Spectral heterogeneity on Phobos and Deimos: HiRISE observations and comparisons to Mars Pathfinder results

The High-Resolution Imaging Science Experiment (HiRISE) onboard Mars Reconnaissance Orbiter (MRO) has been used to observe Phobos and Deimos at spatial scales of around 6 and 20 m/px, respectively. HiRISE (McEwen et al., JGR, 112, CiteID E05S02, DOI: 10.1029/2005JE002605, 2007) has provided, for the first time, high-resolution colour images of the surfaces of the Martian moons. When processed, by the production of colour ratio images for example, the data show considerable small-scale heterogeneity, which might be attributable to fresh impacts exposing different materials otherwise largely hidden by a homogenous regolith. The bluer material that is draped over the south-eastern rim of the largest crater on Phobos, Stickney, has been perforated by an impact to reveal redder material and must therefore be relatively thin. A fresh impact with dark crater rays has been identified. Previously identified mass-wasting features in Stickney and Limtoc craters stand out strongly in colour. The interior deposits in Stickney appear more inhomogeneous than previously suspected. Several other local colour variations are also evident.Deimos is more uniform in colour but does show some small-scale inhomogeneity. The bright “streamers” (Thomas et al., Icarus, 123, 536–556,1996) are relatively blue. One crater to the south-west of Voltaire and its surroundings appear quite strongly reddened with respect to the rest of the surface. The reddening of the surroundings may be the result of ejecta from this impact.The spectral gradients at optical wavelengths observed for both Phobos and Deimos are quantitatively in good agreement with those found by unresolved photometric observations made by the Imager for Mars Pathfinder (IMP; Thomas et al., JGR, 104, 9055–9068, 1999). The spectral gradients of the blue and red units on Phobos bracket the results from IMP.     

流动注射Ferene分光光度法测定海水中溶解态铁的方法优化

热液流体中溶解态铁是海水原位测量的重要参数之一。本研究采用Ferene分光光度法,搭建流动注射分析系统,优化进样条件、显色条件,实现了热液流体中溶解态铁的在线测定。结果表明,测定Fe(II)时,Ferene、缓冲液浓度分别为8×10–3、0.4 mol/L,Ferene、样品流速分别为0.8、0.6 m L/min,显色盘管长度为40 cm时,方法的灵敏度、检测限最佳;测定Fe(III)时,Ferene、缓冲液、抗坏血酸浓度分别为1×10–2、0.5、0.01 mol/L,Ferene/抗坏血酸、样品流速均为1.0 m L/min,还原、显色盘管长度均为40 cm时,方法的灵敏度、检测限最佳。最佳实验条件下,Fe(II)、Fe(III)在0.2~10μmol/L和0.5~16μmol/L范围内,工作曲线回归方程分别为A=0.0834 C+0.0564(μmol/L,n=8,R2=0.997)和A=0.0478C+0.0423(μmol/L,n=8,R2=0.997)。Fe(II)、Fe(III)检测限分别为24、39 nmol/L,相对标准偏差分别为0.8%、1.2%(n=10),加标回收率为97.9%~103.0%。共存离子实验表明,流体中的Na+、Mn2+、Cu2+、Cu+不会对测量造成干扰。     

Changes in the spectral and chemical properties of a water mass passing through extensive macrophyte beds in a large fluvial lake (Lake Saint-Pierre, Québec, Canada)

Large fluvial lakes, as part of river corridors, are recognized as spatially heterogeneous ecosystems. Due to their shallowness, the littoral zone of these lakes occupies a large proportion of their surface and is extensively covered by macrophytes that are known to affect their physical, chemical and biological environments in various ways. This study documents the small-scale (5 km) bio-optical variations associated with the longitudinal passage of a water mass through macrophyte beds during their maximal growth season. The utilization of a 2D hydrodynamic model allowed us to establish hydrological connectivity between stations within the beds, and thus to identify longitudinal heterogeneity along the macrophyte beds. Significant changes in the inherent properties of the water were observed along the upstream-downstream gradient. Due to their effects on hydrodynamics, macrophytes were responsible for a decrease in particles and dissolved organic carbon (DOC) resulting in an increasing penetration depth of ultraviolet (UV) and photosynthetically active radiation (PAR). Along the transect, chromophoric dissolved organic matter (CDOM) decreased more rapidly than DOC resulting in a decrease of the CDOM to DOC ratio. The observed changes in the DOC pool may be explained by the constant input of non-chromophoric DOC from macrophyte leachates and exudation within the bed and/or the photochemical and microbial degradation of CDOM. The implication of such small-scale heterogeneity on Lake Saint-Pierre productivity is discussed.     

Optical and thermal infrared observations of six near-Earth asteroids in 2002

We present thermal infrared photometry and spectrophotometry of six Near-Earth Asteroids (NEAs) using the 3.8 m United Kingdom Infrared Telescope (UKIRT) together with quasi-simultaneous optical observations of five NEAs taken at the 1.0 m Jacobus Kapteyn Telescope (JKT). For Asteroid (6455) 1992 HE we derive a rotational period P=2.736±0.002 h, and an absolute visual magnitude H=14.32±0.24. For Asteroid 2002 HK₁₂ we derive . The Standard Thermal Model (STM), the Fast Rotating Model (FRM) and the Near-Earth Asteroid Thermal Model (NEATM) have been fitted to the measured fluxes to derive albedos and effective diameters. The derived geometric albedos and effective diameters are (6455) 1992 HE: pv=0.26±0.08, Deff=3.55±0.5 km; 1999 HF₁: pv=0.18±0.07, ; 2000 ED₁₀₄: pv=0.18±0.05, Deff=1.21±0.2 km; 2002 HK₁₂: , Deff=0.62±0.2 km; 2002 NX₁₈: pv=0.031±0.009, Deff=2.24±0.3 km; 2002 QE₁₅: , Deff=1.94±0.4 km. The limitations of using the NEATM to observe NEAs at high phase angles are discussed.     

