森林地下碳分配(TBCA)研究进展

森林地下碳分配(TBCA)是森林碳循环的重要通量,对森林碳吸存有十分重要作用.TBCA是森林生态系统GPP中一个最大的汇,可占GPP的21%～61%,土壤呼吸的2/3来自TBCA.目前国际上常用的TBCA测定方法为碳平衡法,在假定地下碳库处于稳定状态时,TBCA可由土壤呼吸减去凋落物量获得,但该方法存在一系列问题.影响森林TBCA的因素有生产力、森林类型、树龄和森林演替阶段、土壤养分和水分有效性、林分密度和树种组成、气候变化因素等.TBCA中各个组成部分均较难以测定和量化,通常假定TBCA中根系呼吸与根系生产力各约占50%,而TBCA中菌根菌和根系分泌物的贡献则仍不清楚.有关TBCA各组分去向及影响机理的研究亦很少.TBCA未来的研究应致力于揭示TBCA的根本驱动因子和其对全球变化的响应机理,以及TBCA转化为土壤新碳的效率及控制因素;同时应提高TBCA测定方法的确定性,特别是应将碳同位素法、微根管法及碳平衡法三者相结合.     

刈割+水淹治理互花米草技术对湿地土壤性状及其有机碳含量的影响

为了监测刈割+水淹+种植秋茄综合治理互花米草对土壤理化特征的影响,于治理前、治理1个月后、治理8个月后采集治理区和对照区(互花米草样地)土壤,测定土壤有机碳含量等理化指标。结果表明,整个治理过程中,互花米草治理区和对照区各土壤层pH值无显著性差异(P>0.05),治理过程未造成土壤pH值的变化;治理区表层土壤(0～10cm)土壤密度显著高于对照区,其他土层则无显著差异(P>0.05),治理过程导致表层土壤板结,土壤密度增大;此外,治理1个月后,治理区表层土壤(0～10cm)有机碳显著高于对照区(P<0.05),治理8个月后则显著低于对照区(P<0.05),治理措施导致土壤表层土壤有机碳含量先增加后降低。总之,刈割+水淹+种植秋茄综合治理互花米草对湿地表层土壤有机碳含量等产生一些影响。     

淮河流域（山东段）南部平原区浅层地下水有机污染特征

随着经济的发展,淮河流域山东段南部平原区地下水污染、环境问题日趋严重。就该区浅层地下水有机污染特征进行了总结,并就污染源、浅层地下水及表层土壤有机污染现状、河流对两侧浅层地下水的影响及污染途径等问题进行了研究。结果表明,该地区浅层地下水中有机组分检出率较低,有机组分中仅有个别指标水质超标,研究区浅层地下水有机污染程度整体较轻。平面分布特征上,有机物检出点及污染严重点主要集中在城镇所在地及周边地区、河道两侧及工矿企业密集区;在垂向分布特征上,浅层地下水的有机污染程度较深层地下水严重,随着深度的增加,污染程度逐渐减弱。     

安徽铜陵矿集区铜官山矿田胶状黄铁矿矿物学特征及其对成矿作用的制约

铜官山矿田是铜陵矿集区内五大矿田之一,矿田内顺层产出的层状硫化物矿体是铜金矿床的主矿体,矿体内含有较多的胶状黄铁矿,其成因的争议制约了对铜金矿床成矿作用的解析。本文主要利用场发射扫描电镜(FE-SEM)等纳米矿物学手段,并结合光学显微镜、粉晶X射线衍射(XRD)、微区激光拉曼光谱分析等方法,对矿田内铜官山矿床及天马山矿床内层状硫化物矿体中胶状黄铁矿矿石的矿物组成、微形貌、微结构等特征进行系统研究,结果表明胶状黄铁矿矿石多呈胶状、鲕状结构,具有同心环状构造,同心环被赤铁矿、菱铁矿与黄铜矿脉穿切。同心环主要由白铁矿+有机质与胶状黄铁矿交替组成。胶状黄铁矿的黄铁矿颗粒粒径从纳米至亚微米均有分布,以自形-半自形立方体为主,少数呈他形,脉体边部胶状黄铁矿颗粒较大,自形程度较高,重结晶显著。矿石中含有少量白云石、伊利石微晶体,与胶状黄铁矿紧密共存,显示典型沉积特征。共存石英磨圆度较高,存在次生加大现象,表面存在胶状黄铁矿印模,显示为碎屑成因。这些综合信息表明胶状黄铁矿非岩浆热液成因,而是与石炭系地层同沉积成岩成因,并可能有微生物作用参与。高孔隙率、高化学活性及较高有机质含量的胶状黄铁矿可能为燕山期岩浆热液演化的含铜成矿流体提供了沉淀剂,对矿田内铜金硫化物矿体的层控性发挥了重要的控制作用。     

Risk Assessment on Organic Contamination of Shallow Groundwater of an Oilfield in Northeast China

With the oil contaminated site of an oil field in northeast as the research area, based on the site geological and hydrogeological conditions, and by virtue of the methods of assessment on current situation of organic contamination and environmental impact assessment as well as leaching mobility assessment on organics, the internal and external risk assessments on organic contamination of shallow groundwater in the research area are conducted respectively. According to the results, about 30 kinds of organic components, including chlorinated hydrocarbons, mononuclear aromatics, heteroaromatic compound, polycyclic aromatic hydrocarbon and n-alkanes, are detected in the shallow groundwater in the research area. The current situation contamination of dichloromethane is the most serious, and all well points are of contamination at medium or above level. Compared with dichloromethane, contamination of trichloromethane and benzene is lighter, but several seriously contaminated well points occur in these two groups. The leaching mobility of dichloromethane, trichloromethane and benzene is extremely high, posing the greatest contamination risks against groundwater.     

