Subsurface Occurrence of Natural Gas Hydrate in the Nankai Trough Area: Implication for Gas Hydrate Concentration

Abstract. The Nankai Trough runs along the Japanese Islands, where extensive BSRs have been recognized in its forearc basins. High resolution seismic surveys and site-survey wells undertaken by the MITI have revealed the gas hydrate distribution at a depth of about 290 mbsf. The MITI Nankai Trough wells were drilled in late 1999 and early 2000. The highlights were successful retrievals of abundant gas hydrate-bearing cores in a variety of sediments from the main hole and the post survey well-2, keeping the cored gas hydrate stable, and the obtaining of continuous well log data in the gas hydrate-dominant intervals from the main hole, the post survey well-1 and the post survey well-3. Gas-hydrate dominant layers were identified at the depth interval from 205 to 268 mbsf. Pore-space hydrate, very small in size, was recognized mostly filling intergranular pores of sandy sediments. Anomalous chloride contents in extracted pore water, core temperature depression, core observations as well as visible gas hydrates confirmed the presence of pore-space hydrates within moderate to thick sand layers. Gas hydrate-bearing sandy strata typically were 10 cm to a meter thick with porosities of about 40 %. Gas hydrate saturations in most hydrate-dominant layers were quite high, up to 90 % pore saturation.
All the gas hydrate-bearing cores were subjected to X-ray CT imagery measurements for observation of undisturbed sedimentary textures and gas-hydrate occurrences before being subjected to other analyses, such as (1) petrophysical properties, (2) biostratigraphy, (3) geochemistry, (4) microbiology and (5) gas hydrate characteristics.     

Origin of Natural Gas in Kekeya Field, Tarim Basin, China

This paper is mainly concentrated on the geochemical characteristics and origin of gas of Kekeya field in the Tarim basin, NW China. This study shows that Permian mudstone is the main source rock of oil and gas. Based on the carbon isotopes of C1--C4, the carbon isotope of gas in Kekeya field is a little heavier than that in the typical marine-derived gas. The relationship between carbon isotopes of methane and ethane is coincident with Faber equation of gas derived from organic matter Ⅰ/Ⅱ. The majority of gas maturity is estimated, based on the formula, at 1.8%-2.2% besides K2 and K18 wells. In addition, the gas derived from 0.9%-1.2% Ro source rocks may also bemixture. ^40Ar/^36Ar and ^3He/^4He ratios from the gas samples also support the mixing process. Moreover, the gas in this region is mainly generated from more mature source rocks although the low mature gas exists.     

武汉地铁及长江隧道沿线地下管线现状分析

本文论述了利用城市地下管线信息系统对武汉地铁和长江隧道沿线进行地下管线现状调查的过程和方法，结果表明利用该系统所完成的分析和成果资料满足了武汉及长江隧道沿线工程可行性研究的需要。     

Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

中国海相油气田勘探实例(之一) 四川盆地罗家寨大型气田的发现和探明

罗家寨气田发现于2000年,是四川盆地迄今为止发现的储量规模最大的一个气田,2002年探明储量为581.08×108m3。其下三叠统飞仙关组储层由碳酸盐岩蒸发台地边缘优质鲕粒滩白云岩构成,圈闭面积大,构造幅度高,具有一定的埋藏隐蔽性。论述了气田的发现和探明过程,气藏地质的特征,以及对碳酸盐岩气藏勘探的启示。     

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.     

Interpretation of radon anomalies in seismotectonic and tectonic-gravitational settings: the south-eastern Crati graben (Northern Calabria, Italy)

The study area is located in the south-eastern part of the Crati valley (Northern Calabria, Italy), which is a graben bordered by N–S trending normal faults and crossed by NW–SE normal left-lateral faults. Numerous severe crustal earthquakes have affected the area in historical time. Present-day seismic activity is mainly related to the N–S faults located along the eastern border of the graben. In this area, much seismically induced deep-seated deformation has also been recognised.In the present paper, radon concentrations in soil gas have been measured and compared with (a) lithology, (b) Quaternary faults, (c) historical and instrumental seismicity, and (d) deep-seated deformation.The results highlight the following:

(a) There is no evidence of a strong correlation between lithology and the radon anomalies.

(b) A clear correlation between the N–S geometry of radon anomalies and the orientation of main fault systems has been recognised, except in the southernmost part of the area, where the radon concentrations are strongly affected by the superposition of the N–S and the NW–SE fault systems.

(c) Epicentral zones of instrumental and historical earthquakes correspond to the highest values of radon concentrations, probably indicating recent activated fault segments. In particular, high radon values occur in the zones struck by earthquakes in 1835, 1854, and 1870.

(d) Deep-seated gravitational deformation generally coincides with zones characterised by low radon concentrations.

In the studied area, the anisotropic distribution of radon concentrations is congruent with the presence of neotectonic features and deep-seated gravitational phenomena. The method used in this study could profitably contribute towards either seismic risk or deep-seated gravitational deformation analyses.     

Microcrack networks in granite affected by a fault zone: Visualization by confocal laser scanning microscopy

Microcracks in the Cretaceous Ryoke-type granite in Japan were investigated by using deep drilling core samples collected in the Mizunami Underground Research Project of the Japan Nuclear Cycle Development Institute (JNC). The granite body suffered brittle deformation associated with Tertiary thrust movement. Based on core-scale and microscopic deformation features, the drill core from a depth of 300 to 700 m is divided into four domains, i.e. (A) undeformed granite, (B) granite intruded by cataclastic seams, (C) fractured granite in the fault damage zone, and (D) foliated cataclasite at the fault center. To characterize microcrack geometries in each domain, we employed the impregnation method using a low-viscous acrylic resin doped with fluorescent agents and captured the microcrack images by confocal laser scanning microscopy (CLSM). The CLSM image in the fault damage zone revealed anisotropic development of microcrack networks related to the fault movement. Both CLSM observation and porosity measurements reveal a drastic increase of micro-pores in the foliated cataclasite, possibly caused by fragmentation, and granulation and crack sealing in the fault zone.     

惰性气体法测定地下水入渗补给量

地下水入渗补给量是重要的水文地质参数。本文介绍了测定地下水入渗补给量的最新方法——惰性气体法的原理与方法，该方法适用于封闭条件下的深层地下水。     

Analysis of rock structure stability in coal mines

In this paper, the theory of limit point instability is used to analyse the stability of rock structures in coal mines. A general method of analysing stability of rock structures is put forward and a uniform instability condition of rock structures is set up. Some instability phenomena, such as rock bursts in circular roadways, pillars and long walls, and the outburst of coal and gas from circular roadways, are discussed analytically. At a later stage, the critical point of rock structure instability is determined. The influence of relative parameters (such as the mechanical properties of rock, coal, and the geometric sizes) on the stability of the rock structures is carefully analysed. Copyright © 2005 John Wiley & Sons, Ltd.