油气化探中甲烷碳同位素应用、存在问题与对策研究

阐述了在地表油气化探实践当中甲烷碳同位素对地表土壤烃气成因判别的有效性，但有时也会遇到判断错误的情况。通过对应用实例的分析，指出因忽略了土壤中异常甲烷是一种混合成因甲烷，从而导致判断失误。为全面解决这一问题，提出了同时选送数量相当的背景土壤样品和异常样品进行甲烷同位素测定，然后通过教学方法计算出真实反映来源于油气藏中的甲烷的碳同位素值的对策方案。     

郯庐断裂带鲁苏皖段构造应力场及分段特征研究

利用Snoke方法求解和收集得到的77次中小地震的震源机制解资料, 采用Gephart应力张量反演方法, 获得了郯庐断裂带鲁苏皖段构造应力场, 最大主压应力方位角为80°, 最小主压应力方位角为172°, 最大、 中等和最小主压应力倾角分别为15°、 65°和19°, 反映了研究区处于近EW向水平作用和近NS向的水平拉张作用环境下。 根据地震活动、 地质构造及震源机制解差异, 我们将郯庐断裂带鲁苏皖段分5个区段开展研究, 结果显示: 5个分区应力场存在局部差异, 最大主压应力方位角处于63°～88°之间, 从北往南总体方向成顺时针偏转的趋势。 跨郯庐断裂带两侧的应力场研究结果显示, 从西到东最大主压应力方向有一个逆时针偏转的趋势, 西侧最大主压应力方向更接近EW向, 东侧更接近NE向, 郯庐断裂带内处于两侧的过渡地段。     

兰坪白秧坪铜银多金属矿床成矿物质来源的铅和硫同位素示踪

白秧坪铜银多金属矿床主要产于白垩系下统景星组石英砂岩、粉砂岩中,矿石铅同位素组成特征与景星组砂岩的铅同位素组成比较接近,表明壳源物质参与了成矿作用。作ZartMan图解和Δγ-Δβ图解表明,矿石铅属于壳幔混合来源。矿石铅μ值介于9.43~9.65之间,Th/U比值介于3.72~3.87之间,表明矿石铅为壳幔混合铅。该矿床硫同位素组成表明,硫来源于深部地幔硫遭受地壳硫的混入。该矿床的成矿作用发生于开放体系之中,成矿物质来源为深部幔源物质混合了壳源物质。     

白云鄂博碳酸岩墙的稀土和微量元素地球化学及对其成因的启示

根据矿物组成白云鄂博矿区的碳酸岩岩可墙可分为白云石型、白云石－方解石共存型和方解石型三种类型。REE和微量元素地球化学表明，这三类碳酸岩岩墙为碳酸岩浆演化不同阶段的产物，白云石型和白云石－方解石共存型对应于早期岩浆阶段，其（La/Nd)n、(La/Yb)n比值随稀土总量的增加而增大，方解石型则对应于碳酸岩浆演化的晚期热液阶段，其稀土总量明显富集，但其（La/Nd)n、(La/Y)n和（La/Yb)n比值随稀土总量的增加却有减小的趋势，热液阶段也是白云鄂博稀土矿化的主要阶段。     

An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.     

大别山东北缘构造片麻岩中锆石U-Pb年代学分析及构造意义

大别造山带是由华北板块和扬子板块经过长期构造演化、最终碰撞拼合的产物。大别山东北缘发育地壳深部构造层次上的构造片麻岩,通过对构造片麻岩的应力场恢复,认为大别山东北缘主要受到NE-SW向的特提斯构造体制和NW-SE向的太平洋构造体制两个体制的作用,并不是受单一的构造体制控制。锆石LA-ICP-MS微区U-Pb同位素测年结果显示,大别山东北缘至少存在3期构造事件。第一期是750±50 Ma的岩浆活动;第二期是210±10 Ma的变质活动;第三期是130±5 Ma的岩浆活动。大别山在碰撞造山后期发生了近水平东西向沿造山带的塑形流变,导致大别山中片麻理和线理走向均为NWW-SEE向,大别造山带发生塑形流变的时间在210±10 Ma左右,大概在195±5 Ma左右郯庐断裂带开始活动,改造了大别山原有的NWW-SEE向构造,使得大别山东端片麻理走向出现NE向转变。     

东昆仑断裂带东端的构造转换与2017年九寨沟MS7.0地震孕震机制

2017年四川九寨沟M_S7.0地震是继2008年汶川M_S8.0地震和2013年芦山M_S7.0地震之后,青藏高原东缘在不到十年的时间内发生的第三个震级M_S7.0以上的强震.这次地震发生在东昆仑断裂带东端,作为青藏高原东北缘的一条大型左旋走滑断裂带,东昆仑断裂带与东端其它构造之间的转换关系仍不清楚,因区内地质构造和地形复杂,东昆仑断裂带东端的主要构造仍缺少深入的研究.本文在总结区域地震构造活动特征、历史地震和现代地震基础上,通过东昆仑断裂带东端已有的和最近开展的活动构造定量研究结果,并结合现今GPS变形场资料和2017年九寨沟M_S7.0地震灾害特征分析,发现东昆仑断裂带最东段塔藏断裂上的左旋走滑除了一小部分继续向东传播转移到文县断裂带上外,大部分转化为其南侧的龙日坝断裂带北段、岷江断裂和虎牙断裂上的近东西向地壳缩短,这可能是岷山隆起的构造机制,而2017年九寨沟M_S7.0地震正是左旋走滑的东昆仑断裂带在东端继续向东扩展的结果.

