300°～500℃锌在含氯、氟溶液中的溶解度

实验在300°～500℃,1Kb,用C-CO_2 Ni-NiO作缓冲剂控制fo_2条件下对ZnS在不同浓度、不同pH值的NaCl-H_2O和NaF-H_2O体系中的溶解度进行研究,同时对ZnCl_2在临界条件不同浓度NaCl溶液中迁移能力进行实验,通过实验结果热力学计算和分析,讨论了温度、介质种类、溶液浓度、pH值等影响Zn溶解度的各种主要因素:确定500C 1kb,Zn在含Cl溶液中主要以ZnCl_2~0形式存在.其标准生成自由能△G_(1.ZnCl_2~0)~0 =161.902kJ/mol;F~-对ZnS比Cl~-对ZnS的溶解能力大,在临界条件均一相中、ZnCl_2~0全部汽化迁移,依据实验数据,建立了Zn溶解度函数关系,使特定条件下的实验数据更具普遍意义.     

Paleosubsidence and active subsidence due to evaporite dissolution in the Zaragoza area (Huerva River valley, NE Spain): processes, spatial distribution and protection measures for transport routes

The lowest 17-km long reach of the Huerva River valley, down to its confluence with the Ebro River in Zaragoza city, flows across salt-bearing evaporites of the Ebro Tertiary Basin (NE Spain). Upstream, the horizontally lying Miocene evaporites are interfingered with non-soluble distal alluvial fan facies (shales and sandstones). The proportion of soluble facies in the Huerva River valley increases in a downstream direction towards the basin depocenter. On the basis of the type and magnitude of the paleosubsidence features, the valley has been divided into four reaches. Along reach I, undeformed terrace deposits less than 4 m thick rest on insoluble detrital bedrock. In reaches II and III, dissolution at the alluvium–bedrock boundary has generated local thickening, deformation and paleocollapse structures, which only affect the alluvial mantle. In reach IV, terrace deposits thicken to over 60 m resulting from a large-scale synsedimentary subsidence. In this sector, subsidence locally affects to both the alluvium and the underlying bedrock. This indicates that dissolution acts at the rockhead beneath the alluvial cover (alluvial karst) and within the evaporitic substratum (interstratal karst). The development of an intraevaporitic karst in reach IV is attributed to gypsum and salt dissolution. Irregular terrace gravel bodies (gravel pockets) embedded in a fine-grained matrix associated with paleocollapse structures have been interpreted as liquefaction–fluidization structures resulting from ground acceleration and suction induced by catastrophic collapses. Subsidence is currently active in the region affecting areas with a thin alluvial cover in reaches III and IV. The low subsidence activity in most of Zaragoza city is explained by the presence of thickened (around 50 m) and indurated alluvial deposits. In the surrounding area, numerous buildings in Cadrete and Santa Fe villages have been severely damaged by subsidence. Natural and human-induced subsidence favours the development of slope movements in the gypsum scarp overlooking Cadrete village. Several transport routes including the Imperial Canal (irrigation canal) and the recently completed Madrid–Barcelona high-speed railway are affected by human-induced sinkholes. The paleocollapse structures exposed in the trenches of this railway and a ring road under construction point to hazardous locations underlain by cavities and collapse structures where special protection measures should be applied. Rigid structures are recommended beneath the high-speed railway with sufficient strength to span the larger sinkholes with no deformation. Electronic monitoring devices linked to a warning system can detect subtle subsidence-induced deformations in carriageways or railways. This research demonstrates that the study of the paleokarst helps to understand the processes involved in the present-day subsidence phenomena and their general spatial distribution.     

Benthic primary production, respiration and remineralisation: in situ measurements in the soft-bottom Abra alba community of the western English Channel (North Brittany)

In situ measurements of ammonium and carbon dioxide fluxes were performed using benthic chambers at the end of spring and the end of summer in two soft-bottom Abra alba communities of the western English Channel (North Brittany): the muddy sand community (5 m, about 10% of surface irradiance) and the fine-sand community (19 m, about 1% of surface irradiance). High rates of ammonium regeneration were measured in the two communities at the end of summer (296.03±40.07 and 201.7±62.74 μmolN m⁻² h⁻¹, respectively) as well as high respiration rates (2.60±0.94 and 2.23±0.59 mmolC m⁻² h⁻¹, respectively). Significant benthic gross primary production (up to 6.11 mmolC m⁻² h⁻¹) was measured in the muddy sand community but no benthic primary production was measured in the fine-sand community. It suggests that microphytobenthic production values used in simulations previously published for these two communities were overestimated while values of community respiration were underestimated. The study confirms that this benthic system is heterotrophic and strengthens the idea that an important pelagic-benthic coupling is required for the functioning in such coastal ecosystems.     

