5－（4－羧基苯偶氮）－8－（对甲苯磺酰氨基）－喹啉与金显色反应研究及应用

以８－氨基喹啉为母体，合成了新试剂５－（４－羧基苯偶氮）－８－（对甲苯磺酰氨基）－喹啉（ＣＰＴＳＱ），研究了它与Ａｕ的显色反应，在ＣＴＭＡＢ存在下，于ｐＨ１０～１３的ＮａＯＨ介质中，ＣＰＴＳＱ与Ａｕ形成２：１紫蓝色络合物，最大吸收峰位于６１０ｎｍ，摩尔吸光系数１．０×ｌ０５Ｌ·ｍｏｌ－１·ｃｍ－１，Ａｕ含量在０～１．２ｍｇ／Ｌ内符合比尔定律。方法选择性好，灵敏度高，操作简便，已用于金矿石样品中Ａｕ的测定，结果满意。     

古交矿区8号煤的实验室热解脱硫

介绍了古交矿区8号煤在不加催化剂和加催化剂两种条件下的实验室热解脱硫试验情况．结果表明，在不加催化剂时，升温速度为5～10℃／min脱硫效果最好，脱硫率大于40％；当在原煤中添加催化剂AlCl3和NH4Cl时，有较好的脱硫作用，焦炭中灰分也没有明显提高，而当添加催化剂CuCl2和CaO时，不能脱除煤中硫。并据此提出了建议脱硫方案。     

The GIS and analysis of earthquake damage distribution of the 1303 Hongtong M=8 earthquake

The geography information system of the 1303 Hongton M=8 earthquake has been established. Using the spatial analysis function of GIS, the spatial distribution characteristics of damage and isoseismal of the earthquake are studies. By comparing with the standard earthquake intensity attenuation relationship, the abnormal damage distribution of the earthquake is found, so the relationship of the abnormal distribution with tectonics, site condition and basin are analyzed. In this paper, the influence on the ground motion generated by earthquake source and the underground structures near source also are studied. The influence on seismic zonation, anti-earthquake design, earthquake prediction and earthquake emergency responding produced by the abnormal density distribution are discussed. Foundation item: National important fundamental research “The Basic Research of Important Project in Damage Environment” and The important project “The Seismic Hazard Assessment Research and Anti-earthquake Structure Research” from China Earthquake Administration during the 10th Five-year Plan. Contribution No. 04FE1008, Institute of Geophysics, China Earthquake Administration.     

Use of microtremor measurement for assessing site effects in Northern Belgium – interpretation of the observed intensity during the MS = 5.0 June 11 1938 earthquake

To provide quantitative information on site effects in the northern part of Belgium, forty-seven H/V microtremor measurements were performed with 5 second seismometers over an area of about 15.000 km². Most of the results show a northward regular increase of the fundamental period in agreement with the augmentation of the Mesozoic and Cainozoic soft sedimentsthickness from a few meters 40 km south of Brussels to 900 m at the Netherlands-Belgium border. The measured resonance frequency values wereconsistent with theoretical computations performed at different sites onthe basis of existing information and shallow seismic experiments. At oneparticular site (Uccle) where borehole data were available, microtremor measurements using an array of four seismological stations with differentapertures allowed to obtain the low frequency part of the Rayleigh wave dispersion curve, extending the range covered by the analysis of surfacewaves artificially generated. The Vs profile derived from the surface waveinversion corroborates the 1 Hz natural frequency of the site. Comparison of these results with the macroseismic information concerning the M_S = 5.0 1938 earthquake which occurred 50 km west of Brussels,confirmed the hypothesis that the geological structure of the Brabant massifis likely to control damage distribution during such an earthquake. Comparisonbetween the intensity map of the 1938 earthquake and the resonance period ofsediments obtained by our microtremor study shows a clear relation betweenthe two parameters. During the 1938 earthquake, site effects played a prominent role due to the dimension of the source whose corner frequency wasabout 1 Hz.     

Stability of arsenopyrite and As(III) in low-temperature acidic solutions

Arsenopyrite is one of the most important pri-mary arsenic mineral. In the Eh-pH diagram of the As-O2-S-H2O system, if the total arsenic concentration (TAs) is taken to be 0.75 mg/L, the total sulfur con-centration, 32 mg/L, the temperature, 25℃and the pressure, one atmosphere pressure for the discrimina-tion of arsenic species, it may be found that under hy-pergene conditions, arsenopyrite is a moderately stable mineral. Only in the strongly alkaline and reducing environment can arsenopy…     

简要介绍R2V的功能及其在数字化图件中的应用

许多物化探及地质成果资料以纸质图件保存,在资料的再利用时需对其进行数字化.这里简要介绍一种数字化功能强大的矢量化软件-R2V的功能,针对物化探图件的特点,探讨了R2V数字化的流程.     

High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

基于光谱角匹配算法的水体信息提取研究

针对水体信息提取时,传统算法不能较好地解决山体阴影被误提为水体的问题,引入多用于高光谱数据处理的光谱角匹配算法,以Land-sat8 OLI(band1-band7)为数据源,以黄河小浪底水库周边区域为实验区,开展水体信息提取研究,结果显示:水体指数法和波段关系提取的结果中有大量的山体阴影信息,提取精度不超过30%,而光谱角匹配法提取结果受阴影的影响较小,提取精度在99%以上。     

Study of high temperature targets identification and temperature retrieval experimental model in SWIR remote sensing based Landsat8

For surface features in short-wave infrared (SWIR, 1.3–3.0 μm) in remote sensing imagery, pixel values depict the total energy including reflection and emission. For surface features at normal temperature in SWIR band, emission energy can be ignored. While for surface features at high temperature in SWIR band, emission energy is equal to or even higher than the reflection energy. So remote sensing imagery of SWIR band can be used to separate emission and reflection energy as well as to realize temperature retrieval of high temperature targets. In this study, the seventh band (SWIR band) of Landsat8 OLI remote sensing imagery is used to perform the theoretical model research for temperature retrieval of high temperature targets. In the meantime, it is also used with the corresponding observation experiment of synchronization satellite to check the theoretical model. The result shows that the radiant flux density for mixed pixels with high temperature targets is higher than adjacent pixels without high temperature targets. Thus, the high temperature pixels can be identified in SWIR band. The retrieval results of temperature and fractional area for high temperature targets are consistent with reality. In the study, the result illustrates that it is effective to identify high temperature targets in remote sensing imagery of SWIR band and the model is appropriate for temperature retrieval use.     

太原市地表热环境时空格局分析

针对鲜有资源型城市的地表热环境研究这一情况,该文基于Landsat8遥感数据,反演了太原市在2013—2015年间共3期的地表温度。提出一个考虑空间格局结构的城市热岛效应指数,在3期数据中,太原市区整体热岛效应指数分别为9.1%、9.8%和8.9%;同时,根据城市功能和路网结构将太原市区划分为6个分区,从分区级层面量化分析了地表热环境的时空分异特征规律,结果表明,太原市区地表温度整体呈现空间分散化特征,不同分区也呈现出不同的时空格局演变过程;最后,选取40个地表温度实测样本点验证反演精度,最大误差绝对值为1.1℃,最小误差绝对值为0.2℃,均方根误差为0.7℃。