微波超快速吸收现象

对１９８８年６月２９日云南天文台高时间分辨率射电望远镜观测到的微波超快速吸收现象进行了分析研究。在世界时０７ｈ３８ｍ５０ｓ至０７ｈ３８ｍ５８ｓ超快速吸收现象出现在太阳活动区ＮＯＡＡ／ＵＳＡＦ５０６０上空的４００ＧＨｚ上,而在２８４ＧＨｚ和１４２ＧＨｚ上空出现的是ｓｐｉｋｅ辐射。当时,该活动区呈现出极其活跃的双极磁场位形。在世界时０７ｈ３８ｍ至０８ｈ４７ｍ先后产生了３Ｂ级和２Ｂ级的Ｈα耀斑,并出现了Ｍ６５Ｘ射线爆发。根据电子回旋脉泽谐波吸收峰的特性,我们计算了三个波段的二次、三次谐波的磁场强度,并采用偶极磁场模型进行分析。对于４００ＧＨｚ上出现的超快速吸收现象,可能是产生的三次谐波脉泽辐射,在穿过吸收区时被吸收掉了。     

石墨炉原子吸收法测定钛铁矿中的微量镉

研究了石墨炉原子吸收测定钛铁矿中微量元素Cd的方法,探索了在高含量的Fe,Ti基体干扰下以NH4H2PO4-H2NCSNH2-EDTA为混合基体改进剂的最佳仪器工作条件。在取样0.200 0g,定容25mL的条件下,方法检出限为0.006μg/g,用国家标准物质验证,其准确度(RE%)10%,12次测定精密度(RSD%)10%,加标回收率90%~110%之间,符合国家相关要求。     

NN detectability in Pluto’s atmosphere

Based on the vapor pressure behavior of Pluto’s surface ices, Pluto’s atmosphere is expected to be predominantly composed of N₂ gas. Measurement of the N₂ isotopologue ¹⁵N/¹⁴N ratio within Pluto’s atmosphere would provide important clues to the evolution of Pluto’s atmosphere from the time of formation to its present state. The most straightforward way of determining the N₂ isotopologue ¹⁵N/¹⁴N ratio in Pluto’s atmosphere is via spectroscopic observation of the ¹⁴N¹⁵N gas species. Recent calculations of the 80–100 nm absorption behavior of the ¹⁴N₂ and ¹⁴N¹⁵N isotopologues by Heays et al. (Heays, A.N. et al. [2011]. J. Chem. Phys. 135, 244301), Lewis et al. (Lewis, B.R., Heays, A.N., Gibson, S.T., Lefebvre-Brion, H., Lefebvre, R. [2008]. J. Chem. Phys. 129, 164306); Lewis et al. (Lewis, B.R., Gibson, S.T., Zhang, W., Lefebvre-Brion, H., Robbe, J.-M. [2005]. J. Chem. Phys. 122, 144302), and Haverd et al. (Haverd, V.E., Lewis, B.R., Gibson, S.T., Stark, G. [2005]. J. Chem. Phys. 123, 214304) show that the peak magnitudes of the ¹⁴N₂ and ¹⁴N¹⁵N absorption bandhead cross-sections are similar, but the locations of the bandhead peaks are offset in wavelength by ∼0.05–0.1 nm. These offsets make the segregation of the ¹⁴N₂ and ¹⁴N¹⁵N absorption signatures possible. We use the most recent N₂ isotopologue absorption cross-section calculations and the atmospheric density profiles resulting from photochemical models developed by Krasnopolsky and Cruickshank (Krasnopolsky, V.A., Cruickshank, D.P. [1999]. J. Geophys. Res. 104, 21979–21996) to predict the level of solar light that will be transmitted through Pluto’s atmosphere as a function of altitude during a Pluto solar occultation. We characterize the detectability of the isotopic absorption signature per altitude assuming ¹⁴N¹⁵N concentrations ranging from 0.1% to 2% of the ¹⁴N₂ density and instrumental spectral resolutions ranging from 0.01 to 0.3 nm. Our simulations indicate that optical depth of unity is attained in the key ¹⁴N¹⁵N absorption bands located between 85 and 90 nm at altitudes ∼1100–1600 km above Pluto’s surface. Additionally, an ¹⁴N¹⁵N isotope absorption depth ∼4–15% is predicted for observations obtained at these altitudes at a spectral resolution of ∼0.2–0.3 nm, if the N₂ isotopologue ¹⁵N/¹⁴N percent ratio is comparable to the 0.37–0.6% ratio observed at Earth, Titan and Mars. If we presume that the predicted absorption depth must be at least 25% greater than the expected observational uncertainty, then it follows that a statistically significant detection of these signatures and constraint of the N₂ isotopologue ¹⁴N/¹⁵N ratio within Pluto’s atmosphere will be possible if the attainable observational signal-to noise (S/N) ratio is ?9. The New Horizons (NH) Mission will be able to obtain high S/N, 0.27–0.35 nm full-width half-max 80–100 nm spectral observations of Pluto using the Alice spectrograph. Based on the NH/Alice specifications we have simulated 0.3 nm spectral resolution solar occultation spectra for the 1100–1600 km altitude range, assuming 30 s integration times. These simulations indicate that NH/Alice will obtain spectral observations within this altitude range with a S/N ratio ∼25–50, and should be able to reliably detect the ¹⁴N¹⁵N gas absorption signature between 85 and 90 nm if the ¹⁴N¹⁵N concentration is ∼0.3% or greater. This, additionally, implies that the non-detection of the ¹⁴N¹⁵N species in the 1100–1600 km range by NH/Alice may be used to reliably establish an upper limit to the N₂ isotopologue ¹⁵N/¹⁴N ratio within Pluto’s atmosphere. Similar results may be derived from 0.2 to 0.3 nm spectral resolution observations of any other N₂-rich Solar System or exoplanet atmosphere, provided the observations are attained with similar S/N levels.     

