Mercury surface composition: Integrating petrologic modeling and remote sensing data to place constraints on FeO abundance

A significant opaque component in Mercury’s crust is inferred based on albedo and spectral observations. Previous workers have favored iron-titanium bearing oxide minerals as the spectrally neutral opaque. A consequence of this hypothesis is that Mercury’s surface would have a high FeO content. An array of remote sensing techniques have not provided definitive constraints on the FeO content of Mercury’s surface. However, spectral observations have not detected a diagnostic 1 μm absorption band and have thus limited the FeO in coexisting silicates to <2 wt.% FeO. In this paper, we assess equilibrium among oxide and silicate minerals to constrain the distribution of iron between opaque oxides and silicates under a variety of environmental conditions. Equilibrium modeling is favored here because the geologic process that produced Mercury’s low-albedo intermediate terrain must have occurred globally, which favors a common widespread igneous process. Based on our modeling, we find that iron-rich ilmenite cannot occur with silicates that do not display a 1 μm absorption feature unless plagioclase abundances are high. However, such high plagioclase abundances are precluded by Mercury’s low albedo. Incorporating equilibrium crystallization modeling with spectral and albedo constraints we find the iron abundance of Mercury’s intermediate terrain is ?10 wt.% FeO. This intermediate iron composition matches constraints provided by visible albedo and total neutron absorption observed by MESSENGER. In fact, the total neutron absorption of mixtures of oxide, plagioclase, olivine and pyroxene for the oxide abundances estimated for Mercury, favor Mg-rich members of the ilmenite-geikielite solid-solution series. This work offers compositional constraints for Fe, Ti, and Mg that will be testable by various MESSENGER instrument data sets after it begins its orbital mission.     

Identification of the Ca-sulfate bassanite in Mawrth Vallis, Mars

The region surrounding the Mawrth Vallis outflow channel on Mars hosts thick layered deposits containing diverse phyllosilicate minerals. Here we report detection of the Ca-sulfate bassanite on the outflow channel floor, requiring a more complex aqueous chemistry than previously inferred for this region. The sulfate-bearing materials underlie phyllosilicate-bearing strata, and provide an opportunity for testing proposed models of martian geochemical evolution with a future landed mission.     

Possible impact melt and debris flows at Tooting Crater, Mars

Candidate examples of impact melt flows and debris flows have been identified at Tooting crater, an extremely young (<2 Myr), 29 km diameter impact crater in Amazonis Planitia, Mars. Using HiRISE and CTX images, and stereo-derived digital elevation models derived from these images, we have studied the rim and interior wall of Tooting crater to document the morphology and topography of several flow features in order to constrain the potential flow formation mechanisms. Four flow types have been identified; including possible impact melt sheets and three types of debris flows. The flow features are all located within 2 km of the rim crest on the southern rim or lie on the southern interior wall of the crater ∼1500 m below the rim crest. Extensive structural failure has modified the northern half of the crater inner wall and we interpret this to have resulted in the destruction of any impact melt emplaced, as well as volatile-rich wall rock. The impact melt flows are fractured on the meter to decameter scale, have ridged, leveed lobes and flow fronts, and cover an area >6 km × 5 km on the southern rim. The debris flows are found on both the inner wall and rim of the crater, are ∼1-2 km in length, and vary from a few tens of meters to >300 m in width. These flows exhibit varying morphologies, from a channelized, leveed flow with arcuate ridges in the channel, to a rubbly flow with a central channel but no obvious levees. The flows indicate that water existed within the target rocks at the time of crater formation, and that both melt and fluidized sediment was generated during this event.     

Evidence for pervasive mud volcanism in Acidalia Planitia, Mars

We have mapped 18,000+ circular mounds in a portion of southern Acidalia Planitia using their sizes, shapes, and responses in Nighttime IR. We estimate that 40,000+ of these features could occur in the area, with a distribution generally corresponding to the southern half of the proposed Acidalia impact basin. The mounds have average diameters of about 1 km and relief up to 180 m and most overlie units mapped as Early Amazonian.High resolution images of mound surfaces show relatively smooth veneers, apron-like extensions onto the plains, moats, and concentric circular crestal structures. Some images show lobate and flow-like features associated with the mounds. Albedo of the mounds is generally higher than that of the surrounding plains. Visible and near-infrared spectra suggest that the mounds and plains have subtle mineralogical differences, with the mounds having enhanced coatings or possibly greater quantities of crystalline ferric oxides.Multiple analogs for these structures were assessed in light of new orbital data and regional mapping. Mud volcanism is the closest terrestrial analogy, though the process in Acidalia would have had distinctly martian attributes. This interpretation is supported by the geologic setting of the Acidalia which sits at the distal end of the Chryse-Acidalia embayment into which large quantities of sediments were deposited through the Hesperian outflow channels. In its distal position, Acidalia would have been a depocenter for accumulation of mud and fluids from outflow sedimentation.Thus, the profusion of mounds in Acidalia is likely to be a consequence of this basin’s unique geologic setting. Basinwide mud eruption may be attributable to overpressure (developed in response to rapid outflow deposition) perhaps aided by regional triggers for fluid expulsion related to events such as tectonic or hydrothermal pulses, destabilization of clathrates, or sublimation of a frozen body of water. Significant release of gas may have been involved, and the extensive mud volcanism could have created long-lived conduits for upwelling groundwaters, providing potential habitats for an in situ microbiota.Mud volcanism transports minimally-altered materials from depth to the surface, and mud volcanoes in Acidalia, therefore, could provide access to samples from deep zones that would otherwise be inaccessible. Since the distal setting of Acidalia also would favor concentration and preservation of potentially-present organic materials, samples brought to the surface by mud volcanism could include biosignatures of possible past or even present life. Accordingly, the mounds of Acidalia may offer a new class of exploration target.     

