保定市大气颗粒物中含碳组分粒径分布

北京-天津-河北地区工业城市保定大气颗粒物(Particulate matter,PM)污染严重,保定大气颗粒物尤其是细粒子和超细粒子污染严重,其中含碳组分具有重大贡献,PM1.1、PM2.1和PM2.1-9.0中含碳气溶胶总量(total carbonaceous aerosols,TCA)分别占到(49±20)%、(45±19)%和(19±7)%。PM9.0中的含碳气溶胶主要富集在PM2.1乃至PM1.1中。颗粒物浓度谱分布及含碳气溶胶富集量呈显著季节变化,由于采暖过程秋冬季各粒径段有机碳(organic carbon,OC)和元素碳(elemental carbon,EC)的浓度均增加,秋、冬季节细颗粒物中OC浓度可高达44.0±38.3、78.5±30.2μg m-3,EC浓度分别为3.5±1.6、8.5±6.8μg m-3。各个季节OC和EC在总悬浮颗粒物(total suspended particulate,TSP)中的几何平均直径(geometric mean diameter,GMD)均集中在较小粒径段。粗颗粒物中OC的GMD在春夏季较高,秋季减少,而冬季最低。而粗颗粒物中EC的GMD则是冬季最高,夏季最低。保定0.4μm的颗粒物中OC/EC比值4个季节的水平较为稳定,春、夏、秋、冬季OC/EC比值分别为5.2、3.5、4.1和5.4,来源主要为交通和燃煤。其余几个粒径段的颗粒物的来源更为复杂,其来源主要为燃煤、木材和生物质。     

Elemental and organic carbon in atmospheric aerosols at downtown and suburban sites in Prague

Organic and elemental carbon (OC and EC) content in PM₁₀ was studied at two sites in Prague, which were located in a suburb and in the downtown. Similar overall average levels were found for both species and also for the PM₁₀ mass at the two sites (i.e., 5.5 and 4.8 μg/m³ for OC, 0.74 and 0.80 μg/m³ for EC, and 33 μg/m³ and 37 μg/m³ for the PM₁₀ mass at the suburb and downtown site, respectively), but substantial differences were observed between the two sites in some seasons and/or meteorological situations. Approximately three times higher values were found for OC in winter compared to summer, with a higher winter/summer ratio for the suburban site. The differences for EC were smaller, but still, compared to summer, more than two times higher EC levels were observed during autumn at the suburban site and 1.5 higher EC levels in winter and autumn at the downtown site. The lowest OC to EC ratios at the suburban site were 3.4, while they were around 1.3 for the downtown site. It was found that the origin of the air masses had a major impact on the observed PM₁₀ mass and OC levels, with largest concentrations noted for air masses recirculating over central Europe and arriving from southeastern Europe in winter. Trajectories coming from the west and northwest originating above the Atlantic Ocean and the Artic brought the cleanest air masses to the sites. For EC the largest difference between the two sites was observed for northwesterly winds during the non-heating season when the suburban site was upwind of Prague.     

Investigation of the ozone and trace gases contribution to the total optical depth in the polluted urban environment of Athens

This study focuses on the determination of optical depths caused by ozone and trace gases absorption in the Chappuis band, 500–700 nm, and the contribution to the Total Minus Rayleigh Optical Depth (TMROD). The optical depths were derived using the transmission functions implemented in the SMARTS parametric model, while the Total Optical Depths (TODs) were derived by solar extinction measurements obtained in Athens during May 1995. From the data analysis it is obvious that both the ozone and trace gases contribute significantly to TMROD in the Chappuis band. More specifically, the trace gases contributions are higher for air with high pollution levels, while ozone's contribution can be significant under clear-sky conditions. Therefore, the correction in TMROD due to ozone and trace gases optical depths is necessary for an accurate determination of the Aerosol Optical Depth (AOD) in the Chappuis band. The optical depth of ozone is generally removed during the process of the AOD retrievals, since the significance of its absorption in the Chappuis band is well understood. Nevertheless, the optical depth of the trace gases (mainly NO₂) is not always taken into account in the AOD retrievals, though its contribution can be significant in urban polluted atmospheres. In this respect, the present study attempts to quantify the ozone and trace gases contributions in an urban environment and to provide some new functions that help estimate the contribution of ozone to the TMROD in the Chappuis band.     