Estimation Approaches of ηUV,PUV and UV Directional Wave Spectra and Their Comparison

The observation and estimation of directional spectra of sea waves is one of the essential subjects of study of oceanic dynamics. On the basis of the irregular linear wave theory, estimation methods for i/UV, PUV and VV directional wave spectra are derived. By using ij and PUV data measured in-situ, directional wave spectra are estimated, meanwhile the virtues and defects of various spectra are comparied. This method provide a basis for the observations of sea waves.     

钌的硫脲比色测定

本文讨论了钌同硫脲的显色反应，在不经分离的条件下，将Ｒｕ还原Ｒｕ￣Ⅱ，Ｒｕ￣Ⅱ与硫脲生成蓝色，λ＿最大＝６３５ｎｍ，在０－３００μｇ／ｍｌ范围内呈线性关系。本法适宜测定含Ｒｕ量较高钌的渣及其选矿成品。     

昆明下半年紫外辐射变化及与云的关系分析(Ⅱ)

依据2003年8月1日到2003年12月31日同步观测得到的地面紫外辐射资料,分析了紫外辐射和云量的关系,在实际天气条件下,紫外辐射变化没有我们所认为的那种有特别明显的规律。云对到达地面的紫外辐射可能有着十分复杂和重要的作用。     

Limnology of an equatorial high mountain lake — Lago San Pablo, Ecuador: The significance of deep diurnal mixing for lake productivity

Equatorial high mountain lakes are a special type of lake occurring mainly in the South American Andes as well as in Central Africa and Asia. They occur at altitudes of a few thousand meters above sea level and are cold-water lakes (<20 °C). Relatively little is known about them. A long-term limnological study was therefore undertaken at Lake Lago San Pablo, Ecuador to analyze the basic limnological processes of this lake, which has a tendency for eutrophication. Lago San Pablo is spread over an area of 668 hectares, has a maximum depth of 35 m, and is located 2660 m above sea level. Its thermal stratification is a monomictic one, with only 1–2 °C difference between the epi- and hypolimnion; overturn is achieved by strong winds during the dry summer period. The stratification phase is characterized by an oxygen deficit in the lower part of the hypolimnion. Besides, strong convective currents occur due to nocturnal cooling, and partial lake mixing was observed during the nocturnal period. This type of lake mixing is called atelomixis, which is characterized by the partial mixing of isolated layers (difference in temperature or ionic content) during stratification. The nutrient level of the lake is quite high: mean P_total concentration = 0.22 mg/l, mean N_total = 1.05 mg/l, soluble reactive phosphorus (SRP) > 0.01 mg/l, and soluble inorganic nitrogen > 0.2 mg/l. Nitrogen and phosphorus are available in the epilimnion all year round (N_{sol. inorg·.} = 0.3 to 1.7 mg/l N, SRP = 0.04 to 0.63 mg/l P). The N/P ratio is sometimes > 14, sometimes < 10, indicating a variability of the limiting nutrient factor. Considering the nutrient level, the phytoplankton biomass is quite low (about 4,000 cells per ml on average; maximum cell number: 13,000 in 1998 and 10,000 in 1999). The mean epilimnic chlorophyll content (Chl a was 10 mg/l in 1998 and 11 g/l in 1999, and the maximum Chl a content was 16 and 22 g/l in 1998 and 1999, respectively.Phytoplankton production can be limited by nutrients, mainly nitrogen, but convective currents can also cause a significant loss of biomass. The lake's euphotic zone is smaller than its epilimnic zone, indicating that light radiation is limiting in the deeper water body, this is caused by a weak thermocline due to destratification by nocturnal cooling, the atelomixis.     

Comparison of UV and IR Laser Ablation ICP-MS on Silicate Reference Materials and Implementation of Normalisation Factors for Quantitative Measurements

Direct analysis of geological reference materials was performed by LA-ICP-MS using two Nd:YAG laser systems operating at 266 nm and 1064 nm. The aim of this work was to compare UV and IR laser ablation and to assess the potential of the technique for the quantitative bulk analysis of rocks, sediments and soils. The laser sampling process was investigated and the analytical performance of both systems was compared. The influence of the laser operating conditions and the nature of the matrix on ICP-MS response factors calculated for major, minor and trace elements was evaluated. Under consistent laser settings, the response factors appeared to be matrix dependent. For a given matrix, the response factors were also significantly different for the two lasers. Normalisation with a single matrix element was effective only for matrices with similar mineralogy. When operating at 266 nm instead of 1064 nm, matrix effects could be reduced but not overcome. However, variations of the response factors between the different matrices appeared to be similar within distinct groups of elements, reflecting geochemical associations. When using multiple internal standards, matrix effects but also effects of the laser wavelength, could be fully compensated.