Origin of the Breno and Esino dolomites in the western Southern Alps (Italy): Implications for a volcanic influence

The Esino Limestone of the western Southern Alps represents a differentiated Ladinian-Lower Carnian (?) carbonate platform comprised of margin, slope and peritidal inner platform facies up to 1000 m thick. A major regional subaerial exposure event lead to coverage by another peritidal Lower Carnian carbonate platform (Breno Formation). Multiphase dolomitization affected the carbonate sediments. Petrographic examinations identified at least three main generations of dolomites (D1, D2, and D3) that occur as both replacement and fracture-filling cements. These phases have crystal-size ranges of 3–35 μm (dolomicrite D1), 40–600 μm (eu-to subhedral crystals D2), and 200 μm to 5 mm (cavity- and fracture-filling anhedral to subhedral saddle dolomite D3), respectively.The fabric retentive near-micritic grain size coupled with low mean Sr concentration (76 ± 37 ppm) and estimated δ¹⁸O of the parent dolomitizing fluids of D1 suggest formation in shallow burial setting at temperature ∼ 45–50 °C with possible contributions from volcanic-related fluids (basinal fluids circulated in volcaniclastics or related to volcanic activity), which is consistent with its abnormally high Fe (4438 ± 4393 ppm) and Mn (1219 ± 1418 ppm) contents. The larger crystal sizes, homogenization temperatures (D2, 108 ± 9 °C; D3, 111 ± 14 °C) of primary two-phase fluid inclusions, and calculated salinity estimates (D2, 23 ± 2 eq wt% NaCl; D3, 20 ± 4 eq wt% NaCl) of D2 and D3 suggest that they formed at later stages under mid-to deeper burial settings at higher temperatures from dolomitizing fluids of higher salinity, which is supported by higher estimated δ¹⁸O values of their parent dolomitizing fluids. This is also consistent with their high Fe (4462 ± 4888 ppm; and 1091 ± 1183 ppm, respectively) and Mn (556 ± 289 ppm and 1091 ± 1183 ppm) contents, and low Sr concentrations (53 ± 31 ppm and 57 ± 24 ppm, respectively).The similarity in shale-normalized (SN) REE patterns and Ce (Ce/Ce*)_SN and La (Pr/Pr*)_SN anomalies of the investigated carbonates support the genetic relationship between the dolomite generations and their calcite precursor. Positive Eu anomalies, coupled with fluid-inclusion gas ratios (N₂/Ar, CO₂/CH₄, Ar/He), high F⁻ concentration, high F/Cl and high Cl/Br molar ratios suggest an origin from diagenetic fluids circulated through volcanic rocks, which is consistent with the co-occurrence of volcaniclastic lenses in the investigated sequence.     

A novel method to estimate mineral compositions of mudrocks: A case study for the Canadian unconventional petroleum systems

The mineral composition of mudrocks is an essential attribute in controlling the reservoir quality of unconventional petroleum systems. The present study introduces a semi-quantitative method to estimate mineral phases of mudrocks in various Canadian unconventional hydrocarbon systems using total elemental analysis (inductively coupled plasma-mass spectrometry (ICP-MS)) and Rock-Eval data (total organic carbon (TOC) and mineral carbon (MinC)).This method involves statistical analysis based on a sound knowledge of hydrocarbon source rock inorganic geochemistry. The workflow can be divided into four steps: (i) converting major elements (Si, Al, Fe, K, Na, Ca, Mg, Ti, and P) to their oxides, (ii) inferring modes of occurrence of elements using statistical analysis of geochemical data (major elements, TOC, and MinC), (iii) identifying the mineral types (oxide, aluminosilicates, carbonates, sulfide, and phosphate) according to elemental occurrences and calculating mineral phase concentrations, and (iv) verifying the results by comparing to XRD data on selected samples. The results, especially for brittle minerals such as quartz, carbonates (e.g. calcite, dolomite, and ankerite), and pyrite, show that the estimated mineral compositions correspond closely and consistently with measured mineralogy obtained from XRD. This method takes advantage of bulk geochemical data already available for hydrocarbon potential and chemostratigraphic studies, without devoting additional samples and cost for XRD analysis.     