1960~2012年中国地区总云量时空变化及其与气温和水汽的关系

基于我国地区543个地面气象台站观测的总云量、平均气温和相对湿度日均值资料,采用正交经验函数（EOF）、气候倾向率和线性趋势分析等方法,研究了1960~2012年总云量的时空变化特征及其与气温和水汽的关系。结果表明:（1）我国地区总云量呈南多北少的带状分布特征,最大值在四川盆地（82%）。近53年来总云量气候倾向率为-0.8%（10a）-1,趋势系数为-0.68,通过了99.9%的信度检验。（2）总云量季节变化特点明显,夏季最多,春秋季次之,冬季最少,其中春季、夏季和秋季有显著的下降趋势。（3）EOF分解的前两个模态表明总云量不仅具有一致减少的变化特征,还具有明显的区域差异。以此同时,平均气温和相对湿度不论在总体变化趋势、地区差异、还是时间演变上,均与总云量保持较高的一致性,进一步证明总云量的变化与气温和水汽有密切关系。     

青藏高原春季不同地区臭氧和大气温度变化趋势的差异性

利用1979—2018年太阳后向散射紫外辐射计SBUV(/2)星下点臭氧遥感资料,结合ERA-Interim和MERRA-2大气温度再分析资料,考察青藏高原区域内拉萨和共和两地春季臭氧和大气温度变化趋势的差异性。结果表明拉萨和共和两个地区的臭氧和大气温度逆转趋势均发生于1999年。对比2008年以来青藏高原整体臭氧总量变化速率（4.5 DU/(10 a)),拉萨臭氧总量变化更快,为5.9 DU/(10 a),共和相对较慢,仅为3.7 DU/(10 a);同时,1999年以来拉萨和共和春季下平流层（100~30 hPa）大气温度分别以0.5~1.4℃/(10 a)和0.01~0.9℃/(10 a)速率增加,上对流层(250~175 hPa)大气温度分别以0.2~1.5℃/(10 a)和0.2~1.2℃/(10 a)速率降低。与2008年以来高原整体大气温度变化相比较,均慢于高原下平流层（125~70 hPa) 1~2℃/(10 a)的增温速率,快于高原上对流层（225~175 hPa）0.4~1.1℃/(10 a)的降温速率。两地臭氧与大气温度的相关系数和回归系数计算结果表明,拉萨和共和两个地区1999年以来春季臭氧恢复速率的不同是导致两地同期下平流层-上对流层温度逆转速率差异的重要因子之一。     

1961～2017年雅鲁藏布江河谷地区夏季气候暖干化趋势

基于1961～2017年青藏高原腹地雅鲁藏布江河谷地区4个站（拉萨、日喀则、泽当和江孜）夏季（6～8月）月平均气温、降水和相对湿度等观测资料,分析了该地区夏季气候年际和年代际演变特征,并探讨了气温、降水和相对湿度在年际和年代际时间尺度上的相互关系以及与总云量和地面水汽压的联系。结果表明:（1）1961～2017年该地区夏季气候出现了暖干化趋势。气温（相对湿度）显著升高（下降）,降水趋势变化不明显;本世纪初气温（相对湿度）均发生了显著的突变。（2）该地区夏季气候因子间在年际和年代际时间尺度上存在密切关系:气温与相对湿度和降水均存在明显的负相关,降水与相对湿度为正相关。（3）该地区夏季气候因子间的年际和年代际变化与同期总云量和地面水汽变化有关。1961～2017年总云量持续减少是气温显著升高的主要原因之一,气温的显著升高和降水变化不明显又造成了相对湿度的显著下降。     

Emission of fine organic aerosol from traditional charcoal broiling in China

The indoor PM_2.5 aerosol samples for charcoal broiling source under Chinese traditional charbroiling and the ambient fine aerosols samples (PM_2.5) were collected in Beijing to investigate the characteristics of the charcoal broiling source and its impact on the fine organic aerosols in the atmosphere. The concentrations of 20 species of the trace organic compounds, including polycyclic aromatic hydrocarbons (PAHs), fatty acids, levoglucosan, and cholesterol in PM_2.5 were identified and quantified by GC/MS. The total PAHs and fatty acids emitted from charcoal broiling to PM_2.5 were 8.97 and 87,000 ng mg⁻¹ respectively. The concentrations of the light molecular weight (LMW) 3- and 4-ring PAHs were much higher than those of the high molecular weight (HMW) 5- and 6-ring PAHs. Fatty acids were the most abundant species in source profile, accounting for over 90% of all identified organic compounds. More polyunsaturated fatty acid (linoleic acids) than the saturated fatty acid (stearic acids) emitted in the cooking. Charcoal broiling is a minor source of PAHs compared to the source of biomass burning. Comparing the ratios of levoglucosan/fatty acid and levoglucosan/cholesterol in the charcoal broiling samples to the ambient samples, it is evident that meat cooking is an important source of fatty acids, but a less important source of cholesterol. Cooking, as one of the source of fine organic particles, plus other anthropogenic sources would be related to the formation of the severe haze occurred and spread over the urban atmosphere in most of the cities of China in the past several years.     