Effect of atmospheric dust loading on martian albedo measurements

This work is devoted to the analysis of the variation of albedo measured by orbiting instruments with atmospheric opacity on Mars. The study has been conduced by analysing Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) data from martian regions with different surface albedo.In support of these data, synthetic spectra with different surface albedo and atmospheric opacities have been computed, so that a comparison has been performed. The synthetic spectra have been retrieved by using two different grain sizes for suspended dust (0.5 and 1.2 μm), allowing a comparison between the two models and the observations.Using the DCI, a parameter describing the quantity of dust deposited on the surface, the effectiveness of the single scattering approximation has been tested for low atmospheric opacity by analysing the quality of the linear fit up to different atmospheric opacity.For more opaque conditions two kinds of fits have been applied to the data, linear and second-order degree polynomial. In this case, we found that the polynomial fit better describes the observations.The analysis of these data made it possible to notice a peculiar trend, already reported by Christensen (1988), of the albedo over Syrtis Major after the occurrence of dust storms, but, differently from that work, now the study of DCI together with atmospheric opacity and albedo allowed us to robustly confirm the hypothesis made by Christensen.Finally, the comparison between observations and synthetic spectra computed with models with different particles grain sizes indicates that dust particles of 0.5 μm diameter are the most effective to change the aerosol atmospheric opacity on Mars.     

Alteration of five organic compounds by glow discharge plasma and UV light under simulated Mars conditions

The Viking missions to Mars failed to detect any organic material in regolith samples. Since then, several removal mechanisms of organic material have been proposed. Two of these proposed methods are removal due to exposure to plasmas created in dust devils and exposure to UV irradiation. The experiments presented here were performed to identify similarities between the two potential removal mechanisms and to identify any compounds produced from these mechanisms that would have been difficult for the Viking instruments to detect. Five organic compounds, phenanthrene, octadecane, octadecanoic acid, decanophenone and benzoic acid, were exposed to a glow discharge plasma created in simulated martian atmospheres as might be present in dust devils, and to UV irradiation similar to that found at the surface of Mars. Glow discharge exposure was carried out in a chamber with 6.9 mbar pressure of a Mars like gas composed mostly of carbon dioxide. The plasma was characterized using emission spectroscopy and found to contain cations and excited neutral species including carbon dioxide, carbon monoxide, and nitrogen. UV irradiation experiments were performed in a Mars chamber which simulates the temperature, pressure, atmospheric composition, and UV fluence rates of equatorial Mars. The non-volatile residues left after each exposure were characterized by mass loss, infrared spectroscopy and high resolution mass spectrometry. Oxidized, higher molecular weight versions of the parent compounds containing carbonyl, hydroxyl and alkenyl functional groups were identified. The presence of these oxidized compounds suggests that searches for organic material in soils on Mars use instrumentation suitable for detection of compounds which contain the above functional groups. Discussions of possible reaction mechanisms are given.     

Super-resolution of THEMIS thermal infrared data: Compositional relationships of surface units below the 100 meter scale on Mars

The Thermal Emission Imaging System (THEMIS) has provided the highest spatial resolution (100 m/pixel) thermal infrared (TIR) data of the surface of Mars to date. These data have enabled the discovery of many small-scale compositional units and helped to better constrain surface processes operating at these scales. However, with higher-resolution visible (VIS) instruments revealing smaller-scale surficial differences, there exists a need to detect and map compositional variability using TIR data at scales below 100 m. Because it is unlikely there will be a higher-resolution TIR instrument sent to Mars in the near future, creative image processing techniques commonly classified under the umbrella of “super-resolution” can be employed to improve or enhance the spatial resolution of the THEMIS TIR data. These approaches typically integrate another higher-resolution dataset and can either be qualitative for visual appeal, quantitative for data accuracy, or some combination of both. The super-resolution approach presented here produces enhanced TIR images that are radiometrically accurate, but also visually appealing. For the technique to be successfully applied, multi- to hyper-spectral data from two different spectral regions are required (e.g., the THEMIS TIR and VIS datasets). The focus here is to introduce this new super-resolution methodology and demonstrate its ability using existing THEMIS IR and VIS data. The quartzofeldspathic deposit in northern Syrtis Major was selected because of the spectral variability detected using the original IR resolution data and to better constrain the relationship between the small-scale surface morphology and areal extent of the deposit as well as its formation process. Despite being associated with the central peaks of two craters, the results here show no positive correlation between the small rocky outcrops and the quartzofeldspathic unit. A gradational contact exists between the unit and basaltic sands within the intercrater eolian material. The super-resolution approach offers an alternative approach to traditional sub-pixel deconvolution identification and provides a higher-resolution IR dataset for thermophysical and spectral analysis on Mars.     

