淮河流域周村水库夏季CDOM吸收光谱特征、空间分布及其来源分析

基于2015年8月采集的24个淮河流域以周村水源水库为代表的表层水样的有色溶解性有机物(CDOM)吸收系数数据,研究了CDOM吸收光谱的空间分布特征,考察了CDOM的吸收系数与水质参数的相关关系,同时探讨了周村水库夏季CDOM的潜在来源.结果显示:依据CDOM的吸收光谱空间分布特性及采样点分布特征,周村水库分为入库口、过渡区和主库区3个特征水域;CDOM的吸收系数沿入库口到主库区依次递减,S值呈现相反的趋势;分析发现S240~500与a(355)和a*(355)呈极显著负相关(R~2=0.98、0.88);CDOM吸收系数a(355)与溶解性有机碳(DOC)浓度具有良好的线性相关,有利于建立DOC遥感反演模型;同时,CDOM吸收系数a(355)与a_(ph)(440)存在极显著正线性相关,表明浮游植物的新陈代谢及其降解产物是夏季周村水库CDOM的潜在来源.综上,通过对夏季周村水库水体CDOM的研究,丰富了关于水源水体CDOM的调查资料,可为日后水库的管理提供技术支撑.     

太湖水体吸收分解(Ⅱ):浮游植物色素吸收分解

蓝藻水华暴发前,浮游植物群类结构的变化可通过其指示型色素的浓度变化来反映.为了同时反演叶绿素a、叶绿素b(绿藻门指示型色素)、叶绿素c(硅藻门指示型色素)和藻蓝素(蓝藻门的指示型色素)的浓度,利用偏最小二乘回归构建线性模型,通过2011年太湖实测吸收数据,较为准确地反演了叶绿素a和藻蓝素的浓度;针对无明显优势藻的春季数据集较为准确地反演了叶绿素b和叶绿素c的浓度.相对于经典最小二乘算法,偏最小二乘法在多色素混合的吸收光谱分析上更为有效.通过反演指示性色素浓度来反映藻类的分布,为富营养化湖泊主要藻类时空分布变化的遥感监测提供了一定的理论与技术支持.     

Intercomparison of NO_x, SO_2, O_3, and Aromatic Hydrocarbons Measured by a Commercial DOAS System and Traditional Point Monitoring Techniques

A field-based Intercomparison study of a commercial Differential Optical Absorption Spectroscopy (DOAS) instrument (OPSIS AB, Sweden) and different point-sample monitoring techniques (PM, based on an air monitoring station, an air monitoring vehicle, and various chemical methods) was conducted in Beijing from October 1999 to January 2000. The mixing ratios of six trace gases including NO, NO2, SO2, O3, benzene, and toluene were monitored continuously during the four months. A good agreement between the DOAS and PM data was found for NO2 and SO2. However, the concentrations of benzene, toluene, and NO obtained by DOAS were significantly lower than those measured by the point monitors. The ozone levels monitored by the DOAS were generally higher than those measured by point monitors. These results may be attributed to a strong vertical gradient of the NO-O3-NO2 system and of the aromatics at the measurement site. Since the exact data evaluation algorithm is not revealed by the manufacturer of the DOAS sys     

紫外线强度等级确定因子的季节性选择

利用南京市2005年2月—2009年1月的紫外线辐射观测资料,分析了到达地面的紫外线辐射强度的季节变化和日变化规律,并重点对各月10—14时的紫外线辐射平均值、最大值和最小值的强度级别分布频率进行了分析和讨论,提出根据不同季节来选择不同的紫外线辐射特性值作为紫外线强度等级的确定因子,夏季采用10—14时的紫外线辐射强度的最大值,冬季采用其最小值,春季和秋季采用其平均值。     

