适用于栅格状孕镶金刚石钻头的胎体配方研究

为了提高钻进坚硬岩层的工作效率,将孕镶金刚石钻头胎体结构设计为栅格状,分析了栅格状孕镶金刚石钻头钻进岩层时的碎岩方式,并采用粉末冶金法制备Inconel 718和CoCrMo试样,通过分析不同烧结温度对两种胎体试样的硬度、耐磨性及抗弯强度的影响,确定了两种材料的最优烧结参数,并对其在该烧结温度下的力学性能进行对比分析。研究结果表明：Inconel 718和CoCrMo均具有较好的抗弯强度,满足钻进坚硬岩层对胎体抗弯强度的要求。Inconel 718的硬度比传统WC基胎体材料小,试样磨损量较大,适合用于地质灾害应急勘查等要求钻进速度快的极端情况;CoCrMo的硬度及耐磨性与传统WC基胎体接近,适合作为孕镶金刚石钻头的胎体材料。     

Evidence for a shock-metamorphic breccia within a buried impact crater,Lake Raeside,Yilgarn Craton,Western Australia

Mineral exploration drilling 60 km west of Leonora in 2008 intersected >95 m of poorly consolidated granitoid-dominated breccia at the base of a Cenozoic paleochannel beneath Lake Raeside. The breccia, initially interpreted as a kimberlite, is composed of poorly consolidated fragments of granitic gneiss, felsite and metamorphosed mafic rock within a matrix of fine to medium-grained breccia. Microscopic examination revealed quartz grains displaying well-developed planar deformation features (PDFs) dominated by the ω? {1013} planar set, diaplectic silica glass and diaplectic plagioclase glass. These features constitute the diagnostic hallmarks of shock metamorphism owing to high-velocity impact of a large meteorite or asteroid. The PDFs in quartz grains of the breccia are distinctly different from metamorphic deformation lamellae produced tectonically or in diatremes. Airborne total magnetic intensity data suggest an outline of an 11 km-diameter crater, consistent with the significant thickness of the shock-metamorphosed breccia at >95 m, suggestive of the existence of a large impact structure.     

热液中二氧化硅与成矿元素锡络合作用的实验标定

热液中二氧化硅与成矿元素锡络合作用的实验标定＊樊文苓陈紫新王声远田弋夫（中国科学院矿床地球化学开放研究实验室，贵阳５５０００２）关键词锡石溶解度二氧化硅的络合作用迁移形式前人对锡在流体中迁移形式的实验研究和热力学计算表明，锡（Ⅱ）的多种氯络合物是高温...     

Spatiotemporal aspects of silica buffering in restored tidal marshes

Losses of pelagic diatom production resulting from silica limitation have not only been blamed for toxic algal blooms, but for the reduction in ability of coastal food webs to support higher trophic levels. Recent research has shown the importance of advective seepage water fluxes of dissolved silica (DSi) from freshwater marshes to pelagic waters during moments of riverine Si-limitation. In this study, we investigated the potential impact of recently installed new tidal areas along the Schelde estuary, located in former polder areas and characterized by so-called controlled reduced tidal regimes (CRT). Nine mass-balance studies were conducted in a newly constructed CRT in the freshwater Schelde estuary. During complete tidal cycles both DSi and amorphous silica (ASi) concentrations were monitored at the entrance culverts and in different habitats in the marsh. A swift DSi-delivery capacity was observed despite the shifted spatiotemporal frame of exchange processes compared to reference marshes. As silica-accumulating vegetation is not yet present, and difference with reference marshes’ deliveries is surprisingly small, we indicate diatomaceous debris and phytoliths to be the main silica source. Although further research is necessary on the driving forces of the different processes involved, restoration of former agricultural areas under CRT-regime provide the potential to buffer silica in the estuary.     

青海湖沉积物生物硅的环境意义初步研究

湖泊沉积物中生物硅含量的变化已经被广泛应用于评价湖泊生产力和古气候变化研究,但大型湖泊不同位置生物硅含量的时空变化及其与环境要素之间的关系仍缺乏详细的现代过程研究。通过对青海湖不同位置表层沉积样品的生物硅含量测定,建立其空间分布模式及最近数百年生物硅含量的时间序列。结果表明,青海湖表层沉积物生物硅含量变化范围是1.75 ％ ~2.98 ％ ,平均值为2.25 ％ 。与世界其他湖泊相比,青海湖生物硅含量处于相对较低水平,可能与其特殊的地理位置和气候条件有关。青海湖生物硅含量的空间分布规律与沉积物质量堆积速率以及陆源组分含量(如SiO2)相反,而与化学/生物沉积组分(如CaCO3)含量的空间分布规律大体一致,说明生物硅的空间分布受到陆源碎屑物质的"稀释效应"影响。时间序列上,生物硅含量与SiO2含量呈相反变化趋势,与指示降雨量变化的 C/N 比值也是反相变化,说明生物硅含量在时间序列上也受与气候条件密切相关的陆源输入的影响。青海湖湖心低沉积速率区域的生物硅指标具有指示古气候变化的潜力。     