The initial responses of hot liquid water released under low atmospheric pressures: Experimental insights

Experiments have been performed to simulate the shallow ascent and surface release of water and brines under low atmospheric pressure. Atmospheric pressure was treated as an independent variable and water temperature and vapor pressure were examined as a function of total pressure variation down to low pressures. The physical and thermal responses of water to reducing pressure were monitored with pressure transducers, temperature sensors and visible imaging. Data were obtained for pure water and for solutions with dissolved NaCl or CO₂. The experiments showed the pressure conditions under which the water remained liquid, underwent a rapid phase change to the gas state by boiling, and then solidified because of removal of latent heat. Liquid water is removed from phase equilibrium by decompression. Solid, liquid and gaseous water are present simultaneously, and not at the 611 Pa triple point, because dynamic interactions between the phases maintain unstable temperature gradients. After phase changes stop, the system reverts to equilibrium with its surroundings. Surface and shallow subsurface pressure conditions were simulated for Mars and the icy satellites of the outer Solar System. Freezing by evaporation in the absence of wind on Mars is shown to be unlikely for pure water at pressures greater than c. 670 Pa, and for saline solutions at pressures greater than c. 610 Pa. The physical nature of ice that forms depends on the salt content. Ice formed from saline water at pressures less than c. 610 Pa could be similar to terrestrial sea ice. Ice formed from pure water at pressures less than c. 100 Pa develops a low thermal conductivity and a ‘honeycomb’ structure created by sublimation. This ice could have a density as low as c. 450 kg m⁻³ and a thermal conductivity as low as 1.6 W m⁻¹ K⁻¹, and is highly reflective, more akin to snow than the clear ice from which it grew. The physical properties of ice formed from either pure or saline water at low pressures will act to reduce the surface temperature, and hence rate of sublimation, thereby prolonging the lifespan of any liquid water beneath.     

Evaporation effects on the formation of martian gullies

In order to investigate the formation of martian gullies and the stability of fluids on Mars, we examined about 120 gully images. Twelve HiRISE images contained a sufficient number of Transverse Aeolian Ridges (TARs) associated with the gullies to make the following measurements: overall gully length, length of the alcove, channel and apron, and we also measured the frequency of nearby TARs. Six of the 12 images examined showed a statistically significant negative correlation between overall gully length (alcove, channel and apron length) and TAR frequency. Previous experimental work from our group has shown that at temperatures below ∼200 K, evaporation rate increases by about an order of magnitude as wind speed increases from 0 to ∼15 m/s. Thus the negative correlations we observe between gully length and dune frequency can be explained by formation at temperatures below ∼200 K where wind speed/evaporation is a factor governing gully length. In these cases evaporation of the fluid carving the gully was a constraint on their dimensions. Cases where there is no correlation between gully length and TAR frequency, can be explained by formation at temperatures >200 K. The temperatures are consistent with Global Circulation Model and Thermal Emission Spectrometer (TES) data for these latitudes. The temperatures suggested by these trends are consistent with the fluid responsible for gully formation being a strong brine, such as Fe₂(SO₄)₃ which has a eutectic temperature of ∼200 K. We also find that formation timescales for gullies are 10⁵-10⁶ years.     

Formation of an eroded lava channel within an Elysium Planitia impact crater: Distinguishing between a mechanical and thermal origin

A lava channel identified on the wall of an Elysium Planitia impact crater is investigated to identify the dominant erosion mechanism, mechanical vs. thermal, acting during channel formation. Observations of channel morphology are used to supplement analytical models of lava channel formation in order to calculate the duration of channel formation, the velocity of the lava flowing through the channel, and the erosion rate in each erosion regime considered. Results demonstrate that the channel observed in the Elysium Planitia impact crater formed primarily due to mechanical erosion. In a more general sense, results of this study suggest that lava channels can form primarily due to thermal erosion in the presence of more gradual slopes and more consolidated substrates whereas lava channels can form primarily due to mechanical erosion in the presence of more energetic flows on steeper slopes and more poorly consolidated substrates. Therefore, both erosion regimes must be considered when analyzing origins of eroded lava channels that cut through strata of different strengths.