Application of the photoacoustic method for characterization of natural galena (PbS)

Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D _T≈0.16 × 10^?5 m² s^?1), the coefficient of diffusion (D between 0.15×10^?2 0.16×10^?2 m² s^?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s _g≈65.5 m s^?1 and s _b≈66.4 m s^?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×10¹⁸ cm^?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed.     

塔里木盆地岩石层热结构特征

在大地热流密度分布的基础上，研究了塔里木盆地中库尔勒－若羌和阿克苏－叶城两条剖面岩石层热结构特征．由岩石层Ｐ波速度分布转换成生热率剖面，用二维数值模型获得了岩石层热结构和热状态特征．结果表明，塔里木盆地壳幔边界温度的高低与其埋深密切相关．居里等温面深度大，地幔热流密度较低．岩石层厚度变化与其新生代期间挠曲过程密切相关．在岩石层温度分布基础上，确定了深部脆－韧性过渡带深度和岩石层屈服强度，表明塔里木盆地岩石层相对较冷，且具有刚性的地球动力学特征．     

福建省西部大地热流值

根据福建省西部53个钻孔的实测地温数据和300多块岩石样品的实测热导率数据,计算了29个大地热流值,说明福建西部热流的平均值为74mW/m²,相当于中新生代活动区的热流值。     

320矿床成因和找矿方向

320矿床的含矿土岩是一套强烈硅化(角)砾状和(角)砾质岩,是地洼初动期岩溶洞穴沉(堆)积岩——以钙屑岩为主的混杂陆源沉积岩,受硅化形成。硅化主要发育于岩溶沉积岩中,并波及它附近的地层。这一事件发生于地洼余动期初,形成于低温环境,硅来自沉积岩源,流体起源于大气降水。320矿床是一个硅化改造的古岩溶矿床,它与美国亚利桑那州的硅化溶解-塌陷角砾岩筒相同。这类矿床在华南碳酸盐岩地区找矿潜力很大。     

High-temperature X-ray investigation of natural columbites

Structural investigations at high temperature were carried out on natural columbite samples across the join Fe(Nb_0.95Ta_0.05)₂O₆–Mn(Nb_0.95Ta_0.05)₂O₆. The samples were preliminarily annealed to attain the complete cation-ordered state and avoid the superimposition of the effects of cation ordering during high-temperature studies. Unit-cell parameters of three columbites with different X_Fe content were measured at regular intervals in the temperature range 25–900 °C using single-crystal X-ray diffraction techniques. The crystal structures of completely ordered ferrocolumbite and manganocolumbite were also refined from intensity data collected at room temperature, 300 and 600 °C. Structural thermal expansion coefficients show positive, linear expansion of a, b, c lattice constants and cell volume. In general, slightly higher expansion occurs along a and c directions. However, anisotropy decreases sharply with decreasing Fe content. Reversibility of thermal expansion in the investigated temperature range was checked by high-temperature diffraction studies under heating-up and cooling-down conditions. Impurities do not play an important role in thermal expansion of columbites; expansion coefficients measured on two crystals of the same sample characterized by different Ti content are in fact almost identical. Structural changes with temperature essentially affect bond lengths: volumes of both A and B octahedral sites increase linearly with temperature, whereas interpolyhedral geometrical parameters do not vary significantly.     

Characterization of beryl (aquamarine variety) from pegmatites of Minas Gerais,Brazil

Eight samples of the beryl variety aquamarine were selected from four pegmatites in the Governador Valadares and Araçuaí regions in northeastern Minas Gerais State, Brazil. These samples were fully characterized by chemical analysis, infrared and UV-visible spectroscopy, thermal analyses, and high-temperature X-ray diffraction (from room temperature up to 800 °C). Several physical and chemical properties of beryl were found to depend on the amount of water and ions residing in the structural channels. The thermal expansion coefficients from room temperature to about 800 °C are temperature-independent, with αa ? ?3.2 × 10^?6 ° C^?1 and αc ? ?8.7 × 10^?6 ° C^?1. The contraction of both a and c unit-cell parameters with increasing temperature and the shift of the infrared band centered at about 1200 cm^?1 were tentatively ascribed to interactions between channel water and the silicate rings.The color of beryl seems to be dictated by the relative proportions of Fe³⁺ in the octahedralsites and of fe²⁺ in the channels. Thus, deep-blue samples have little Fe³⁺, whereas greener samples have more Fe³⁺ or less channel Fe²⁺.     