Photosynthetic bark: Use of chlorophyll absorption continuum index to estimate Boswellia papyrifera bark chlorophyll content

Quantification of chlorophyll content provides useful insight into the physiological performance of plants. Several leaf chlorophyll estimation techniques, using hyperspectral instruments, are available. However, to our knowledge, a non-destructive bark chlorophyll estimation technique is not available. We set out to assess Boswellia papyrifera tree bark chlorophyll content and to provide an appropriate bark chlorophyll estimation technique using hyperspectral remote sensing techniques. In contrast to the leaves, the bark of B. papyrifera has several outer layers masking the inner photosynthetic bark layer. Thus, our interest includes understanding how much light energy is transmitted to the photosynthetic inner bark and to what extent the inner photosynthetic bark chlorophyll activity could be remotely sensed during both the wet and the dry season. In this study, chlorophyll estimation using the chlorophyll absorption continuum index (CACI) yielded a higher R² (0.87) than others indices and methods, such as the use of single band, simple ratios, normalized differences, and conventional red edge position (REP) based estimation techniques. The chlorophyll absorption continuum index approach considers the increase or widening in area of the chlorophyll absorption region, attributed to high concentrations of chlorophyll causing spectral shifts in both the yellow and the red edge. During the wet season B. papyrifera trees contain more bark layers than during the dry season. Having less bark layers during the dry season (leaf off condition) is an advantage for the plants as then their inner photosynthetic bark is more exposed to light, enabling them to trap light energy. It is concluded that B. papyrifera bark chlorophyll content can be reliably estimated using the chlorophyll absorption continuum index analysis. Further research on the use of bark signatures is recommended, in order to discriminate the deciduous B. papyrifera from other species during the dry season.     

利用氧气和水汽吸收波段暗像元假设的MERIS影像二类水体大气校正方法

摘 要:MERIS数据以其更为合理的水色波段设置和300m较高的空间分辨率,在内陆湖泊水环境遥感监测中有较大的应用潜力, 对其进行有效的大气校正则是水环境参数定量化反演的前提。以太湖为研究区, 研究基于氧气和水汽吸收波段的暗象元假设, 改进传统的近红外波段暗像元假设的大气校正方法。采用MERIS L2p数据辅助获取湖区气溶胶参数, 并利用2007年11月11日、2008年11月20日以及2009年4月25日三景MERIS影像进行方法验证。结果表明, 该方法能够快速、有效地完成MERIS影像的大气校正, 与地面准同步实测数据相比, 三次校正的RMSP都在25%以下; 与BEAM自带的二类水体大气校正算法、气溶胶厚度辅助的6S大气校正以及改进的暗象元算法进行精度比较, 表明该算法校正精度较高。由于该算法不需要同步实测气溶胶数据, 因此具有一定的适用性。     

Treatability of Dye Solutions Containing Disperse Dyes by Fenton and Fenton‐Solar Light Oxidation Processes

