黄海、东海水体总吸收系数光谱特性及其统计反演模式研究

利用现场实测的表观光学量和固有光学量数据,得到了我国黄海、东海近岸二类水体多个波段的总吸收系数的统计反演模式。此反演模式采用412/555、490/555两个波段遥感反射比比值的二项式,得到波长412、440、488、510、532、555nm处的总吸收系数,其反演值和实测值的平均相对误差不大于25.8%,相关系数R2达到了0.75到0.85。水体总吸收系数几种统计模型的误差敏感性分析表明,反演模式对±5%的遥感反射比输入误差导致结果增加误差最大为24.0%,因此反演模式是可用的。同时给出了412、488、510、532、555nm各波段的总吸收系数同波段440nm的总吸收系数之间的关系。结果表明,在400—600nm波段范围内,每一个波段的总吸收系数与440nm波段的总吸收系数的相关性均较高,相关系数R2都超过了0.99。通过对拟合直线的斜率与波长进行回归,得到斜率和波长的关系,其相关系数R2为0.99,这样利用本文中建立的各波段总吸收系数关系模型,可以从一个已知波段的总吸收系数反演出任何另外一个波段的总吸收系数,这就在水色反演与应用中大大减少了未知因子的个数。     

Elemental and organic carbon in atmospheric aerosols at downtown and suburban sites in Prague

Organic and elemental carbon (OC and EC) content in PM₁₀ was studied at two sites in Prague, which were located in a suburb and in the downtown. Similar overall average levels were found for both species and also for the PM₁₀ mass at the two sites (i.e., 5.5 and 4.8 μg/m³ for OC, 0.74 and 0.80 μg/m³ for EC, and 33 μg/m³ and 37 μg/m³ for the PM₁₀ mass at the suburb and downtown site, respectively), but substantial differences were observed between the two sites in some seasons and/or meteorological situations. Approximately three times higher values were found for OC in winter compared to summer, with a higher winter/summer ratio for the suburban site. The differences for EC were smaller, but still, compared to summer, more than two times higher EC levels were observed during autumn at the suburban site and 1.5 higher EC levels in winter and autumn at the downtown site. The lowest OC to EC ratios at the suburban site were 3.4, while they were around 1.3 for the downtown site. It was found that the origin of the air masses had a major impact on the observed PM₁₀ mass and OC levels, with largest concentrations noted for air masses recirculating over central Europe and arriving from southeastern Europe in winter. Trajectories coming from the west and northwest originating above the Atlantic Ocean and the Artic brought the cleanest air masses to the sites. For EC the largest difference between the two sites was observed for northwesterly winds during the non-heating season when the suburban site was upwind of Prague.     

新疆太阳总辐射资料的均一性检验与气候学估算式的再探讨

参照新疆105个气象台站＂元数据＂,在对12个辐射站逐月日照百分率与月总辐射资料序列进行质量控制检验的基础上,对无效值与缺测值进行了插补订正,继而以Potter非均一性客观检验方法对资料序列进行了非均一性检测,同时以SNTH方法对产生间断的序列进行了相应的非均一化订正。在均一化的月总辐射与月日照百分率资料序列基础上,探...     

Investigation of the ozone and trace gases contribution to the total optical depth in the polluted urban environment of Athens

This study focuses on the determination of optical depths caused by ozone and trace gases absorption in the Chappuis band, 500–700 nm, and the contribution to the Total Minus Rayleigh Optical Depth (TMROD). The optical depths were derived using the transmission functions implemented in the SMARTS parametric model, while the Total Optical Depths (TODs) were derived by solar extinction measurements obtained in Athens during May 1995. From the data analysis it is obvious that both the ozone and trace gases contribute significantly to TMROD in the Chappuis band. More specifically, the trace gases contributions are higher for air with high pollution levels, while ozone's contribution can be significant under clear-sky conditions. Therefore, the correction in TMROD due to ozone and trace gases optical depths is necessary for an accurate determination of the Aerosol Optical Depth (AOD) in the Chappuis band. The optical depth of ozone is generally removed during the process of the AOD retrievals, since the significance of its absorption in the Chappuis band is well understood. Nevertheless, the optical depth of the trace gases (mainly NO₂) is not always taken into account in the AOD retrievals, though its contribution can be significant in urban polluted atmospheres. In this respect, the present study attempts to quantify the ozone and trace gases contributions in an urban environment and to provide some new functions that help estimate the contribution of ozone to the TMROD in the Chappuis band.     