Geochemistry of the thermal springs and fumaroles of Basse-Terre Island,Guadeloupe, Lesser Antilles

 The purpose of this work was to study jointly the volcanic-hydrothermal system of the high-risk volcano La Soufrière, in the southern part of Basse-Terre, and the geothermal area of Bouillante, on its western coast, to derive an all-embracing and coherent conceptual geochemical model that provides the necessary basis for adequate volcanic surveillance and further geothermal exploration. The active andesitic dome of La Soufrière has erupted eight times since 1660, most recently in 1976–1977. All these historic eruptions have been phreatic. High-salinity, Na–Cl geothermal liquids circulate in the Bouillante geothermal reservoir, at temperatures close to 250  °C. These Na–Cl solutions rise toward the surface, undergo boiling and mixing with groundwater and/or seawater, and feed most Na–Cl thermal springs in the central Bouillante area. The Na–Cl thermal springs are surrounded by Na–HCO₃ thermal springs and by the Na–Cl thermal spring of Anse à la Barque (a groundwater slightly mixed with seawater), which are all heated through conductive transfer. The two main fumarolic fields of La Soufrière area discharge vapors formed through boiling of hydrothermal aqueous solutions at temperatures of 190–215  °C below the "Ty" fault area and close to 260  °C below the dome summit. The boiling liquid producing the vapors of the Ty fault area has δD and δ¹⁸O values relatively similar to those of the Na–Cl liquids of the Bouillante geothermal reservoir, whereas the liquid originating the vapors of the summit fumaroles is strongly enriched in ¹⁸O, due to input of magmatic fluids from below. This process is also responsible for the paucity of CH₄ in the fumaroles. The thermal features around La Soufrière dome include: (a) Ca–SO₄ springs, produced through absorption of hydrothermal vapors in shallow groundwaters; (b) conductively heated, Ca–Na–HCO₃ springs; and (c) two Ca–Na–Cl springs produced through mixing of shallow Ca–SO₄ waters and deep Na–Cl hydrothermal liquids. The geographical distribution of the different thermal features of La Soufrière area indicates the presence of: (a) a central zone dominated by the ascent of steam, which either discharges at the surface in the fumarolic fields or is absorbed in shallow groundwaters; and (b) an outer zone, where the shallow groundwaters are heated through conduction or addition of Na–Cl liquids coming from hydrothermal aquifer(s). Received: 9 November 1998 / Accepted: 15 July 1999     

高精度热电离质谱(TIMS)铀系法洞穴沉积物(石笋)年龄的研究

用高精度热电离质谱技术测定石笋的年龄,初步建立了热电离质谱铀系年龄的方法。 4个样品的测定结果复现性较好,铀含量、同位素比值及年龄值与标准值吻合,数据的精度大大提高,显示了质谱铀系年龄方法具有样品量少、时间短、精度高的优点。     

东亚副热带西风急流季节变化特征及其热力影响机制探讨

利用1961—2000年NCEP/NCAR月平均再分析资料对东亚副热带西风急流强度和位置的季节变化进行了分析,指出急流位置季节变化不仅有明显的南北向移动,6—7月还存在东西方向的突变特征,同时急流轴在北进过程中具有东西向的不一致性,急流中心强度的变化超前于位置的南北移动。在此基础上,采用动态追随急流中心移动的方法,探讨东亚副热带西风急流季节变化的热力影响机制,发现东亚副热带西风急流强度变化及位置移动与对流层中上层气温南北差异的分布结构有很好的对应关系,这说明急流的季节演变是对辐射季节变化及由于东亚特殊的海陆分布和青藏高原大地形影响而造成纬向不均匀加热的响应。从各热量输送项与急流的关系来看,从冬半年到夏半年的增暖时段,急流中心南北温差减小,急流减弱北进;从夏半年到冬半年的降温时段,急流中心南北温差增大,急流加强南退。热量平流输送的经向差异是造成急流中心南北温差的主要原因,急流跟随热量平流输送最大经向梯度中心位置南北移动。非绝热加热对急流中心的东西移动有引导作用,青藏高原春夏季对对流层中上层强大的加热作用是导致6—7月急流中心位置西移突变的原因。     

建筑群对城市冠层动力、热力效应的数值试验研究

利用中尺度模式MM5,分别耦合传统的边界层参数化方案和城市冠层参数化方案,模拟了2001年冬季北京冠层大气的动力、热力特征,并和观测资料进行了对比分析.分析结果表明,城市冠层参数化方案更能细致描述建筑群对城市冠层大气的动力、热力作用.由于建筑群的动力、热力作用,使北京城区的温度升高,风速减小,湍流动能增强,形成了明显的增温区、阻风区和湍能增强区,中心均位于城区高大建筑群附近,并向郊区递减.