固相吸附毒素跟踪技术(SPATT)在浙江南麂海域的应用

浙江南麂岛海域是我国近岸贝类的重点养殖区,近年来一直遭受脂溶性贝类毒素(lipophilic shellfish toxins,LSTs)的污染,威胁着人类健康。为了建立有效的食品安全预警方法,本研究利用固相吸附毒素跟踪技术(solid phase adsorption toxin tracking,SPATT)在该海域进行了为期一年的野外监测和LSTs毒素分析。结果表明:7种LSTs毒素在SPATT(DIAION?HP20)中被检出,分别是大田软海绵酸(okadaic acid,OA)、鳍藻毒素-1(dinophysistoxin-1,DTX-1)、虾夷扇贝毒素(yessotoxin,YTX)及其衍生物homo YTX、扇贝毒素-2(pectenotoxin-2,PTX-2)及其衍生物7-epi-PTX2sa和环亚胺毒素(gymnodimine,GYM);有8种毒素在厚壳贻贝(Mytilus galloprovincialis)中被检出,分别是OA、DTX1、homo YTX、PTX2、7-epi-PTX2sa、GYM、原多甲藻酸贝类毒素-3(azaspiracid-3,AZA-3)和虾夷扇贝毒素衍生物45-OH-homo YTX。整体而言,SPATT(HP20)中吸附的毒素种类与贝肉中监测出的毒素种类大体上一致,且两者间OA、DTX1和PTX2的浓度在时间上具有较好的相关性,可见SPATT(HP20)对这些LSTs毒素具有较高的灵敏度,有望作为水体中LSTs毒素的预警监测材料。南麂岛海域LSTs分布特征明显,夏季最高,其次是春秋季,冬季最低,其中2014年夏季贝肉中OA毒素含量高达77.19ng/g贝肉,超出国家限量标准(45ng/g贝肉)比例达11.76%,为浙江南麂海域贻贝的食用安全带来隐患。     

Stability and capsizing analysis of nonlinear ship rolling in wind and stochastic beam seas

Considering the actual seaway condition, stability and capsizing of nonlinear ship rolling system in stochastic beam seas is of significant importance for voyage safety. Safe zone are defined in the phase space plan of the unperturbed Hamilton system to qualitatively distinguish ship motions as capsize and noncapsize. Capsize events are defined by solutions passing out of the safe zone. The probability of such an occurrence is studied by virtue of the random Melnikov function and the concept of phase space flux. In this paper, besides conventional wave excitation, the effect of wind load is also taken into account. The introduction of wind load will lead to asymmetry, in other words, it transforms the symmetric heteroclinic orbits into asymmetric homoclinic orbits. For asymmetric dynamical system, the orbital analytic solutions and its power spectrum are not readily available, and the technique of discrete time Fourier transformation (DTFT) is used. In the end, as verification of theoretical critical significant wave height, capsizing probability contour diagram is generated by means of numerical simulation. The contour diagram shows that these analytical methods provide reliable and predictive results about the likelihood of a vessel capsizing in a given seaway condition.     

A novel method to estimate mineral compositions of mudrocks: A case study for the Canadian unconventional petroleum systems

The mineral composition of mudrocks is an essential attribute in controlling the reservoir quality of unconventional petroleum systems. The present study introduces a semi-quantitative method to estimate mineral phases of mudrocks in various Canadian unconventional hydrocarbon systems using total elemental analysis (inductively coupled plasma-mass spectrometry (ICP-MS)) and Rock-Eval data (total organic carbon (TOC) and mineral carbon (MinC)).This method involves statistical analysis based on a sound knowledge of hydrocarbon source rock inorganic geochemistry. The workflow can be divided into four steps: (i) converting major elements (Si, Al, Fe, K, Na, Ca, Mg, Ti, and P) to their oxides, (ii) inferring modes of occurrence of elements using statistical analysis of geochemical data (major elements, TOC, and MinC), (iii) identifying the mineral types (oxide, aluminosilicates, carbonates, sulfide, and phosphate) according to elemental occurrences and calculating mineral phase concentrations, and (iv) verifying the results by comparing to XRD data on selected samples. The results, especially for brittle minerals such as quartz, carbonates (e.g. calcite, dolomite, and ankerite), and pyrite, show that the estimated mineral compositions correspond closely and consistently with measured mineralogy obtained from XRD. This method takes advantage of bulk geochemical data already available for hydrocarbon potential and chemostratigraphic studies, without devoting additional samples and cost for XRD analysis.     