太平洋海气CO2通量对气候事件的响应

应用一个嵌套了海洋生物地球化学循环的太平洋环流碳循环模式,分析了1960～2000年太平洋不同海区海气碳通量随时间的变化。模拟结果显示,赤道太平洋为大气CO₂的排放区,南、北太平洋(南、北纬15°至模式计算区域南、北边界)为吸收区。3个海区海气碳通量随时间均存在显著的波动,其中赤道太平洋海气碳通量年际波动最显著。3个海区海气碳通量年际波动对气候事件的响应并不一致,在El Niño年赤道太平洋冷舌的强度和总溶解无机碳(DIC)的浓度以及输出生产力均会受到上升流减弱的影响而降低,La Niña年这些海气碳通量控制要素的分布情况则正好相反,但在南北太平洋副热带以及高纬度海区,El Niño和La Niña对这些要素带来的影响却并不一定相反,对输出生产力的影响甚至是一致的。以海表温度(SST)为例考察海气碳通量与物理场之间的关系表明,在赤道太平洋上升流对DIC的影响是控制海气碳通量变化的主要因素,而在其他海区,尤其是副热带海区,由于垂直运动的年际变化较小,且生物生产力水平较低,SST的波动对海气碳通量年际变化的影响更加重要。     

青藏高原春季不同地区臭氧和大气温度变化趋势的差异性

利用1979—2018年太阳后向散射紫外辐射计SBUV(/2)星下点臭氧遥感资料,结合ERA-Interim和MERRA-2大气温度再分析资料,考察青藏高原区域内拉萨和共和两地春季臭氧和大气温度变化趋势的差异性。结果表明拉萨和共和两个地区的臭氧和大气温度逆转趋势均发生于1999年。对比2008年以来青藏高原整体臭氧总量变化速率（4.5 DU/(10 a)),拉萨臭氧总量变化更快,为5.9 DU/(10 a),共和相对较慢,仅为3.7 DU/(10 a);同时,1999年以来拉萨和共和春季下平流层（100~30 hPa）大气温度分别以0.5~1.4℃/(10 a)和0.01~0.9℃/(10 a)速率增加,上对流层(250~175 hPa)大气温度分别以0.2~1.5℃/(10 a)和0.2~1.2℃/(10 a)速率降低。与2008年以来高原整体大气温度变化相比较,均慢于高原下平流层（125~70 hPa) 1~2℃/(10 a)的增温速率,快于高原上对流层（225~175 hPa）0.4~1.1℃/(10 a)的降温速率。两地臭氧与大气温度的相关系数和回归系数计算结果表明,拉萨和共和两个地区1999年以来春季臭氧恢复速率的不同是导致两地同期下平流层-上对流层温度逆转速率差异的重要因子之一。     

1961～2017年雅鲁藏布江河谷地区夏季气候暖干化趋势

基于1961～2017年青藏高原腹地雅鲁藏布江河谷地区4个站（拉萨、日喀则、泽当和江孜）夏季（6～8月）月平均气温、降水和相对湿度等观测资料,分析了该地区夏季气候年际和年代际演变特征,并探讨了气温、降水和相对湿度在年际和年代际时间尺度上的相互关系以及与总云量和地面水汽压的联系。结果表明:（1）1961～2017年该地区夏季气候出现了暖干化趋势。气温（相对湿度）显著升高（下降）,降水趋势变化不明显;本世纪初气温（相对湿度）均发生了显著的突变。（2）该地区夏季气候因子间在年际和年代际时间尺度上存在密切关系:气温与相对湿度和降水均存在明显的负相关,降水与相对湿度为正相关。（3）该地区夏季气候因子间的年际和年代际变化与同期总云量和地面水汽变化有关。1961～2017年总云量持续减少是气温显著升高的主要原因之一,气温的显著升高和降水变化不明显又造成了相对湿度的显著下降。     