西北印度洋中脊玄武岩源区地幔特征

利用全球岩石地球化学数据库(Pet DB)中有关卡尔斯伯格洋脊(CR)、北中印度洋脊(NCIR)及南中印度洋脊(SCIR)玄武岩的微量元素及同位素组成数据,分析了玄武岩的元素地球化学特征及其沿脊轴的变化,旨在探讨玄武岩源区地幔的(不)均一性及岩浆作用过程的差异。初步研究结果表明:CR、NCIR及SCIR玄武岩组成相近,仅在个别脊段表现有微量稀土元素和同位素组成上的差异,玄武岩整体与N-MORB组成特征相近,与先前通常认为的典型印度洋中脊玄武岩不同。玄武质岩浆主要源自尖晶石二辉橄榄岩地幔的熔融,岩浆源区主要由两个地幔端元构成,即以亏损型地幔(DMM)为主(69%),其次为富集型地幔(EMⅡ,27%)。富集组分可能源自古老陆壳物质的混染。自CR经NCIR到SCIR整个印度洋中脊西北分支玄武岩的Sr、Nd及Pb同位素组成表现出均一性,表明岩浆源区地幔组成相近。在SCIR 19°S附近脊段岩浆源区地幔存在有不均一性,有EMⅡ型地幔端元混入的迹象。在CR 3.5°N附近脊段,玄武岩明显富集K、Ba、La及U等微量元素,但由于缺少同位素数据,源区地幔特征有待进一步研究。在上述研究成果的基础上,提出了该区大比例尺的调查填图及密集采样和精细室内分析是CR深入研究的基础,同时加强Sr、Nd、Pb及Re、Os、Be等同位素分析测试,可提供揭示CR地幔不均一性的可靠依据,而厘清印度洋型地幔对CR的影响程度则有助于深入认识地幔不均一性的成因及地幔动力学过程。     

南海中尺度涡强度的季节和年际变化分析

为了研究南海中尺度涡强度的季节和年际变化规律,利用Matlab提取50 a(1958~2007年)简单海洋资料同化(Simple Ocean Data Assimilation,SODA)月平均数据集中流场和海表面高度场数据,应用一个涡旋自动探测算法对南海中尺度涡初始生成位置进行分析,并分析了海表面高度异常均方根值的季节变化和年际变化。结果表明:50 a里南海中尺度涡主要分布在吕宋岛西北海域、吕宋岛西南海域和越南以东广大海域,秋、冬季中尺度涡能量较高,春季中尺度涡最弱,中尺度涡强度高值区年际变化明显。从季节变化上看,海面高度异常均方根春、夏季最小,秋冬季最大;从年际变化上看,与同时期Nino3指数有显著负相关,周期大约为3 a。     

长江口及其邻近海域叶绿素a分布特征及其与低氧区形成的关系

于2013年3月和8月研究了长江口及其邻近海域叶绿素a的分布特征,并对环境因子和长江冲淡水对浮游植物生物量分布的影响进行了探讨。结果表明,叶绿素a浓度在丰水期较高,平均值为5.18μg/L,最高值达32.05μg/L,现场海水出现变色现象;与同期历史资料对比分析,发现该海域叶绿素a浓度呈现出波动增长趋势。丰水期与枯水期叶绿素a的相对高值区均位于冲淡水的中部,122.5°E~123°E之间;丰水期在调查海域出现溶解氧低值区与低氧区,最低值仅为0.64 mg/L;发现低氧区出现位置北移、面积扩大和溶解氧最低值下降的趋势。底层溶解氧低值区分布与表层叶绿素高值区大致吻合,表明低氧现象与表层浮游植物的生长和现存量密切相关,在跃层存在的水体中表层浮游植物的大量繁殖易造成底层低氧区的出现。     

