Qualitätsanforderungen an Oberflächengewässer: Zielvorgaben,Qualitätsziele und chemische Gewässergüteklassifizierung

Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.     

Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Ein kompetitiver Immunoassay zur Bestimmung des Herbizids Fluazifop in Trink- und Grundwasser

A Competitive Immunoassay for the Determination of the Herbicide Fluazifop in Drinking Water and Groundwater A competitive solid-phase enzyme immunoassay using rabbit polyclonal antibodies was developed for the detection of the herbicide fluazifop [(RS)-2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid] in drinking water and groundwater. Present regulatory limits for drinking water in Germany were taken as the critical level. The carrier protein was bovine serum albumin; horseradish peroxidase was used as marker enzyme with 3,3′,5,5′-tetramethylbenzidine as substrate. A high concentration of high-affinity antibodies in the serum, optimization of test conditions (antibody and enzyme tracer concentration, incubation time etc.), and very low cross reactivities to substances of similar structures led to a highly sensitive and specific ELISA with a detection limit below 0.1 μg/L for fluazifop as free acid. On testing the suitability of the assay's use as a screening test with one hundred drinking-water samples, the three samples which had been spiked in the laboratory were recognized as positive with respect to their fluazifop content. Confirmation by gas chromatography-mass spectrometry showed the test results of two other samples to be false positive. False negative results did not appear. The concentration was in the detection limit region of 0.1 μg/L.     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

Distribution of trace metals in the Odra River system: Water–suspended matter–sediments

Extensive investigations of trace metals concentrations in water, suspended particulate matter (SPM) and bottom sediments of the whole Odra River system were carried out over the years 1997–2000. The vertical distribution of selected metals and their mobility were also studied in the sediment cores from upper and middle river sections. Significant levels of metal contamination were found. Median concentrations (Cd, Pb, Cu, Zn and As) in the SPM and sediments were (mg kg⁻¹) 7.1 and 8.9 Cd, 128 and 146 Pb, 81 and 119 Cu, 1198 and 1204 Zn, 48 and 54 As, respectively. The highest metal pollution of the Odra River solids was found with cadmium, zinc, lead and arsenic, showing high similarity in their frequency distributions in both SPM and sediments. Cd, Zn and As appear to be of particular concern because of the high levels, that appear to be bioavailable, and their high mobility. The exchangeable and carbonate chemical forms of Cd and Zn reached up to 50% of their total amount. Besides the determination of total metal concentration, the metal chemical forms in river solids were investigated. The results of very wide studies of the Odra River system through 4 years suggest that metal pollution decreased, especially for Zn, Pb and Cu. Among all metals studied in the Odra River sediments, substantial reductions of Cd contamination were observed neither in the period after ’97 flood, nor if compared with the earlier results obtained before ’97. No essential differences of the metal contents were observed among the samples for the same river compartment, from the same locality, taken within the five sampling campaigns. The pattern of spatial and vertical metal distributions in the river solids indicates that a variety of sources might be responsible for the contamination; very intensive, historical and current mining and smelting activities probably are the most important ones.     

Temporal and spatial variations in water flow and sediment load in Narmada River Basin, India: natural and man-made factors

The Narmada River flows through the Deccan volcanics and transports water and sediments to the adjacent Arabian Sea. In a first-ever attempt, spatial and temporal (annual, seasonal, monthly and daily) variations in water discharge and sediment loads of Narmada River and its tributaries and the probable causes for these variations are discussed. The study has been carried out with data from twenty-two years of daily water discharge at nineteen locations and sediment concentrations data at fourteen locations in the entire Narmada River Basin. Water flow in the river is a major factor influencing sediment loads in the river. The monsoon season, which accounts for 85 to 95% of total annual rainfall in the basin, is the main source of water flow in the river. Almost 85 to 98% of annual sediment loads in the river are transported during the monsoon season (June to November). The average annual sediment flux to the Arabian Sea at Garudeshwar (farthest downstream location) is 34.29×10⁶ t year⁻¹ with a water discharge of 23.57 km³ year⁻¹. These numbers are the latest and revised estimates for Narmada River. Water flow in the river is influenced by rainfall, catchment area and groundwater inputs, whereas rainfall intensity, geology/soil characteristics of the catchment area and presence of reservoirs/dams play a major role in sediment discharge. The largest dam in the basin, namely Sardar Sarovar Dam, traps almost 60–80% of sediments carried by the river before it reaches the Arabian Sea.     