Study of the total lightning activity in a hailstorm

A thunderstorm that developed over northeastern Spain on 16 June 2006 is analyzed. This severe thunderstorm produced hailstones as large as 40 mm and had a lifetime of 3 h and 30 min. Radar cross-sections show strong vertical development with cloud echo tops reaching an altitude of 13 km. The specific characteristics of the lightning activity of this storm were: (i) a large amount (81%) of negative cloud-to-ground (−CG) flashes with very low peak currents (< 10 kA in absolute value), (ii) a very large proportion of intra-cloud (IC) flashes with an IC/CG ratio reaching about 400, (iii) a large number of “short” IC flashes (with only 1-VHF source according to SAFIR detection), (iv) a large increase of the −CG flash rate and of the CG proportion near the end of the storm. The rate of −CG flashes with a low peak current were observed to evolve similarly to the rates of IC flashes. Most of them have been assumed to be IC flashes misclassified by the Spanish Lightning Detection Network (SLDN). They have been filtered as it is usually done for misclassified +CG flashes. After this filtering, CG flash rates remained very low (< 1 min^− 1) with +CG flashes sometimes dominant. All the particular lightning activity characteristics similar to those observed in the Severe Thunderstorm Electrification and Precipitation Study (STEPS) campaigns support the hypothesis that this thunderstorm could have had an inverted-polarity or complex charge structure. The maximum IC flash rate (67 min^− 1) peaked 24 min before the presence of reflectivity higher than 60 dBZ. The IC activity abruptly decreased during the period when reflectivity was dramatically increasing. The time of maximum reflectivity observed by radar was consistent with the times of reported hail at the ground.     

保定市大气颗粒物中含碳组分粒径分布

北京-天津-河北地区工业城市保定大气颗粒物(Particulate matter,PM)污染严重,保定大气颗粒物尤其是细粒子和超细粒子污染严重,其中含碳组分具有重大贡献,PM1.1、PM2.1和PM2.1-9.0中含碳气溶胶总量(total carbonaceous aerosols,TCA)分别占到(49±20)%、(45±19)%和(19±7)%。PM9.0中的含碳气溶胶主要富集在PM2.1乃至PM1.1中。颗粒物浓度谱分布及含碳气溶胶富集量呈显著季节变化,由于采暖过程秋冬季各粒径段有机碳(organic carbon,OC)和元素碳(elemental carbon,EC)的浓度均增加,秋、冬季节细颗粒物中OC浓度可高达44.0±38.3、78.5±30.2μg m-3,EC浓度分别为3.5±1.6、8.5±6.8μg m-3。各个季节OC和EC在总悬浮颗粒物(total suspended particulate,TSP)中的几何平均直径(geometric mean diameter,GMD)均集中在较小粒径段。粗颗粒物中OC的GMD在春夏季较高,秋季减少,而冬季最低。而粗颗粒物中EC的GMD则是冬季最高,夏季最低。保定0.4μm的颗粒物中OC/EC比值4个季节的水平较为稳定,春、夏、秋、冬季OC/EC比值分别为5.2、3.5、4.1和5.4,来源主要为交通和燃煤。其余几个粒径段的颗粒物的来源更为复杂,其来源主要为燃煤、木材和生物质。     

关于沥青成因的讨论

以英国北威尔士和我国黔东湘西、新疆乌尔禾和塔里木的沥青为例,讨论了沥青的 Pb、Sr、Nd 同位素地球化学特征。结果表明:(1)沥青(前身物石油)的形成可能有多种途径,如壳源有机物生成(北威尔士、黔东湘西)和深源无机合成,后者的地质环境为地幔俯冲带(乌尔禾沥青)或下地壳麻粒岩相(塔里木);(2)沥青生成的时代比习惯认为的要古老得多。Pb、Sr、Nd 同位素还可给出原油运移、沥青沉淀的年龄。深入研究沥青的成因,对油气资源评价、勘探目标选择有重要意义。