Coupled Reactive Transport Modeling of Redox Processes in a Nitrate-Polluted Sandy Aquifer

The reactive transport modeling of a complicated suite of reactions apparent in the aquifer during the application of N-containing fertilizers is reported. The unconfined sandy aquifer can be subdivided into an oxic zone which contains groundwater with oxygen and nitrate and an anoxic zone characterized by elevated iron and sulfate concentrations in groundwater. Oxygen and nitrate are being reduced by pyrite and organic matter that commonly apparent in the aquifer. The oxidation of pyrite is modeled using the local equilibrium approach, whereas decomposition of organic matter, with the adoption of kinetic approach. The system is buffered by dissolution of aluminum and iron oxides. The modeling process is a two-step procedure. First, the processes are modeled in the one-dimensional (1D) column using PHREEQC code. Subsequently, the calibrated and verified data were copied and used in two-dimensional (2D) PHAST model. Prior to the performance of reactive transport modeling operations with PHAST, a reliable flow model was executed. Finally, predictions are made for the distribution of water chemistry for the year 2008. Model predicts that sulfate derived from the ongoing pyrite oxidation is reduced by the dissolved organic carbon at the higher depth and forms pyrite by the reaction with iron. The results of this study highlight the importance of understanding the interplay between the transport and chemical reactions that occur during the input of nitrate to the aquifer. Reactive transport modeling incorporating the use of a newly developed code PHAST have proved to be a powerful tool for analyzing and quantifying such interactions.     

Race/Ethnicity in Visual Imagery of Dutch Nature Conservation Organizations

Nature conservation organizations in various Western countries, including the Netherlands, have noted that racial/ethnic minorities compared to Whites are “underparticipating” in recreation in natural areas and in nature conservation practices. Previous research trying to explain (under-)participation by racial/ethnic minorities in outdoor recreation and nature conservation mainly focused on characteristics of racial/ethnic groups. This study argues that nature conservation organizations themselves—although in all likelihood unintentionally—may play a role in participation of racial/ethnic minorities as well, through their promotional material. A content analysis of 22,974 pictures in magazines and on websites of four large Dutch nature conservation organizations shows that only 3.8% of the depicted people were non-White. Our results indicate that visual imagery of nature conservation organizations, at least in the Netherlands, (re)produces an image of outdoor recreation and nature conservation as being activities almost exclusively performed by Whites.     

工业测量系统最新进展及应用

主要介绍了四种工业测量系统，即经纬仪、全站仪、激光跟踪以及数字近景摄影测量系统的原理及最新进展，还介绍了工业测量系统在天线检测、顶管施工、大坝变形监测及水库闸门检测等领域的实际应用情况。     

应重视选用芳烃演化参数评价高演化碳酸盐岩

现被广泛应用的测定高演化碳酸盐岩成熟度指标的多项有机岩石学评价方法，各有其不同的局限性，应用效果并不理想。研究发现，可利用芳烃演化新参数来代替其它失效的分子参数来评价碳酸盐岩有机质。芳烃因其结构、组成的特殊性和稳定性，在高演化阶段与油气生成及煤源岩成熟度有着良好的相关性，具有成为高演化碳酸盐岩成熟度指标的基础。从生产实践的角度看，芳烃演化参数有特殊适用性及选取的可行性。     

Mobilisierbarkeit von hydrophoben organischen Schadstoffen in belasteten Böden und Abfällen. Teil I: Mobilisierbarkeit von PCB,PAK und n-Alkanen durch Lösungsvermittler

Mobilization Potential of Hydrophobic Organic Compounds (HOCs) in Contaminated Soils and Waste Materials. Part I: Mobilization Potential of PCBs, PAHs, and Aliphatic Hydrocarbons in the Presence of Solubilizing Substances When using an elution procedure for organic pollutants to estimate the leaching behaviour of contamined soils and waste deposits, the influence of organic matter in solids and eluates adequately has to be considered. In batch tests with a solid/liquid ratio of 1:10, various aqueous solutions were composed, the solubilizing effect of which can be attributed to ubiquitous natural compounds (e. g., phospholipids, humic and carbonic acids). These solutions were evaluated in regard to the mobilization of PAHs, PCBs, and aliphatic hydrocarbons in soil and waste samples. The results were compared with batch tests containing sodium dodecyl sulfate (SDS), the properties and applications of which are selected and optimized in order to simulate the chemical interactions between pollutant and solubilizing substances of natural sources. Under alkaline conditions, the part of eluated pollutants was high because of the release of humic substances indigenous to the sample. Low concentrations of phospholipids and humic acid could decrease the mobility of aliphatic hydrocarbons. The extend of HOC mobilization is affected by specific interdependences between solubilizing substances and reactive matter of the samples. For most samples, 5.0 g/L concentrated SDS solution was able to simulate the most effective natural solutizer potential in regard to the mobilization of PAHs, PCBs, and aliphatic hydrocarbons within the system of batch tests. Whereas elution with pure water caused significant deviations in pollutant composition and too low yields, the use of SDS effected à good conformity. Modified in such a manner, the elution procedure can follow DIN 38414 part 4, when loss of pollutants will be minimized; e. g., centrifugation is needed to separate phases.     

