浙江省北部地区土壤元素有效量研究

本文以浙江省北部地区205件碱性土壤采用两种浸提方法取得的重金属可浸提量数据为依据,研究了不同浸提方法元素浸提量差异性及其关系,为农业地质环境研究中土壤元素浸提方法的选择及不同浸提方法取得的数据资料的处理与对比提供了技术方法.以105件典型土壤样的土壤类型、土壤理化指标及全量、有效量资料为依据,研究了土壤元素有效量、有效度的影响因素.其成果是环境评价、地球化学灾害预测与防治、合理肥施的科学依据.     

上海地区基于静力触探的液化判别分析

上海地区(及其他软土地区)以静探触探作为岩土工程勘察的主要原位测试手段,积累了大量的工程数据,其结果稳定可靠,重现性好,具客观性。采用上海地区静探液化判别方法,对收集的大量资料进行统计分析,以期通过静探Ps值快速、简单地作出地基土是否液化的初步判断,有效指导勘察设计工作。     

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.     

包气带硝酸盐分布的差异性及其形成机理:以正定、栾城为例

在地表等量氮输入条件下,包气带中硝酸盐含量分布是其抗污染能力的直接表征。阐明不同包气带中硝酸盐分布的差异并分析其成因对于评价下覆含水层的硝酸盐污染脆弱性、保护地下水资源免遭硝酸盐污染,具有重要意义。本文基于太行山山前冲洪积扇上栾城和正定两个16m深包气带硝酸盐含量数据,指出两个剖面上包气带中硝酸盐分布特征的差异性。分析研究区的施肥历史、大气降水的入渗补给强度及土壤有机质含量,认为包气带水分运移速度和反硝化能力是导致包气带硝酸盐分布差异的两个关键因素。在分析N同位素测试技术进步的基础上,指出利用同位素技术对包气带中的反硝化能力的定量化研究有望取得新进展。     

利用扫描电镜、压汞法、氮气吸附法评价近海黏土孔隙特征

近海地区黏土的微观结构单元--黏土畴中含有大量的粒内孔隙,其孔径小至纳米级,这部分孔隙对黏土的物理指标、水稳性、膨胀性、收缩性等具有重要影响,一般方法很难准确地描述其孔隙特征。试验利用扫描电镜、压汞法、氮气吸附法对湛江黏土的微观孔隙特征及其孔隙发育的控制因素分析,建立微观结构与物理指标、力学行为的相互关系与灵敏性分析。结果表明,湛江黏土具有不良物理性质和良好力学特性指标的异常组合,是一种高灵敏性的强胶结结构性黏性土,其机制主要是：湛江黏土的微观结构为带有胶质联结特性的、定向性无序的开放式絮凝结构,孔隙结构为具有较高的强度和空间稳定性的边－面－角联结的空间网架系统。由于特殊的孔隙网架结构以及“墨水瓶”型孔隙的存在,导致退汞过程出现滞留现象及产生吸附回线。研究表明,联合扫描电镜、压汞法、氮气吸附法能够准确、完整地对近海地区黏土孔隙体系特征进行定性与定量的评价。     

氮、磷、硅对条纹小环藻生长和叶绿素a含量的影响

采用单因子实验方法研究氮、磷和硅营养盐对条纹小环藻(Cyclotella striata)生长和叶绿素a含量的影响。结果表明:在不同磷和硅营养盐浓度下,条纹小环藻比生长率μ变化显著(P<0.05),其中,硝酸盐为0.60~0.85 d-1,硅酸盐为0.49~0.61 d-1,磷酸盐为0.46~0.51 d-1。总体而言,在一定的营养盐浓度范围内,条纹小环藻的最大藻细胞密度Nmax随着氮、磷和硅营养盐浓度的增加而增大;条纹小环藻叶绿素a(Chl a)含量亦随着氮、硅浓度的增加,与Nmax增加趋势一致,但随着磷浓度的增加Chl a先增加后减小,与Nmax不一致。条纹小环藻的主要限制营养元素是氮和硅,而磷可能不会成为其短期培养的限制因子。     

http://dx.doi.org/10.1016/j.gsf.2016.09.005

We propose the nuclear geyser model to elucidate an optimal site to bear the first life.Our model overcomes the difficulties that previously proposed models have encountered.Nuclear geyser is a geyser driven by a natural nuclear reactor,which was likely common in the Hadean Earth,because of a much higher abundance of ~(235)U as nuclear fuel.The nuclear geyser supplies the following:(1)high-density ionizing radiation to promote chemical chain reactions that even tar can be used for intermediate material to restart chemical reactions,(2)a system to maintain the circulation of material and energy,which includes cyclic environmental conditions(warm/cool,dry/wet,etc.)to enable to produce complex organic compounds,(3)a lower temperature than 100℃ as not to break down macromolecular organic compounds,(4)a locally reductive environment depending on rock types exposed along the geyser wall,and(5)a container to confine and accumulate volatile chemicals.These five factors are the necessary conditions that the birth place of life must satisfy.Only the nuclear geyser can meet all five,in contrast to the previously proposed birth sites,such as tidal flat,submarine hydrothermal vent,and outer space.The nuclear reactor and associated geyser,which maintain the circulations of material and energy with its surrounding environment,are regarded as the nuclear geyser system that enables numerous kinds of chemical reactions to synthesize complex organic compounds,and where the most primitive metabolism could be generated.     

非饱和黄土土-水特征曲线与渗透系数Childs & Collis-Geroge模型预测

我国黄土厚度大,黄土地区地下水位深,降雨量少,黄土多处于非饱和状态,土-水特征曲线是非饱和黄土应力状态、强度及渗透性研究的基础。以陇东高原马兰黄土为试验对象,采用张力计法测定原状土样的土-水特征曲线,采用三种理论模型对试验数据拟合,其中Gardner模型简单、参数少,但Fredlund & Xing模型拟合效果最好。基于已测得的土-水特征曲线,采用Childs & Collis-Geroge预测非饱和渗透系数的模型,计算得到非饱和黄土渗透系数与基质吸力或含水率的关系,发现黄土从饱和到非饱和,其渗透系数急剧降低,黄土非饱和渗透系数与基质吸力或体积含水率的关系均可用指数函数表示。本文对典型黄土土-水特征曲线的研究及渗透性的预测为黄土工程问题,如降雨入渗的边坡稳定性评价、非饱和地基湿陷变形计算等提供理论基础。     

自吸水分对煤中瓦斯解吸的综合影响

为研究自吸水分对煤中瓦斯解吸的影响,利用自主设计的实验装置,实现了水分在煤中的自发渗吸,单独研究了水分对瓦斯的置换效应,并对不同含水率条件下煤中瓦斯的置换解吸量、卸压解吸量以及残余瓦斯含量进行了测定。结果表明：水分能够促进煤中吸附态瓦斯发生置换解吸,且含水率越大,置换解吸量越大;卸压解吸过程中,相同时间内含水煤样瓦斯解吸量小于干燥煤,且随着含水率升高,解吸量逐渐减小;充分解吸后含水煤样的残余瓦斯含量小于干燥煤,在4%~10%含水率,随着含水率升高,残余瓦斯含量逐渐降低;针对晋城矿区永红煤矿的无烟煤,自吸水分对瓦斯解吸整体上表现为促进作用,水分对瓦斯解吸的影响是置换效应与水锁效应综合作用的结果。