X-ray powder diffraction

 The structural behavior of synthetic gahnite (ZnAl₂O₄) has been investigated by X-ray powder diffraction at high pressure (0–43 GPa) and room temperature, on the ID9 beamline at ESRF. The equation of state of gahnite has been derived using the models of Birch–Murnaghan, Vinet and Poirier–Tarantola, and the results have been mutually compared (the elastic bulk modulus and its derivatives versus P determined by the third-order Birch–Murnaghan equation of state are K ₀=201.7(±0.9) GPa, K ^′ ₀=7.62(±0.09) and K ^″ ₀=−0.1022 GPa⁻¹ (implied value). The compressibilities of the tetrahedral and octahedral bond lengths [0.00188(8) and 0.00142(5) GPa⁻¹ at P=0, respectively], and the␣polyhedral volume compressibilities of the four-␣and␣sixfold coordination sites [0.0057(2) and 0.0041(2) GPa⁻¹ at P=0, respectively] are discussed. Received: 15 January 2001 / Accepted: 23 April 2001