放牛沟硫铁多金属矿床汞的地球化学异常特征

放牛沟矿床中的矿物、岩石及矿石含汞量的差异说明汞的次生地球化学异常来自矿体,特别是PbZn矿体。壤中气汞(Hg°)、土壤吸附汞(△Hg)及全汞(THg)异常套合出现是PbZn矿体的可靠标志。全汞异常能反映浅部矿体;吸附汞和壤中气汞异常不但反映浅部矿体,还能指示盲矿体及含矿断裂。根据汞的地球化学异常特征的研究,结合地质、土壤和岩石地球化学勘查结果,提出了两处找矿有希望地段。     

太平洋大尺度环流数值模拟 I:数学模式及其性能

本工作基于曾庆存的海洋环流模式设计思想和大气物理研究所海洋环流模式(IAPOGCM)基本动力框架,设计并实现了四层太平洋环流模式;同时引进稳定有效的时间积分方案和海表热通量参数化方法,对太平洋大尺度环流进行了较为系统的数值模拟. 本文首先导出消除“刚盖”近似、扣除海洋标准层结、保持总有效能量守恒的OGCM基本方程组;给出空间差分格式和时间积分方案,引入海表热通量计算方法;然后,在太平洋区域对所设计的四层OGCM的一些模式性能进行了分析、表明,时间积分方案采用基于“灵活性系数”技术的加速收敛方法和适应过程中流场正压斜压进一步分解算法,同时采取一些技术处理,可确保模式稳定而有效地进行长时间数值积分、有效能量分析表明,与海面起伏相联系的有效表面位能是总有效能量的重要组成部分,它与动能同量级甚至更大些,因此在OGCM中须考虑有效表面位能与其它能量间的转换机制,这在物理上更加合理,而采用“刚盖”近似则是不合理的;同时,扣除海洋标准层结,缩小了位能与动能之间的量级差别,有利于长期数值积分的稳定进行.此外,这个模式能直接计算海面起伏和分析有效能量,使得表面流场和上层海洋热储率的模拟比已有文献的结果有明显的改进.除模式设计外,本部分只给出模式的基本性能,系统的模拟结果将在第Ⅱ,Ⅲ两部分发表.     

Effects of peat content,rainfall duration and aggregate size on soil crust strength

The effect of peat on crust strength was investigated using ten soils with organic matter levels ranging from 1-50 to 18-23 per cent. As peat content increased, the crust strength reduced. This occurred in spite of the inability of peat to increase the stability of soil aggregates. Peat reduced crust strength by acting as a mulch on the soil surface, thereby reducing breakdown of soil aggregates. Peat also formed a source of weakness on the soil, reducing crust formation. Using a factorial experiment involving a further seven soils with different levels of peat treatment, exposed to four rainfall durations and with two aggregate sizes, crust strength was described in terms of the direct effects and the interactions of these factors. Most of the crust strength values reduced with increasing peat content. For each soil, crust strength increased significantly with increasing rainfall duration. Crust strength was greater for the smaller aggregate size. The most significant interactions affecting crust strength were between soil and aggregate size, rainfall duration and aggregate size, and soil and rainfall duration in that order. These interactions were used to describe the effect of organic matter in form of peat on crust strength. For each soil and aggregate size, polynomial relationships were established to relate crust strength to total kinetic energy of rainfall.     

北半球大气臭氧和气温的关系

本文根据北半球21个臭氧站1979年7月1—31日逐日日平均臭氧总量与日平均10—200hPa气温资料,分析了逐日臭氧变化与气温变化的相互联系和影响。结果发现,臭氧总量变化落后于50—200hPa层气温变化,超前于5—50hPa层气温变化。     

有机岩石学及其在油气评价中的应用

  简要介绍了有机岩石学研究方法的发展与特.点，系统的论述了这门新兴学科用于确定烃源岩成熟度、有机质类型，研究油气生成、运移与聚集等方面所取得的进展。