The influence of Cr on the garnet–spinel transition in the Earth''s mantle: experiments in the system MgO–Cr2O3–SiO2 and thermodynamic modelling

The position of the transition from spinel peridotite to garnet peridotite in a simplified chemical composition has been determined experimentally at high pressures and high temperatures. The univariant reaction MgCr₂O₄+2Mg₂Si₂O₆=Mg₃Cr₂Si₃O₁₂+Mg₂SiO₄, has a negative slope in P–T space between 1200 °C and 1600 °C. The experimental results, combined with assessed thermodynamic data for MgCr₂O₄, MgSiO₃ and Mg₂SiO₄ give the entropy and enthalpy of formation of knorringite garnet (Mg₃Cr₂Si₃O₁₂). Thermodynamic calculations in simplified chemical compositions indicate that Cr shifts the garnet-in reaction to much higher pressures than previously anticipated. Moreover, in Cr-bearing systems a pressure–temperature field exists where garnet and spinel coexist. The width of this divariant field strongly depends on the Cr/(Cr+Al) of the system.     

Structural changes and valence states in the MgCr<Subscript>2</Subscript>O<Subscript>4</Subscript>–FeCr<Subscript>2</Subscript>O<Subscript>4</Subscript> solid solution series

The influence on the structure of Fe²⁺ Mg substitution was studied in synthetic single crystals belonging to the MgCr₂O₄–FeCr₂O₄ series produced by flux growth at 900–1200 °C in controlled atmosphere. Samples were analyzed by single-crystal X-ray diffraction, electron microprobe analyses, optical absorption-, infrared- and Mössbauer spectroscopy. The Mössbauer data show that iron occurs almost exclusively as ^IVFe²⁺. Only minor Fe³⁺ (<0.005 apfu) was observed in samples with very low total Fe. Optical absorption spectra show that chromium with few exceptions is present as a trivalent cation at the octahedral site. Additional absorption bands attributable to Cr²⁺ and Cr³⁺ at the tetrahedral site are evident in spectra of end-member magnesiochromite and solid-solution crystals with low ferrous contents. Structural parameters a₀, u and T–O increase with chromite content, while the M–O bond distance remains nearly constant, with an average value equal to 1.995(1) Å corresponding to the Cr³⁺ octahedral bond distance. The ideal trend between cell parameter, T–O bond length and Fe²⁺ content (apfu) is described by the following linear relations: a₀=8.3325(5) + 0.0443(8)Fe²⁺ (Å) and T–O=1.9645(6) + 0.033(1)Fe²⁺ (Å) Consequently, Fe²⁺ and Mg tetrahedral bond lengths are equal to 1.998(1) Å and 1.965(1) Å, respectively.     

探地雷达空气回波特点与处理方法

探地雷达发射的电磁波在整个空间传播,存在空气中回波,空气中回波可分为以下3种：直达波、系统振铃、反射回波。直达波位于探地雷达记录的初期很小时间段,对识别地下介质反射影响不大,系统振铃和地表反射体的回波是探地雷达探地工作的主要干扰。空气中反射体的反射回波时距曲线一般有两种形式：双曲线型、线型。可以通过计算介质中电磁波波速来识别反射回波是空气中反射体形成的,还是地下介质反射形成的。应用水平背景移除、二维滤波可以有效滤除探测剖面中的水平和倾斜同向轴干扰信号;利用地下介质和空气中雷达波速进行偏移处理的资料进行对比解释可以有效提高解释的正确性。     

氨基酸在粘土高岭石上吸附等温线的研究

研究了4种氨基酸（甘氨酸，赖氨酸，天冬氨酸，谷氨酸）在粘土高岭石上的吸附等温线以及金属铜离子对其等温线的影响。研究表明，氨基酸在高岭石上的吸附等温线以及金属铜离子存在时的吸附等温线均属Langmuir型等温线；铜离子浓度增加时，其等温线斜率也增加，并认为体系可形成Ⅰ型三元表面络合物，铜离子对氨基酸在高岭石上等温线影响的规律和在相同体系中它对氨基酸在高岭石上交换吸附百分率E（%）-pH曲线的影响规律相一致。     