Variations in sediment yield over the advance and retreat of a calving glacier, Laguna San Rafael, North Patagonian Icefield

Bathymetric and sub-bottom acoustic data were collected in Laguna San Rafael, Chile, to determine sediment yields during the Little Ice Age advance and subsequent retreat of San Rafael Glacier. The sediment volumes and subaqueous landforms imaged are used to interpret the proglacial dynamics and estimate erosion rates from a temperate tidewater glacier over a complete advance-retreat cycle. Sediment yields from San Rafael Glacier averaged 2.7 × 10⁷ m³/a since the end of the Little Ice Age, circa AD 1898, corresponding to average basin-wide erosion rates of 23 ± 9 mm/a; the highest erosion rates, 68 ± 23 mm/a, occurred at the start of the retreat phase, and have since been steadily decreasing. Erosion rates were much lower during glacial advance, averaging at most 7 mm/a, than during retreat. Such large glacial sediment yields over two centuries of advance and retreat suggest that the contribution of sediments stored subglacially cannot account for much of the sediment being delivered to the terminus today. The detailed sub-bottom information of a proglacial lagoon yields important clues as to the timing of erosion, deposition and transfer of glacigenic sediments from orogens to the continental shelves, and the influence of glacier dynamics on this process.     

Cenozoic detachment folding in the southern Tianshan foreland,NW China: Shortening distances and rates

Intracontinental foreland basins with fold-and-thrust belts on the southern periphery of the Tianshan orogenic belt in China resulted from still-active contractional deformation ultimately cased by the India–Asia collision. To quantify the amounts of shortening distance and the rates of deformation, and to decipher the architectural framework, we mapped the stratigraphy and structure of four anticlines in the Kuqa and Baicheng foreland thrust belts in the central southern Tianshan. In the Baicheng foreland thrust belts, Lower Cretaceous Baxigai and Bashijiqike Formations located in the core of the Kumugeliemu anticline are overlain by the Paleocene to Eocene Kumugeliemu Formation, above which are conformable Oligocene through Pleistocene sediments. A disharmonic transition from parallel to unconformable bedding at the boundary of the Miocene Kangcun and Pliocene Kuqa Formations suggests a change from pre-detachment folded strata to beds deposited on top of a growing anticline. Most of the anticlines have steep limbs (70–90°) and are box to isoclinal folds, suggestive of detachment folding or faulted detachment folding (faults that transect a fold core or limb). Shortening estimates calculated from the cross-sections by the Excess area method indicate that the total shortening for the Kelasu, Kuchetawu, Kezile and Yaken sections are 6.3 km, 6.4 km, 5.8 km and 0.6 km, respectively, and the respective depths of the detachment zones are (2.3 km and 6.9 km), 2.3 km, 2.5 km and 3.4 km. Time estimates derived from a paleomagnetic study indicate that the transition to syn-folding strata occurred at ∼6.5 Ma at the Kuchetawu section along the Kuqa river. In addition, according to our field observations and previous sedimentary rate studies, the initial time of folding of the Yaken anticline was at 0.15–0.21 Ma. Therefore, the average shortening rate that began at ∼6 Ma was ∼2 mm/a for the Kelasu, Kuchetawu and Kezile sections. At 0.15–0.21 Ma, the average shortening rate increased to 3–4 mm/a in the Yaken section. Combined with the recent GPS data, the shortening rate in the central southern Tianshan area increased to 4.7 ± 1.5 mm/a at present. We suggest that there was a linear increase in shortening rate in the southern Tianshan foreland basin, which also indicates that the far field stress increased considerably from the late Miocene to Present in response to the India–Asia collision.     

Subseabed disposal of radioactive waste: effects of consolidational fluid flow

Subseabed disposal of radioactive waste applies a multiple-barrier concept with the sediment being the most important barrier for preventing a release of nuclides into the biosphere. While many investigations have been carried out to analyze the risk potential in this type of disposal, the effects of sediment consolidation and associated fluid flow have not fully been taken into consideration. Here, possible effects of consolidational fluid flow in the penetrator disposal option and possible consequences to the transport of nuclides in the sediment are analyzed. Results of numerical experiments demonstrate that consolidation contributes to the transport of radioactive nuclides released from containers buried in the sediment and to the release of nuclides at the sediment-water interface. Both depend on geological conditions and to a large extent on possible alterations of hydraulic conductivity i of the sediment in the vicinity of the entry path of a penetrator.Symbols c concentration ml m^–3 - c _a concentration of adsorbed solute mg kg^–1 (relative to dry weight of sorbing substance) - c _in solute concentration of source q mg m^–3 - c ₀ initial concentration mg m^–3 - ID dispersion tensorm ²s^–1 - ID ^* diffusion tensor m²s^–1 - D coefficient of dispersion m²s^–1 - d ₀ coefficient of molecular diffusion m²s^–1 - d coefficient of effective diffusion m²s^–1 - g gravity m²s^–1 - h piezometric pressure m - k hydraulic conductivity m²s^–1 - m mass kg - p pressure Pa - q source/sink m³s^–1 - S ₀ specific surface m²m^–3 - t time s - v velocity m s^–1 - x, z cartesian coordinates m - compressibiliy of sediment m²N^–1 - _L longitudinal dispersivity m - effective porosity (decimal fraction) - density kg m^–3 - _s density of sediment kg m^–3 - _w density of water kg m^–3 - decay constant per s - kinematic viscosity m²s^–1     

Global airline networks and nodal regions

Transportation infrastructure has always played an important role in the economic fate of regions. In particular, airline networks have dramatically decreased the geographic and temporal constraints of moving people, goods and information; all of which are increasingly crucial inputs for the information economy. As a result, regions have become more concerned with both the quantity and quality of airline connections. The purpose of this paper is to examine the emerging global hierarchy of airline network connectivity. Using a proprietary database of nearly 900 airline carrier schedules from 2006, we examine regional connectivity between 4,650 worldwide origins and destinations. Through the use of network analysis and graph theoretical techniques, results indicate an increasingly complex web of nodal hierarchies in North America, Europe and Asia.