Carbonaceous materials in size-segregated atmospheric aerosols from urban and coastal-rural areas at the Western European Coast

A high-volume cascade impactor, equipped with a PM10 inlet, was used to collect size-segregated aerosol samples during the summer of 2004 at two Portuguese locations: a coastal-rural area (Moitinhos) and an urban area (Oporto). Concentrations of airborne particulate matter (PM), total carbon (TC), organic carbon (OC), elemental carbon (EC), and water-soluble organic carbon (WSOC) were determined for the following particle size ranges: < 0.49, 0.49–0.95, 0.95–3.0, and 3.0–10 µm. The total PM mass concentrations at the urban and coastal-rural sites ranged from 22.8 to 79.6 μg m^− 3 and 19.9 to 28.2 μg m^− 3, respectively, and more than 56% of the total aerosol mass was found in the fractions below 3.0 μm. At both locations the highest concentrations of OC and EC were found in the submicrometer size range. The regional variability for the OC and EC concentrations, with the highest concentrations being found in the urban area, was related to the contribution of local primary sources (mostly traffic emissions). It was also verified an enrichment of the small size particles in WSOC, representing on average 37.3(± 12.4)% and 59.7(± 18.0)% of OC in the very fine aerosol at the coastal-rural and urban areas, respectively. The amount of secondary OC calculated by the minimum OC/EC ratio method indicates that secondary organic aerosol formation was important throughout the study at both sites. The obtained results suggest that long-range transport and favourable summer conditions for photochemical oxidation are key factors determining secondary OC formation in the coastal-rural and urban areas. The ultraviolet absorption properties of the chromophoric constituents of the WSOC fractions were also different among the different particle size ranges and also between the two sampling locations, thus suggesting the strong impact of the diverse emission sources into the composition of the size-segregated organic aerosol.     

Case study of cloud physical and chemical processes in low clouds at Mt. Brocken

Frequency distributions of cloud base height and cloud type of low clouds observed between May and October 1998 at Mt. Brocken (Germany) have been derived from ceilometer measurements and synoptic observations. The summit at 1142 m a.s.l. was about 50% of that time in cloud. During daytime, Stratus clouds were the dominant cloud type (65%), whereas Cumulus clouds amounted to 27% and Stratocumulus clouds to 8%. Evidence was found that the increase of the cloud base height observed at Mt. Brocken continues since the end of the 1980s. An example for a clear anticorrelation between the liquid water content (LWC) of the cloud and the height above cloud base is shown. Other results of this detailed case study of a cloud event on October 8, 1998 concerning phase partitioning of water-soluble inorganic compounds, black carbon (BC) and organic carbon (OC) between the liquid and the interstitial phase will also be presented. The observed ion-specific increase in the solute mass per cubic meter of air with decrease of the distance between sampling position and cloud base was caused mainly by entrainment of air from the below-cloud layer. As expected, for sulfate, ammonia and nitrate, high scavenging coefficients (>0.8) were found. OC exhibits a high scavenging fraction of between 0.4 and 0.7; the value for black carbon (0.2–0.4) implies that soot was possibly to some extent internally mixed in the cloud condensation nuclei (CCN). Simultaneous measurements during a cloud event of HNO₂ and HNO₃ in the gas phase and N(III) and N(V) in the liquid phase were made for the first time.     

新疆太阳总辐射资料的均一性检验与气候学估算式的再探讨

参照新疆105个气象台站＂元数据＂,在对12个辐射站逐月日照百分率与月总辐射资料序列进行质量控制检验的基础上,对无效值与缺测值进行了插补订正,继而以Potter非均一性客观检验方法对资料序列进行了非均一性检测,同时以SNTH方法对产生间断的序列进行了相应的非均一化订正。在均一化的月总辐射与月日照百分率资料序列基础上,探...