Optimal routing for waste collection: a case study in Singapore

ABSTRACT

To collect and dispose growing amounts of municipal solid waste (MSW) changed to be a hot topic along with the rapid urbanization in past decades. Cities are more and more dependent on the incineration instead of landfilling due to the cost-efficiency and environmental concerns. Considering the limited number of incineration plants and complicated situation of transportation in both spatial and temporal dimensions in different cities, the optimal routing for waste collection turns to be meaningful research topic. In this research, the ant colony optimization (ACO)-based multi-objective routing model coupled with min-max model and Dijkstra’s algorithm is proposed to address the question of which route to take from these waste-generating points to the target incineration plant(s) considering travel time, accident probability (black spots), and population exposure, so as to support the routing decision-making. The model is successfully implemented in Singapore and the effectiveness of the model has also been justified. Besides, few limitations of this research have also been discussed, some of which would also be the future directions of our research, especially the design and integration of a web-based routing decision-making support system.     

Applying disk-based discontinuous deformation analysis (DDA) to simulate Donghekou landslide triggered by the Wenchuan earthquake

In this paper, for the first time, disk-based discontinuous deformation analysis (DDA) is applied to simulate a real landslide triggered by an earthquake. For this purpose, the kinematic behaviour of the Donghekou landslide triggered by the Wenchuan earthquake is simulated and the results obtained using disk-based DDA are compared with actual data. The comparisons show that there is a good agreement between the results obtained using disk-based DDA and observed data. The simulation results provided an understanding of the failure behaviour and temporal evolution of the landslide. This study shows that disk-based DDA is a practical numerical tool that can be used to simulate the post-failure behaviour of landslides triggered by an earthquake.     

基于LabView的松科2井项目管理系统

松科二井2013年正式启动,2018年5月完井,历时6年,最终井深7018 m。项目执行过程中,形成合同700多个、文件200多个、汇款流水1000多笔、报账流水1600多笔。针对松科二井合同、文件繁多,财务流程繁杂,涉及项目多的特点,基于LabVIEW平台设计了一套项目管理系统。该系统可全程记录松科二井上述合同、文件、汇款和报账信息,建立合同及对应批次汇款和报销的勾稽关系,具有模糊查询、修改、超链接等功能。     

四川江油马角坝刺林包剖面二叠-三叠系间粘土岩研究

二叠-三叠纪之交华南地区普遍发育火山成因的粘土岩,其对于了解二叠纪末大规模火山活动及扬子板块碎屑物质来源具有重要意义。本文对扬子西缘马角坝刺林包剖面飞仙关组底部粘土岩进行了碎屑锆石U-Pb定年及原位Hf同位素测试、X衍射和全岩地球化学分析,以揭示粘土岩的岩石成分及物源信息。镜下特征、X衍射及主量元素特征表明岩石中粘土矿物主要为伊利石,含少量方解石、石英。碎屑锆石年龄显示,特征峰值年龄主要集中在2 615~2 383、1 868~1 328、1 186~778和430~246 Ma,并出现~250 Ma特征高峰,结合原位Hf同位素特征表明锆石与秦岭造山带、华南典型PTB剖面粘土岩及峨眉山大火成岩省具有较高的相似性。同时,通过微量、稀土元素分析发现粘土岩中Zr、Hf、Th、Cr、Co、Ti相对富集,与华南典型PTB粘土岩和峨眉山玄武岩相近,并结合构造背景及锆石特征,综合认为刺林包剖面PTB粘土岩来自于秦岭造山带及龙门山岛链局部剥蚀区、二叠纪末火山活动和峨眉山大火成岩省剥蚀岩体。     

Results of magnetotelluric surveyon reference geophysical profiles of the Karaton-Sarkamys block in Kazakhstan

A digital geoelectric model of the Karaton-Sarkamys block located in the southern (Kazakhstan) part of the Caspian Depression has been developed on the basis of processing and interpretation of magnetotelluric sounding data. Geoelectric sections and structural maps of geoelectric layers have been constructed. It has been shown that magnetotelluric sounding combined with seismic and GIS data can be efficiently used to obtain additional information on the lithologic and reservoir properties of petroleum plays.