常压法合成Methomyl的研究

提出一种合成Methomyl的改良法。该方法的特点是反应可在常压下进行。对常压反应的优宜条件作了系统研究,并讨论了反应机理。     

Sources and hydrothermal alteration of organic matter in Quaternary sediments: A synthesis of studies from the Central Gulf of California

Deep sea drilling in the Central Gulf of California, a young and active spreading centre, shows that the high heat flow typical of these regions causes extensive alteration of sediment organic matter, especially near sills and above magma chambers where hydrothermal activity is concentrated. Even on the nearby passive margin, where there are no sills, heat flow is moderately high and hydrocarbon generation has begun in immature sequences. Migrating light hydrocarbons are detected especially where hydrothermal activity is concentrated. Thermogenic methane is more widespread, though not in the passive margin bordering the spreading centre. Despite the incidence of hydrocarbon generation and migration, the amounts of hydrocarbons involved are relatively small and apparently do not lead to commercially significant accumulations of petroleum.The organic matter in these sediments is mostly marine because the Gulf of California generally has low runoff from land and highly productive surface waters. Turbidites rich in terrigenous organic material are locally abundant in the mainly pelagic section in the Guaymas Basin. The highest concentrations of organic matter are found in laminated diatomites deposited on the Guaymas passive margin within the oxygen minimum zone.     

A2O·3MoO3·3H2O(A＝Na、K)晶须的合成与表征

在常温条件下合成了两种钾、钠的钼酸盐晶须 ,用FT -IR和XRD对其结构进行了分析 ,SEM照片清晰表明这两种化合物为针状晶须。     

东南沿海地震区地震活动特性与未来趋势分析

根据地震资料，对东南沿海地震区地震活动特下及未来趋势进行了初步分析与研究，结果表明：（１）从地震活动轮回分析，东南沿海地震区从１９５９年开始的第五个轮回中的地震活动时段，估计将延续到２０３１年前后结束，而后转入本轮回的平静时段；（２）２０００年以前，研究区有可能发生１次Ｍｓ≥６．０地震，到２００５到则最多发生２次；（３）东南沿海地震区下一次发生Ｍｓ≥６．０地震的地区可能在河源－邵武地震带上，尤其可     

江苏及周边地区中强震电磁异常综合特征分析

在地电阻率各向异性、地磁垂直分量日变化幅度响应比和逐日比、地磁垂直分量北京时21点绝对值空间相关及地磁垂直分量日变化空间相关方法在江苏地区的研究结果基础上,综合分析了这些方法提取的江苏及周边地区中强震异常的综合特征,给出了这些异常在震前出现的先后次序、地震三要素与这些异常的综合关系.     

BPM载频产生器的研制

介绍BPM短波投时台新的载频产生器的设计与实现。该BPM载频产生器以原子颁标的5MHz标频信号为参考，利用频率合成技术，产生出供发射机使用的2．5MHz、5MHz、10MHz、15MHz和20MHz五种高准确度的载频信号。这些信号既能单独输出，也可利用面板控制或遥控选择输出。为了保证系统的可靠性，来用了两冗余结构。并设置了必要的报警与指示。     

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.     

1951-2008年辽宁冰雹的时空分布特征

选取1951-2008年辽宁省56个站气象资料和中国气象灾害大典等资料,对冰雹时空分布进行了统计分析。结果表明：辽宁冰雹日数以山地为最多,丘陵次之,平原和沿海最少。移动路径基本与山脉、河流、海岸线等地形走向一致。冰雹具有明显的季节变化,主要出现在4-10月。5-6月为冰雹多发期,6月为最多,5月次之。近30a辽宁省年冰雹日数呈减少趋势。冰雹发生主要集中在中午至傍晚。辽西走廊、辽宁中部平原及辽东半岛南部大连地区为冰雹灾害重点防御区。产生冰雹的天气系统按高空形势分类主要有4种：冷涡、冷涡后部横槽、高空槽和槽后西北气流,对应地面形势多为低压冷锋。     

2015年尼泊尔8.1级地震前后拉萨地电场观测数据变化分析*

2015年4月25日尼泊尔8.1级强烈地震前后,拉萨地磁台(以下简称“拉萨台”)地电场观测数据出现了长时间、大幅度异常变化。在对拉萨台地电场观测条件、观测系统以及观测结果进行初步讨论的基础上,利用“能量合成累加”和“MSA功率谱分析”等数据处理方法,从“时间域”和“频率域”两个方面,对该异常变化的主要特征和演化过程进行了分析。结果显示,尼泊尔8.1级地震前后,拉萨台的地电场观测数据异常变化,经历了“趋势变化-扰动变化-发震期-恢复期”等发展阶段,以及“低频变化-高频变化-平稳变化-高频变化”等演化过程。综合分析认为,拉萨台地电场观测异常变化特征和演化过程,与相关现象和机理研究结果基本吻合,能够完整反映强烈地震孕育、发生和发展全过程,是具有一定客观性、典型性和代表性的珍贵资料。