This study attempts to explore the possibility of treating dye solutions containing Disperse Yellow 119 and Disperse Red 167 by Fenton and Fenton under solar‐light oxidation processes. Experiments were conducted to examine the effects of various operating conditions on the performance of the treatment systems. The Fenton results showed that 98.6% spectral absorption coefficient (SAC) and 90.8% chemical oxygen demand (COD) removals were proved at pH 3, 50 mg/L Fe²⁺, and 75 mg/L H₂O₂, 15 min oxidation time for Disperse Yellow 119. After 40 min solar irradiation time during Fenton process the SAC removal was 99.1%. COD reduction of about 98.3% was observed at the same time. It was also obtained as 97.8% SAC and 97.7% COD removal with pH 3, 75 mg/L Fe²⁺, 100 mg/L H₂O₂, and 25 min oxidation time for Disperse Red 167 at this optimum conditions. For Disperse Red 167 during Fenton under solar light process, after 40 min of solar irradiation time the SAC and COD reduction were obtained 99.3 and 98.4%, respectively.     

Application of multivariate model based on three simulated sensors for water quality variables estimation in Shitoukoumen Reservoir,Jilin Province,China

This study applied a multivariate model based on three simulated sensors to estimating water quality variables in Shitoukoumen Reservoir, Changchun City, Jilin Province, China, including concentration of total suspended matter, concentration of chlorophyll-a and non-pigment matter absorption. Two field campaigns for spectra measurements with a total of 40 samples were carried out on June 13 and September 23, 2008. The in-situ spectra were recalculated to the spectral bands and sensitivities of the instruments applied in this paper, i.e. Landsat TM, Alos and P6, by using the average method. And the recalculated spectra were used for estimating water quality variables by the single model and multivariate model. The results show that the multivariate model is superior to the single model as the multivariate model takes the combined effects of water components into consideration and can estimate water quality variables simultaneously. According to R ² and RMSE, Alos is superior to other sensors for water quality variables estimation although the precision of non-pigment matter absorption inversion performed the second.     

孔间电磁波CT法在左江电站火成岩坝基风化结构评价中的应用

孔间电磁波CT法不仅在岩溶探测以及岩浆岩地层岩石风化界面的探测,有广阔的应用前景。针对左江电站坝基岩浆岩地层的霏细岩,岩石中含石英、长石、蒙脱石等矿物,加上应力作用易隐存风化界面及软弱夹层,直接影响坝基安全。提出运用不断改进的孔间电磁波法及CT处理软件,对所获数据进行反演成像,结果显示,实际观测的吸收系数值与岩样测试结果基本吻合。在所探查的3对钻孔剖面,数字图像清晰给出了岩石结构和风化层界面深度,结果已得到钻探验证,为左江电站坝基帷幕灌浆深度提供了可靠依据。     

低频激振器楼面激振试验研究

本文对一座六层双向单跨的1:4钢框架模型进行土槽中低频激振器楼面激振试验,根据牛顿第二定律和作用力与反作用力原理,将激振器输出的信号转化为作用在结构上的动力作用,研究上部动力荷载作用下土与结构的动力相互作用。对采集的信号进行频谱分析和时域分析,研究体系的基频和模型顶层的加速度和位移反应,并与刚性地基上的结果进行比较。结果表明,土与结构的相互作用能有效降低体系的动力反应。考虑SSI效应时,大刚度结构对顶层加速度的削弱及位移的放大可能小于小刚度结构,这种削弱作用的大小主要是由结构的刚重比来决定。     

The proportions and variations of the light absorption coefficients of major ocean color components in the East China Sea

The East China Sea (ECS),one of the largest continental seas,has dynamic hydrology and complex optical characteristics that make ocean color remote-sensing retrieval difficult.The distributions and proportions of the light absorption coefficients of major ocean color components based on two large-scale investigations in the ECS are presented,showing these features in typical summer and winter seasons.The absorption coefficient a CDOM,a NAP and a phy of colored dissolved organic matter,non-algal particle,and pigment of phytoplankton show a decreasing trend from the coast to the outer shelf.According to the a CDOM distribution at 440 nm,the Changjiang River plume shows an abnormal southeastward transport.An extremely high a NAP value patch at 440 nm is present in the middle coast.The chlorophyll-a-specific phytoplankton pigment absorption (a phy) is much higher in winter than in summer,which may cause serious underestimated results when applying the averaged a phy into remote-sensing algorithms for chlorophyll concentration retrieval.The importance of phytoplankton size was evident in outer shelf waters.The absorption of a CDOM (440) is a dominant component accounting for over half of the total seawater absorption in summer.The a NAP (440) accounts for 64% of the absorption of the ECS coastal area in winter.