     

危地马拉翡翠宝石矿物学特征及其与缅甸翡翠的对比研究

危地马拉目前已成为仅次于缅甸的第二大翡翠原料供应地.这两个产地翡翠辨别的需求愈发迫切,且应用意义较大.采用显微镜观察、电子探针分析及背散射电子照相获得危地马拉蓝水料翡翠的矿物成分及结构构造特征,结合两产地翡翠产出的大地构造环境、自然地理环境、原石特征与矿物成分特征等进行对比分析.总体上,危地马拉翡翠次生原石有一定的磨圆...     

河南嵩山地区元古宙五佛山群沉积岩的地球化学特征及其对物源区和构造环境的制约

河南嵩山地区位于华北克拉通南缘,保存有较为完整的太古宙-古元古代变质结晶基底和之后的沉积盖层。五佛山群直接角度不整合覆盖于新太古界登封群和古元古界嵩山群之上,为嵩山地区结晶基底之上分布广泛的第一沉积盖层。其主要由(长石)石英砂岩组成,夹少量的粉砂质页岩、泥岩和薄层灰岩。从下而上岩性相变明显,代表两次较大的沉积旋回。地球化学特征上,五佛山群砂岩的SiO₂含量(70.18%~95.21%)明显比泥质岩(20.79%~52.27%)高,但Fe₂O₃、MgO、CaO和K₂O含量比泥质岩低,表明泥质岩中含有较多的基性组分和富钾矿物。泥质岩的稀土总量(∑REE=131×10^-6~169×10^-6)比砂岩(∑REE=7.30×10^-6~158×10^-6)高,反映泥质岩中较高含量的粘土矿物对稀土元素具有较强的吸附作用。砂岩样品的成分变异指数(ICV=0.89~3.59)较低,说明其成熟度较高,为稳定构造环境下沉积的产物。泥质岩的ICV值为4.04~17.50,SiO₂/Al₂O₃比值(3.90~5.58)和La/V比值较低(0.45~0.65),说明其成熟度较低,形成环境相对比较活动。较低的化学蚀变指数(CIA=7.52~66.1)反映碎屑沉积岩 的源区遭受相对较弱的化学风化作用,其中砂岩(CIA=27.6~66.1)的化学风化强度比泥质岩(CIA=7.52~24.9)高。五佛山群碎屑沉积物主要来源于古元古代中酸性组分,有少量基性组分的加入。其下部和中部的砂岩与华北南缘同时代的沉积地层均形成于被动大陆边缘的沉积环境,说明华北克拉通南缘在熊耳群之后进入了一个稳定的沉积阶段。而五佛山群上部泥质岩形成于与大陆岛弧相关的沉积盆地,显示地壳活动性增强,沉积环境上暗示由被动大陆边缘向活动大陆边缘过渡的过程,可能与秦岭造山带形成初期的板 块活动有关。     

Evidence for Neotethys rooted within the Vardar suture zone from the Voras Massif, northernmost Greece

Three conflicting models are currently proposed for the location and tectonic setting of the Eurasian continental margin and adjacent Tethys ocean in the Balkan region during Mesozoic–Early Tertiary time. Model 1 places the Eurasian margin within the Rhodope zone relatively close to the Moesian platform. A Tethyan oceanic basin was located to the south bordering a large “Serbo-Pelagonian” microcontinent. Model 2 correlates an integral “Serbo-Pelagonian” continental unit with the Eurasian margin and locates the Tethys further southwest. Model 3 envisages the Pelagonian zone and the Serbo-Macedonian zone as conjugate continental units separated by a Tethyan ocean that was sutured in Early Tertiary time to create the Vardar zone of northern Greece and former Yugoslavia. These published alternatives are tested in this paper based on a study of the tectono-stratigraphy of a completely exposed transect located in the Voras Mountains of northernmost Greece. The outcrop extends across the Vardar zone, from the Pelagonian zone in the west to the Serbo-Macedonian zone in the east.Within the Voras Massif, six east-dipping imbricate thrust sheets are recognised. Of these, Units 1–4 correlate with the regional Pelagonian zone in the west (and related Almopias sub-zone). By contrast, Units 5–6 show a contrasting tectono-stratigraphy and correlate with the Paikon Massif and the Serbo-Macedonian zone to the east. These units form a stack of thrust sheets, with Unit 1 at the base and Unit 6 at the top. Unstacking these thrust sheets places ophiolitic units between the Pelagonian zone and the Serbo-Macedonian zone, as in Model 3. Additional implications are, first, that the Paikon Massif cannot be seen as a window of Pelagonian basement, as in Model 1, and, secondly, Jurassic andesitic volcanics of the Paikon Massif locally preserve a gneissose continental basement, ruling out a recently suggested origin as an intra-oceanic arc.We envisage that the Almopias (Vardar) ocean rifted in Triassic time, followed by seafloor spreading. The Almopias ocean was consumed beneath the Serbo-Macedonian margin in Jurassic time, generating subduction-related arc volcanism in the Paikon Massif and related units. Ophiolites were emplaced onto the Pelagonian margin in the west and covered by Late Jurassic (pre-Kimmeridgian) conglomerates. Other ophiolitic rocks formed within the Vardar zone (Ano Garefi ophiolite, Unit 4) in latest Jurassic–Early Cretaceous time and were not deformed until Early Tertiary time. The Vardar zone finally sutured in the Early Tertiary creating the present imbricate thrust structure of the Voras Mountains.