济阳坳陷古近系沙四段上亚段烃源岩沉积有机相研究

根据沉积构造、古生物组合、有机质赋存方式等特征研究,明确了沉积过程底水含氧量对古近系湖相烃源岩中有机 质的组成和含量的控制作用。在此基础上借鉴沉积有机相和古氧相研究的成果,将济阳坳陷古近系沙四段上亚段湖相烃源 岩划分为四种沉积有机相,分别为缺氧相、短暂充氧相、低氧相、充氧相,并且确定了不同类型沉积有机相的判识标志。 并结合测井资料开展了烃源岩沉积有机相的单井、连井及平面分布特征分析,提出沙四段上亚段烃源岩的发育存在着明显 的东西差异,东部地区明显优于西部地区,而不同走向断裂的活动差异控制了优质烃源岩的分布。沙四段上亚段烃源岩的 分布规律对于下一步勘探决策的制定和深层隐蔽油气藏成藏规律研究具有重要意义。     

Development of a diatom-based model for inferring total phosphorus in southeastern Australian water storages

Diatom-based transfer functions for inferring epilimnetic total phosphorus (TP) have been developed from a data set of 33 southeastern Australian water storages. Regular institutional monitoring of these sites has allowed comparison of models developed from TP data covering different time periods. A model based on mean annual TP performs better than models derived from winter maximum TP, spring minimum TP or TP nearest the time of diatom sampling. A mean annual TP model (WA-PLS 2 component) has a jack-knifed diatom-inferred versus measured TP correlation coefficient (r ² _jack) of 0.69 and a root-mean-square-error of prediction (RMSEP) of 0.246 log₁₀g TP l^–1, while alternative models have RMSEP > 0.27. Deletion of two samples with uncharacteristic species composition and environmental conditions improved performance of the mean annual TP model (r ² _jack= 0.74; RMSEP = 0.233 log₁₀g TP l^–1). Comparison with other published diatom-TP calibration models indicates that this model performs relatively well, with possible contributing factors including the extensive characterisation of TP (with an average 15 determinations making up the annual mean) and the dominance of planktonic diatoms in most sites. Downcore application of the model will allow the reconstruction of reservoir nutrient histories since commissioning, and thus provide a basis for understanding and management of reservoirs.     

Loss on ignition: a qualitative or quantitative method for organic matter and carbonate mineral content in sediments?

Since the publication of the paper of , loss on ignition (LOI) has been widely used as a method to estimate the amount of organic matter and carbonate mineral content (and indirectly of organic and inorganic carbon) in sediments. The relationships between LOI at 550 °C (LOI₅₅₀) and organic carbon (OC) content and between LOI at 950 °C (LOI₉₅₀) and inorganic carbon (IC) content are currently accepted as a standard. However, the comparison of 150 analyses of samples of diverse lithologies, collected from a single core, reveals that these relationships are affected by sediment composition (presence of clays, salts, and the variable content of organic carbon). This results in an incremental error on the estimation of carbon content from LOI values that invalidates the use of LOI values as a quantitative method for estimating carbon content. Conversely, the general trends of LOI₅₅₀ and LOI₉₅₀ show a good correlation with carbon content (both organic and inorganic) allowing use of LOI as a qualitative test for carbon content. Similarly, in our case, LOI at 105 °C (LOI₁₀₅) is a good qualitative proxy for the trends in gypsum content.     

OPTIMIZATION IN ORGANIC SYNTHESIS.AN APPROACH TO OBTAINING KINETIC INFORMATION BY SEQUENTIAL RESPONSE SURFACE MODELLING.OUTLINE OF THE PRINCIPLES

A method is presented by which it is possible to estimate the initial rate of chemical reactions when theexperimental conditions are varied according to a response surface design.The method is intended as acomplementary method for analysing data obtained from experiments in synthetic chemistry when theobjective is to optimize the yield of the reaction.Data obtained by simulations have been used to develop the method.From the simulated reactions itis shown that sequential analysis of the chemical yield of the reaction makes it possible to estimate modelswhich describe how the parameters of the response surface of the yield vary over time.The derivativesof these time functions of the response surface parameters can be used to define a rate function whichdescribes how the variations in the experimental conditions influence the rate of the reaction.It is shown how such rate functions can be used to afford reasonable estimates of the initial rates ofthe reaction.The initial reaction rates thus estimated can be used to determine the kinetic order of thereactants and also to provide estimates of the activation energy of the reaction.A thorough discussion of how canonical analysis of the rate function may assist in the elucidation ofreaction mechanisms is given.     

盐场卤水成色原因分析及脱色方法研究

以天津汉沽盐场高镁卤水为研究对象,对其杂质形式、成色原因进行了系统分析。研究表明,卤水中的成色物质主要是大量的饱和脂类、羧酸类、醇醚类、胺类及不饱和的芳烃类、醛酮类、烯烃类等有机物质,经过氧化氢氧化-氢氧化锆吸附联合脱色工艺后,卤水色度及CODCr去除率分别可达99%和85%,镁离子的损失率可控制在1%以下,吸附剂氢氧化锆经脱附再生后可循环使用,大大降低了工艺运行成本。