南水北调地下水回补对潮白河冲洪积扇中上部地表形变响应及控制因素

2014年南水进京后,持续开展地下水回补对于遏制和减缓地面沉降发展起到重要作用,但地下水回升由此带来的不同区域、不同层位的地面沉降与回弹机制及其控制因素尚不明确。深入探讨和研究回补时间、回补量、回补地点与水位及地表形变之间的关系,了解地表形变发生机理和识别主控因素,为后续如何科学回补,发挥最大化水资源回补效益、对地面沉降防治和超采区治理具有极其重要意义。本文以潮白河冲洪积扇中上部区域为例,采用永久散射体差分干涉测量（PS InSAR）技术获取研究区地面沉降形变信息,并结合区域分层地下水位动态变化、分层沉降变化等多手段进行耦合,查明研究区地表形变与多因素之间的响应与控制因素。结果表明:南水持续回补导致区域地面沉降减缓,并在牛栏山地区出现地表抬升,抬升范围也随着水位上升逐渐向中下游扩展,2022年最大回弹速率达46.9 mm/a;地表形变具有明显的受断裂所控制的第四系沉积差异特性,以黄庄—高丽营断裂、顺义断裂和南口—孙河断裂所分割的后沙峪凹陷范围内变化明显大于其他地区;地下水位变幅与富水性差异决定水位上升范围与响应变化,而沉积构造作用所造成第四系沉积差异在地下水流向上具有一定控制作用。结果为地面沉降防控和机理研究提供理论和科学依据,同时也为后续开展地下水科学回补和方案优化提供指导和借鉴。     

Dynamical features of near-inertial motions in global ocean based on the GDP dataset from 2000 to 2019

Based on the latest oceanic surface drifter dataset from the global drifter program during 2000–2019, this study investigated the global variation of relative frequency shift(RFS), near-inertial energy(NIE) and inverse excess bandwidth(IEB) of near-inertial motions, and analyzed their relations with oceanic mesoscale dynamics, relative vorticity and strain. Compared with previous works, we have some new findings in this study:(1) the RFS was high with negative values in some regions in which we found a significant blue shift of the RFS in the equatorward of 30°N(S) and from 50°N to 60°N in the Pacific, and a red shift in the western boundary currents and their extension regions, the North Atlantic and the Antarctic Circumpolar Current regions;(2) more peak values of the NIE were found in global regions like the South Indian Ocean, the Luzon Strait and some areas of the South Ocean;(3) the global distribution of the IEB were characterized by clear zonal bands and affected by vorticity and wind field;(4)the RFS was elevated as the absolute value of the gradient of vorticity increased, the IEB did not depend on the gradient of vorticity, and the eddy kinetic energy(EKE) weakened with the decrease of the absolute value of RFS;(5) the NIE decreased with increasing absolute value of the relative vorticity and the gradient of vorticity, but it increased with increasing strain and EKE when EKE was larger than 0.003 2 m~2/s~2.     

南水北调西线工程区地质图三维可视化表达及其意义

传统地质图由于采用正射投影的方法表达地质现象,只能表达地质现象在二维欧氏空间的定位,很难表达地质现象的三维空间特征。结合数字高程模型,在地理信息系统的支持下制作的南水北调西线工程区的三维可视化地质图,可更好地判读地质体的空间信息,便于分析地质体的空间展布规律。     

高速远程崩滑动力学的研究现状及发展趋势

高速远程崩滑动力学机理的研究,一直是国内外工程地质与山地灾害领域崩塌、滑坡灾害研究的前沿热点问题。对这一研究领域,最近几十年来所取得的研究成果、研究现状及发展趋势进行了述评。厘定了高速远程崩滑的定义;详细地阐述了国内外众多典型重大高速远程崩滑灾害事件的几何学、运动学特征;概述了迄今为止所提出的高速远程崩滑形成的各种动力学机理;分析与讨论了高速远程崩滑动力学机理研究的发展趋势与动向;提出了今后进一步研究的总体思路、目标与应重点解决的关键问题。