冰—水球形粒子在太阳短波段的吸收与衰减

根据Mie理论以及Aden和Kerker的理论,分别计算了纯水、纯冰和冰—水分层同心球在可见光和近红外波段的吸收、散射与衰减截面。结果表明,对于同样尺度大小的粒子,表面融化冰球或冰外壳包水球的单次散射特征值与纯冰纯水球的相比在整个太阳辐射短波段都相差不大,这是因为在此波段范围内冰和水的复折射指数的实部和虚部都很接近。此结果基本排除了0℃层附近表面融化冰晶粒子在太阳波段可能产生强吸收带,从而可以解释（部分的）云吸收异常现象这一想法。另一方面,在整层云吸收计算中,相对水含量可能较小但尺度较大的冰晶粒子的吸收是     

Momentum Absorption in Rough-Wall Boundary Layers with Sparse Roughness Elements in Random and Clustered Distributions

A wind-tunnel experiment has been used to investigate momentum absorption by rough surfaces with sparse random and clustered distributions of roughness elements. An unusual (though longstanding) method was used to measure the boundary-layer depth δ and friction velocity u _* and thence to infer the functional relationship z ₀/h = f(λ) between the normalised roughness length z ₀/ h and the roughness density λ (where z ₀ is the roughness length and h the mean height of the roughness elements). The method for finding u _* is based on fitting the velocity defect in the outer layer to a functional form for the dimensionless velocity-defect profile in a canonical zero-pressure-gradient boundary layer. For the conditions investigated here, involving boundary layers over sparse roughness with strong local heterogeneity, this velocity-defect-law method is found to be more robust than several alternative methods for finding u _* (uw covariance, momentum integral and slope of the logarithmic velocity profile).The experimental results show that, (1) there is general agreement in the relationship z ₀/h = f(λ) between the present experiment with random arrays and other wind-tunnel experiments with regular arrays; (2) the main effect of clustering is to increase the scatter in the z ₀/h = f(λ) relationship, through increased local horizontal heterogeneity; (3) this scatter obscures any trend in the z ₀/h = f(λ) relationship in response to clustering; and (4) the agreement between the body of wind-tunnel data (taken as a whole) and field data is good, though with scatter for which it is likely that a major contribution stems from local horizontal heterogeneity in the field.     

臭氧吸收参数数据库精度检验和验证

利用国际权威期刊上发表的臭氧吸收截面观测数据,检验和验证了现有的紫外正演模式TOMRAD臭氧吸收参数数据库。结果表明,在Hartley臭氧吸收带上,观测数据与数据库参数吻合状况很好;而在Huggins臭氧吸收带上,观测数据与数据库参数在部分波长上存在较大偏差,某些波长上的偏差超过50%。鉴于此,FY-3紫外臭氧探测仪资料处理计算中,选取臭氧吸收参数,必须特别慎重。     

大气NO2柱浓度多轴差分吸收光谱测量技术及应用

介绍了以太阳散射光为光源的多轴差分吸收光谱技术（Multi-Axis Differential Optical Absorption Spectroscopy,简称MAX-DOAS）,以及MAX-DOAS仪器试验应用.试验中选取中午仪器测量的天顶散射光光谱为参考光谱即Fraunhofer参考光谱,并将测量光谱进行消噪、波长校准以及去除Fraunhofer结构处理.利用分子吸收光学厚度和Ring效应光学厚度对处理后的测量光谱进行最小二乘法拟合,反演出了大气NO2差分斜柱浓度（Differential Slant Column Densities,简称DSCD）.分析了天津武清NO2的差分斜柱浓度反演结果,用简单快捷的几何法将NO2差分斜柱浓度转化成对流层垂直柱浓度（Vertical Column Densities,简称VCD）.研究表明,MAX-DOAS可以有效地监测污染地区对流层NO2的垂直柱浓度.     

基于紫外辐射测量冰雹的新方法研究

冰雹对农业、工业等会造成很大危害,多年来一直没有一种比较有效、简单的方法来对冰雹进行测量和预测.本文给出了一种利用测量闪电中紫外线的方法进行冰雹的测量和预测的方法和设备,经实验验证,这种方法能够较精确地测量出冰雹存在的类型(非雹云、弱雹云和强雹云),从而为有效地进行消雹作业提供依据.