P－350浸渍树脂分离富集Ag，Cd体系及其应用

以Ｐ－３５０吸附于ＤＡ＿（２０１）树脂上，制得了Ｐ－３５０浸渍树脂，通过柱层析法，试验了树脂吸附和解脱Ａｇ，Ｃｄ的条件和干扰离子的影响。建立了Ｐ－３５０浸渍树脂分离－富集Ａｇ，Ｃｄ体系，并应用于岩石样品分析中，效果较好。     

Shock metamorphism on the moon

Shock metamorphism of the lunar samples is discussed. All types of lunar glasses formed by various-size collision-type impact are found as impact glass, ropy glass and agglutinates. The agglutinates bonded by crystal and glassy materials contain hydrogen and helium from the solar wind components. Lunar shocked minerals of plagioclase and silica show anomalous compositions and densities. There are typical two formation processes on planetary materials formed by shock events; that is (1) shocked quartz formed by silica-rich target rocks (esp. on evolved planets of the Earth and Mars), and (2) shocked silica with minor Al contents formed from plagioclase-rich primordial crusts of the Moon. The both shocked silica grows to coarse-grain normal crystals after high-temperature metamorphism which cannot distinguish the original main formation event of impact process.     

硅灰加固宁波软土的试验研究

为探索硅灰对软土的力学性质的影响,以宁波鄞州地区一种淤泥质黏土为试样,掺入不同量的硅灰,对硅灰加固土的力学性质和结构特征进行了测试。采用三轴不固结不排水剪切试验,测试分析了不同掺入量的硅灰加固土的应力应变关系,通过扫描电镜SEM照片分析了不同硅灰掺入量的硅灰加固土的结构特征。结果表明:(1)硅灰可以提高软土的黏聚力,黏聚力随着硅灰掺入量的增加而增大;(2)随着硅灰掺入量的增加,硅灰加固土的抗变形能力呈先增加后减小的趋势;(3)同一围压条件下,随着硅灰掺入量的增加,硅灰加固土的破坏偏应力逐渐增加;(4)随着硅灰掺入量的增加,硅灰加固土中大孔隙逐渐减少,小孔隙逐渐数量增加,孔径<1μm的小孔隙组分逐渐占优。     

Adsorption characteristics of copper ion on nanoporous silica

Adsorption by nanoporous media is critically involved in many fundamental geological and geochemical processes including chemical weathering,element migration and enrichment,environmental pollution,etc.Yet,the adsorption behavior of metal ions on nanoporous materials has not been systematically investigated.In this study,MCM-41 material with a monodisperse pore size(4.4 nm)and a large BET specific surface area(839 m^2/g)was hydrothermally prepared and used as a model silica adsorbent to study the adsorption characteristics of Cu^2+as a representative metal ion.The Cu^2+adsorption capacity was found to increase with increasing suspension pH in the range from 3 to 5 and to decrease in the presence of NaNO3.At 25℃,pH=5,and a solid-to-liquid ratio of 5 g/L,the adsorption capacity was determined to be 0.29 mg/g,which can be converted to a dimensionless partition coefficient of 45,indicating a strong enriching effect of nanoporous silica.The adsorption isotherm and kinetic data were fitted to several commonly used thermodynamic,kinetic,and diffusion models.The adsorption mechanism was also studied by Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy and synchrotron-based X-ray absorption spectroscopy.The results suggest that Cu2+ion adsorption is an entropy-driven endothermal process,possibly involving both outer-sphere and inner-sphere complexes.     

The silica supersaturated waters of northern Evia and eastern central Greece

The area of north Evia and eastern central Greece is characterized by strong geomorphological contrast and is built up mainly of consolidated rocks. Unconsolidated young sediments of Pleistocene to Holocene age cover the valley and basin flats, forming the most productive aquifers in this area. However, two more types of aquifers can be distinguished within the consolidated rock area. The first one is associated with karstified limestones and the second with strongly tectonized ultramafic rocks. The schist–chert formation, with intercalations of shales and cherts, seals the ultramafic masses underneath. Surface and spring waters associated with ultramafic rocks in north Evia and eastern central Greece were studied. Two types of water can be distinguished: (1) high Mg²⁺ and SiO₂ , bicarbonate as the dominant anion, pH 7·4–9·2, temperature 9·5–16·3 °C, low TDS (total dissolved solutes) (459–1037 mg/l), found both in peridotite and serpentinite areas, classified as Mg–HCO₃ type; (2) high Ca²⁺, low Mg²⁺ and SiO₂ , hydroxyl ion as the major anion, pH 11·2, temperature 28 °C, very low TDS (122 mg/l), found in peridotite areas, classified as Ca–OH type. The studied waters are highly supersaturated with respect to quartz, amorphous silica, brucite and most low temperature magnesium silicates (antigorite, sepiolite, talc, etc.). These waters show relatively narrow SiO₂ concentration ranges and a trend parallel to the amorphous silica saturation surface. The silica supersaturated waters have the potential to precipitate silica and consequently could affect the people of the local communities that use it as drinking water, causing health problems (kidney stones). Copyright © 1999 John Wiley & Sons, Ltd.