Temporal and spatial variations in the geochemistry of major and minor particulate and selected dissolved elements of Thermaikos Gulf, Northwestern Aegean Sea

The objectives of this study were to examine both spatial and temporal changes of particulate major elements and minor metals, as well as dissolved Mn and Cd, in the waters of Thermaikos Gulf. Collections of water and suspended particulate matter (SPM), as depth profiles (5–8 depths), were undertaken at 10 principal stations, essentially on a N–S traverse of the western side of the Gulf.One of the principal aims of the study was to observe if there was any change in the patterning of the elements between the three occupations of the stations: (a) in September 2001, immediately before the commencement of trawling; (b) in October 2001, whilst fishing was active; and (c) in winter/early spring conditions (February 2002), when fishing was still active, but after a change of river/atmospheric conditions.Bottom (20 m) waters were dominated by sediment resuspension; this was identified by concentration changes in the aluminosilicate elements (e.g. Al, Ti, K, Fe) of the SPM. A two- to three-fold increase occurred between September and October, caused probably by trawling; this was sustained at the offshore stations, in February. During February, the western inshore stations showed little sediment resuspension, caused by extreme winter cooling and the sinking of water. Consequently, a N–S density discontinuity existed at all water depths, which prevented the thermohaline cyclonic circulation from penetrating into the western seaboard of the Gulf. The distribution of dissolved and particulate Mn in the lower waters was due to redox cycling of the element at the benthic boundary; this was more intense in the north, where the organic supply was higher.Biogenic element concentrations and Ca/Al, Si/Al ratios showed no evidence that trawling activity promoted higher biological production. Strong correlations of Co, Cr, Ni and V, with Al and K, showed that these elements were associated strongly with detrital aluminosilicates. However, the variable association of Cd, Pb and Zn, with K (and Al), especially in the upper waters, implied an anthropogenic source derived from the rivers and the city of Thessaloniki. Examination of the Kd's of Cd showed a two-order of magnitude decrease with depth, caused by resuspension and possible advection of relatively unpolluted sediments, into the western Gulf.     

Estimating global discards and their potential reduction for the Galician fishing fleet (NW Spain)

This study presents the first comprehensive estimation of discard amounts in the Galician fishing fleet, in order to provide an integral view of this increasing environmental problem at a regional scale. Subsequently, a series of improvement actions relating to discard minimization are suggested with the goal of enhancing the performance of the Galician fishing fleet through discard minimization. Discard estimates were constructed individually for the different Galician fisheries by aggregating primary data obtained from a total of 89 fishing vessels and secondary data for those fleets that were not directly sampled. Results showed that roughly 60,250 t of marine organisms were discarded by the Galician fleet in 2008, representing 16.9% of the total capture. Moreover, an important percentage of these discards were linked mainly to trawling vessels and to a lesser extent, to certain long lining fisheries. Therefore, improved management measures in target stocks should take into account the fact that alternative fishing gears other than trawl nets may reduce the amount of discards for certain species. This estimation may improve the assessment of stocks and help to quantify the damage that discards may have on wild ecosystems.     

Environmental assessment of frozen common octopus (Octopus vulgaris) captured by Spanish fishing vessels in the Mauritanian EEZ

Mauritania, one of the most dependent fish trade nations in the world, has an important octopus fishery within its EEZ. Fishing treaties between the EU and this Sub-Saharan nation have permitted 24 Spanish cephalopod trawling vessels to target this species for its export as a frozen product, mainly to Spain, Italy and Japan. This article presents Life Cycle Assessment (LCA) methodology in order to assess and compare the environmental impacts related to the capture, processing and exportation of packed frozen octopus from this fishery to the main importing nations. Environmental results show that frozen common octopus presented a remarkable dominance of the fishing vessel activities, due to the high energy intensity of the fishery and to the fact that these activities include harvesting, processing and preliminary packaging. Post-harvesting activities presented low relative contributions in all impact categories, minimizing the food mile effect of exporting to Japan, thanks to the slow transportation through marine freight of frozen octopus. The results for fishery-specific indicators showed regular trends for trawling fleets, with high discard and seafloor impact rates. Therefore, improvement actions focused on the minimization of energy use and fishery-specific impacts and the shift to less ozone layer damaging cooling agents are the main targets in order to improve the sustainability of this product, as long as the slow freighting characteristics of the imported product are maintained.     

Methods applied in studies of benthic marine debris

The ocean floor is one of the main accumulation sites of marine debris. The study of this kind of debris still lags behind that of shorelines. It is necessary to identify the methods used to evaluate this debris and how the results are presented and interpreted. From the available literature on benthic marine debris (26 studies), six sampling methods were registered: bottom trawl net, sonar, submersible, snorkeling, scuba diving and manta tow. The most frequent method used was bottom trawl net, followed by the three methods of diving. The majority of the debris was classified according to their former use and the results usually expressed as items per unity of area. To facilitate comparisons of the contamination levels among sites and regions some standardization requirements are suggested.     

Chemical composition of short sediment cores from Thermaikos Gulf (Eastern Mediterranean): Sediment accumulation rates, trawling and winnowing effects

Four cores recovered within the framework of the INTERPOL Project have been analysed for their grain size and geochemistry; sediment accumulation rates (SARs) were also determined from ²¹⁰Pb and ¹³⁷Cs profiles. Two cores are representative of the Axios and Aliakmon Rivers depositional environment, whilst the third core represents the Pinios River province; the fourth core represents an environment of outer shelf relict sands. Apparent SARs ranged between 0.667 g cm⁻² yr⁻¹ (Axios and Aliakmon Rivers) and 0.414 g cm⁻² yr⁻¹ (Pinios River). Trawling activities and biomixing are critical processes that may be responsible for the mixing of the surface sediments, as observed from the excess ²¹⁰Pb profiles. The thickness of the surface mixed layer was 4.5 cm in the vicinity of Axios and Aliakmon Rivers and in the area of Pinios River, 3.75 cm on the outer shelf and 1 cm in the area where no trawling was observed. Sediment accumulation appeared to be regulated by variations in the riverine discharge, shelf transport pathways and winnowing processes. Major element variations, such as Si, Al, Ti, V and Ni, were dominated by terrigenous supply as aluminosilicate minerals and quartz, whereas most Ca and Sr were biogenic. Si/Al and Ca/Al ratios have been used to express changes in sediment accumulation and winnowing. Redox processes were depicted by Mn, which showed an increase in the depth of its redoxcline, from 1 cm in inshore stations to 2 cm on the outer shelf. Si/Al ratios follow the Ca/Al ratios and can be used to assess percentage winnowing in the sediment. Increases in these ratios indicate a decrease in sediment input rates and are seen in the upper parts of most of the cores. Anthropogenic or ‘excess’ metal contents have been calculated from Zn/V and Pb/V ratios. Their distributions in the cores showed that by far the highest contamination is associated with the Axios River output, whilst sediments influenced by the Pinios River were relatively uncontaminated.