Fracture void structure: implications for flow, transport and deformation

 This review focuses on studies of flow, transport and deformation processes at a scale of a single discontinuity. The paper provides an evaluation of: (1) various methods suggested for geometrical characterization of void structure; and (2) theoretical and practical problems arising from significant differences between the actual geometry of fracture void structure and its parallel plate representation. The use of an equivalent aperture concept is shown to be seriously misleading in: (a) evaluation of flow regime, and hence selection of appropriate flow laws; (b) correlating tracer and hydraulic tests, and assessment of solute transport properties; and (c) relating hydraulic and mechanical apertures, and predicting influence of stress perturbation and deformability. Received: 2 August 1999 · Accepted: 30 November 1999     

Cosmogenic isotope (Cl) surface exposure dating of the Norber erratics, Yorkshire Dales: Further constraints on the timing of the LGM deglaciation in Britain

Cosmogenic isotope (³⁶Cl) surface exposure dating of four of the erratic boulders at Norber in the Yorkshire Dales National Park, northwest England, yielded mean ages of ∼22.2 ± 2.0 ka BP and ∼18.0 ± 1.6 ka BP for their emplacement. These two mean values derive from different ³⁶Cl production rates used for exposure age calculation. The ages are uncorrected for temporal variations in production rates and may underestimate the true ages by 5-7%. The former age, although implying early deglaciation for this area of the British ice sheet, is not incompatible with minimum deglaciation ages from other contexts and locations in northwest England. However, the latter age is more consistent with the same minimum deglaciation ages and geochronological evidence for ice-free conditions in parts of the northern sector of the Irish Sea. Within uncertainties, the younger of the mean ages from Norber may indicate that boulder emplacement was associated with North Atlantic Heinrich event 1. The limited spatial (downvalley) extent of the Norber boulders implies that at the time of their deposition the ice margin was coincident with the distal margin of the erratic train. Loss of ice cover at Norber was followed by persistent stadial conditions until the abrupt opening of the Lateglacial Interstadial when large carnivorous mammals colonised the area. The ³⁶Cl ages are between ∼3.0 ka and ∼13.0 ka older than previous estimates based on rates of limestone dissolution derived from the heights of pedestals beneath the erratics.     

Spatio-temporal occurrences and mineralogical–geochemical characteristics of airborne dusts in Khuzestan Province (southwestern Iran)

Dust storms in Khuzestan province (Iran) are causing problems in industries and human health. To mitigate the impact of those phenomena, it is vital to know the physical and chemical characteristics of airborne dusts. In this paper, we give an overview of the spatio-temporal occurrences and geochemical characteristics of airborne dusts in Khuzestan. Meteorological data from 10 stations in Khuzestan during 1996–2009 indicate (a) an average of 47 dust storm days per year, (b) a lowest annual average of 13 dust storm days in 1998, (c) a highest annual average of 104 dust storm days in 2008, and (d) an average increase of two dust storm days per year. Above-average number of dust storm days usually occurred in the cities of Dezful, Ahvaz, Masjed-e-Soleiman, Abadan and Bostan, whereas below-average number of dust storm days usually occurred in the cities of Mahshahr, Ramhormoz, Behbahan, Shoushtar and Izeh. XRD analyses of airborne dust samples collected in 2008 and 2009 show that the mineralogy of airborne dusts is dominated by calcite, followed by quartz and then kaolinite, with minor gypsum. SEM analyses of the samples indicate that airborne dusts have rounded irregular, prismatic and rhombic shapes. The sizes of airborne dusts vary from 2 to 52 μm, but 10 to 22 μm are the dominant sizes. The smallest and largest dust particles are clays, sulfates or carbonates. XRF and ICP analyses of the samples show that the most important oxide compositions of airborne dusts are SiO₂, Al₂O₃, Fe₂O₃, CaO and MgO. Estimates of enrichment factors (EF) for all studied elements show that Mn, Hf, U, Sc, K, V and Sr, with EF < 10, are of natural origin, whereas Na, Ni, Co, Ba and Cr, with EF > 10, are of anthropogenic origin. Flat REE patterns with depletion in Th, V, Nb, Zr and enrichment in Al, Rb, Sr and Mn indicate that airborne dusts in Khuzestan come from the same source, which is likely an eroded sedimentary environment outside Iran. In general, airborne dusts in Khuzestan are geochemically similar to airborne dusts elsewhere in the world.