准噶尔盆地中央坳陷带包裹体特征及成藏期次分析

本文研究了准噶尔盆地中央坳陷带主力油层流体包裹体的特征,统计分析了各区块已揭示的主力油层的流体包裹体均一化温度,明确了主力油藏主成藏期流体包裹体均一化温度范围;在此基础上,通过单井埋藏史和热史的恢复,结合主力烃源生排烃热演化,确定了各区块主力油藏主成藏期发生的时间:中部1区块为新近纪渐新世(40 Ma),中部2区块为晚白垩世早期(95～88 Ma),中部3区块为白垩世末-古近纪早期(75～60 Ma),中部4区块第一期成藏时间为早白垩世末(105～95 Ma),第二期成藏时间为晚白垩世晚期(85～72 Ma).     

Fluid Inclusions in Surface‐temperature Halite: Sample Preparation and Application

Paleo-temperature and paleo-environment can be interpreted from measuring homogenization temperatures of fluid inclusions within halite. In order to conduct such measurements, vapor bubbles within low-temperature fluid inclusion often need to be created through cooling process by using cooling stage or freezer. Proper cooling is critical for interpreting measured temperature data. We tested two common cooling methods, using heating/freezing stage and freezer, for studying fluid inclusions in halite precipitated in laboratory at conrtolled temperature of 25℃. While using the heating/freezing stage, halite samples were kept at-18℃ for 40–50 min; whereas for freezer, samples were stored at-18℃ for 1, 10, 20 and 40 days, respectively. By comparing the homogenization temperatures of the two cooling processes, we explored the detailed experimental processes and developed an optimal cooling nucleation procedure for homogenization temperature analyses of fluid inclusions within surface-temperature halite. The results show that the maximum homogenization temperatures from both methods approximate the actual brine temperature of 25℃. However, extended refrigeration time has noticeable influence on the results. The refrigeration time of the experiment can be shortened to meet requirements.     

焉耆盆地三工河组储层流体包裹体形成期次分析

焉耆盆地三工河组流体包裹体具有丰度低、个体小的特征,并以液态烃相包裹体为主,主要分布在石英颗粒的溶孔或溶缝当中。结合盆地成岩作用和有机质演化历史分析,认为它们形成于侏罗纪晚期的以压溶和溶蚀作用为特征的晚成岩作用阶段。包裹体均一温度呈双峰型分布,具有 10 1~ 110℃和 12 1~ 130℃两个区间,结合焉耆盆地的埋藏史和盆地的热史,这两个温度区间分别对应于晚侏罗世和侏罗纪末期。包裹体组份特征分析也证实该地区存在两期包裹体,并且包裹体组分主要是在烃源岩低成熟阶段形成的。可以认为,焉耆盆地三工河组储层的流体包裹体主要是在晚侏罗世烃源岩的低成熟阶段和侏罗纪末期烃源岩的成熟阶段形成。     

王集-新庄地区包裹体特征及油气成藏期次

通过采集泌阳凹陷王集-新庄地区岩心样品,对其中包裹体进行盐度特征分析、镜下观察及均一温度测定;结果表明王集-新庄地区包裹体分为两期,与盆地埋藏史和热史研究划分的早、晚两个成藏期相对应。结合生排烃史综合分析,该区油气分两期成藏,早期油气成藏期主要发生在核一段末期~廖庄组沉积期,为小规模油气成藏,该期主要生成低熟油;晚期油气成藏期主要发生在廖庄末抬升期,为大规模油气成藏,是形成现今油田的主要成藏期。利用油气包裹体进行油气成藏研究,必须和宿主矿物的矿物岩石学分析及其他成藏期次分析方法结合使用,才能使分析结果更加客观可信。     

松辽盆地南部红岗油田青山口组砂岩中片钠铝石的形成温度

主要以松辽盆地南部红岗油田富含片钠铝石砂岩的红143和红146井为研究对象,通过普通薄片鉴定、茜素红-S染色、扫描电镜、能谱分析、显微测温等分析方法,对研究区含片钠铝石砂岩的成岩共生序列,尤其是流体包裹体均一温度进行了详细的研究.红岗油田成岩共生序列为:黏土矿物→石英次生加大边→方解石→片钠铝石→铁白云石→石英愈合微裂...     

豫西南高庄金矿床流体包裹体组合研究及其成矿流体特征

高庄金矿床形成于华北板块和扬子板块造山后的板内伸展环境,矿体是二郎坪群中充填于平行造山带走向的脆韧性剪切带中的石英-金多金属硫化物矿脉。本次运用"流体包裹体组合"(FIA)方法进行流体包裹体特征研究。研究表明,高庄金矿含矿石英中包裹体主要有CO_2-H_2O型三相包裹体、CO_2包裹体和水溶液包裹体3种类型,其中,CO_2-H_2O型三相包裹体为主体类型,完全均一温度变化范围为286~349℃,w(Na Cleq)为0.41%~4.14%,估算流体密度为0.788~0.874 g/cm3,成矿压力为130~160 MPa,成矿深度为4.8~5.9 km,成矿流体具有中温,富CO_2、低盐度的特征。在同一视域内可见CO2-H2O型三相包裹体和水溶液包裹体共存,均一方式各异,且均有相近的均一温度,指示存在流体不混溶作用。成矿流体中水的δDH_2O=-83.4‰~-76.3‰,δ18OH_2O=5.8‰~7.1‰,显示成矿流体来自于岩浆热液。结合区域构造背景,认为高庄金矿床为形成于华北板块与扬子板块碰撞造山作用后,板块内部构造变形过程中形成的中温岩浆热液型金矿。     

Chloride transfer in cement‐based materials. Part 1. Theoretical basis and modelling

In this first part of the work, we develop macroscopic models for migration and diffusion–migration of ionic species in saturated porous media, based on periodic homogenization. The prior application is chloride transport in cementitious materials. The dimensional analysis of Nernst–Planck equation lets appear to dimensionless numbers characterizing the ionic transfer in the porous medium. Using experimental data obtained from electrodiffusion tests on cement‐based materials (Part II), these dimensionless numbers are linked to the perturbation parameter ?. For a strong imposed electrical field, the asymptotic expansion of Nernst–Planck equation leads to a macroscopic model where the migration is predominant. For a weak imposed electrical field or in natural diffusion, we obtain a macroscopic model coupling diffusion and migration at the same order. In both models, the expression of the homogenized diffusion tensor is identical and only involves the geometric properties of the material microstructure. Copyright © 2012 John Wiley & Sons, Ltd.     

Second‐order work analysis for granular materials using a multiscale approach

It has been established that the second‐order work criterion is a general necessary condition for all instabilities by divergence in rate‐independent granular materials. The relation between the values of discrete second‐order work at the intergranular contact point level and its global macroscopic value is recalled at the beginning of this paper. Then, the basic purpose of the paper is tackled by an analysis of the main features of second‐order work criterion in relation with the granular microstructure. For that, it is considered a novel micromechanical model (the so‐called ‘H‐microdirectional model’), which has the property to involve three scales: grain scale, mesoscale with a specific granular configuration and continuum mechanics macroscale. Eventually, these exhibited features (a bifurcation stress domain and some instability cones) are qualitatively compared with the ones provided by direct numerical simulations issued from a discrete element model. The ultimate goal is to analyse what happens at the granular scale, when the macrosecond‐order work is vanishing at the macrolevel. Copyright © 2013 John Wiley & Sons, Ltd.