地月系L_2点中继星激光测距成功率的估算

为了模拟位于地月系L2点的中继星"鹊桥"与月球的位置关系,进而估算中继星激光测距的成功率,按照轨道周期约为14天的要求对中继星所在的晕轨道进行计算,建立了一个综合考虑望远镜抖动、大气抖动和预报轨道横向偏离的模型。从数值上给出了一条轨道周期为14. 78天,X方向(地月连线方向)振幅为12 493 km,Y方向为34 596 km,Z方向(垂直于地月轨道平面方向)为11 916 km的周期轨道。由于晕轨道的最小振幅远大于月球遮挡的临界振幅4 000 km,因此月球对中继星不存在遮挡问题。基于建立的测距成功率模型,根据昆明站(国际编号:7820)的激光测距系统对运行在该轨道上的中继星进行测距成功率分析,结果表明:测距成功率随着中继星横向轨道标准差的增大呈快速降低的趋势。对于中继星到测站的平均距离而言,当中继星没有横向偏离时,探测器产生的光电子数为0. 151,成功率为14. 07%;横向偏离2 km时,光电子数降为0. 035,成功率降为3. 46%。对比最近距离与最远距离的情况,无横向偏离的情况下,探测器产生的光电子数从0. 174降为0. 139,成功率从16. 01%降为13. 02%。该计算结果可为云南天文台1. 2 m望远镜实现中继星激光测距提供参考。     

黄河口总碱度保守与非保守行为探讨

为了阐明黄河口TAlk（总碱度）的行为特征及主要影响因素,根据2004年4月黄河口TAlk实测数据,结合其它化学要素的同步观测资料对其进行了初步探讨.研究结果表明： 黄河口水体在S〈24的区域范围内TAlk呈现出非保守行为,其中 S〈5时TAlk非保守表现为净TAlk的“亏损”, 即水体TAlk低于理论混合TAlk,是由于水体中DIC的沉淀作用引起;在盐度为8～24之间,TAlk非保守表现为净TAlk的“增加”,即水体TAlk高于理论混合TAlk,主要是由于水体中颗粒碳酸盐溶解引起;水体中的CO2参与了颗粒碳酸盐的溶解,并且很可能是影响水体中碳酸盐溶解的主要因素.     

“门”地貌单元的能量耗散和过程机制

基岩岛屿组成的"门"地貌单元是珠江河口区别于世界其他河口的重要地貌特征之一。文章基于重整化群k-ε湍流模型(RNG k-ε)的FLOW3D流体计算模型研究了"门"地貌单元的时均动力结构及湍流能耗特性。"门"地形致动力结构伴随不同类型能耗区。根据能耗空间分布特性可分为核心区(A1区)、混合区(A2区)、上游区(A3区)、下游区(A4区)。"门"地形作用下,不同分区的动力结构、湍流特性、能量转化、能量耗散特征及其驱动机制不同。     

海洋二号微波散射计极地海冰识别算法研究

An Antarctic sea ice identification algorithm on the HY-2A scatterometer(HSCAT) employs backscattering coefficient(σ0) and active polarization ratio(APR) for a preliminary sea ice identification.Then standard deviation(STD) filtering and space filtering are carried out.Finally,it is used to identify sea ice.A process uses a σ0,STD threshold and an APR as sea ice indicators.The sea ice identification results are verified using the sea ice distribution data of the ASMR2 released by the National Snow and Ice Data Center as a reference.The results show very good consistence of sea ice development trends,seasonal changes,area distribution,and sea ice edge distribution of the sea ice identification results obtained by this algorithm relative to the ASMR2 sea ice results.The accuracy of a sea ice coverage is 90.8% versus the ASMR2 sea ice results.This indicates that this algorithm is reliable.     

Spatial variability in the partial pressures of CO2 in the northern Bering and Chukchi seas

In the summers of 1999 and 2003, the 1st and 2nd Chinese National Arctic Research Expeditions measured the partial pressure of CO₂ in the air and surface waters (pCO₂) of the Bering Sea and the western Arctic Ocean. The lowest pCO₂ values were found in continental shelf waters, increased values over the Bering Sea shelf slope, and the highest values in the waters of the Bering Abyssal Plain (BAP) and the Canadian Basin. These differences arise from a combination of various source waters, biological uptake, and seasonal warming. The Chukchi Sea was found to be a carbon dioxide sink, a result of the increased open water due to rapid sea-ice melting, high primary production over the shelf and in marginal ice zones (MIZ), and transport of low pCO₂ waters from the Bering Sea. As a consequence of differences in inflow water masses, relatively low pCO₂ concentrations occurred in the Anadyr waters that dominate the western Bering Strait, and relatively high values in the waters of the Alaskan Coastal Current (ACC) in the eastern strait. The generally lower pCO₂ values found in mid-August compared to at the end of July in the Bering Strait region (66–69°N) are attributed to the presence of phytoplankton blooms. In August, higher pCO₂ than in July between 68.5 and 69°N along 169°W was associated with higher sea-surface temperatures (SST), possibly as an influence of the ACC. In August in the MIZ, pCO₂ was observed to increase along with the temperature, indicating that SST plays an important role when the pack ice melts and recedes.