Tectono–Thermal Evolution, Hydrocarbon Filling and Accumulation Phases of the Hari Sag, in the Yingen–Ejinaqi Basin, Inner Mongolia, Northern China

This work restored the erosion thickness of the top surface of each Cretaceous formations penetrated by the typical well in the Hari sag, and simulated the subsidence burial history of this well with software BasinMod. It is firstly pointed out that the tectonic subsidence evolution of the Hari sag since the Cretaceous can be divided into four phases: initial subsidence phase, rapid subsidence phase,uplift and erosion phase, and stable slow subsidence phase. A detailed reconstruction of the tectonothermal evolution and hydrocarbon generation histories of typical well was undertaken using the EASY R_0% model, which is constrained by vitrinite reflectance(R_0) and homogenization temperatures of fluid inclusions. In the rapid subsidence phase, the peak period of hydrocarbon generation was reached at c.a.105.59 Ma with the increasing thermal evolution degree. A concomitant rapid increase in paleotemperatures occurred and reached a maximum geothermal gradient of about 43-45℃/km. The main hydrocarbon generation period ensued around 105.59-80.00 Ma and the greatest buried depth of the Hari sag was reached at c.a. 80.00 Ma, when the maximum paleo-temperature was over 180℃.Subsequently, the sag entered an uplift and erosion phase followed by a stable slow subsidence phase during which the temperature gradient, thermal evolution, and hydrocarbon generation decreased gradually. The hydrocarbon accumulation period was discussed based on homogenization temperatures of inclusions and it is believed that two periods of rapid hydrocarbon accumulation events occurred during the Cretaceous rapid subsidence phase. The first accumulation period observed in the Bayingebi Formation(K_1 b) occurred primarily around 105.59-103.50 Ma with temperatures of 125-150℃. The second accumulation period observed in the Suhongtu Formation(K_1 s) occurred primarily around84.00-80.00 Ma with temperatures of 120-130℃. The second is the major accumulation period, and the accumulation mainly occurred in the Late Cretaceous. The hydrocarbon accumulation process was comprehensively controlled by tectono-thermal evolution and hydrocarbon generation history. During the rapid subsidence phase, the paleo temperature and geothermal gradient increased rapidly and resulted in increasing thermal evolution extending into the peak period of hydrocarbon generation,which is the key reason for hydrocarbon filling and accumulation.     

柴达木盆地东部上石炭统克鲁克组碎屑岩储层特征及控制因素

柴达木盆地上石炭统克鲁克组是该区重要的古生界勘探层位,组内发育多套良好的碎屑岩层。为探究其岩石物性特征及控制因素,本次以野外露头调查为基础,利用普通薄片、铸体薄片鉴定及扫描电镜等手段,结合物性测试和压汞资料,对克鲁克组碎屑岩纵向分布规律,储层岩性、物性、孔喉特征及孔隙类型进行分析。认为克鲁克地层中克2段发育的三角洲前缘亚相和克3段的具障壁海岸潮坪相的大套含砾粗砂岩、粗砂岩砂体原生、次生孔洞发育,孔喉大、分布集中、分选好,为有利的碎屑岩储层。早成岩期压实作用、重结晶及胶结作用对克鲁克组砂岩的原生孔隙破坏严重,晚成岩期储层改造形成的溶孔、裂缝—溶孔是油气成藏的主要储存空间。该研究为预测柴东石炭系克鲁克组油气有利区域提供依据,为今后该地区的油气勘探提供理论支撑。     

Research Progress and Prospect on Reactivation of Ancient Landslides

The ancient landslide has endured long-term slope evolution which results in its complicated material and special rock-soil properties. The risk of ancient landslide reactivation is substantially increasing due to the increase of intensified human engineering activities and the frequency of extreme weather events. Many ancient landslides have been reactivated all over the world and led to serious fatalities and severe damage to many important engineering facilities such as transportation and hydropower engineering projects. On the basis of the analysis of the research situation about the ancient landslides at home and abroad, the main research advances were summarized including the regional developing laws and recognizing of the ancient landslides, the mechanics properties of ancient landslide body and related sliding zone, reactivation mechanism of ancient landslides, reactivating process and modeling analysis of ancient landslides, early recognization of ancient landslide reactivation, etc. To meet the demands of disaster prevention and reduction, three key scientific issues were put forward to be solved: ①automaticaly establishing the methodology and identification criterions for recognition of ancient landslide; ②revealing the reactivation mechanism of ancient landslide based on a new strength theory; ③establishing the early rapid recognition method and predictive model for ancient landslide reactivation. Solving the above mentioned scientific theory and methodology will facilitate the planning and site selection of major projects as well as the disaster prevention and reduction in ancient landslide developing areas.     

测井地质学前世、今生与未来——写在《测井地质学·第二版》出版之时

测井地质学以地质学和测井学的方法理论为指导,综合运用各种测井信息,来解决基础地质和石油地质的地质问题。经过数十年发展,测井地质学在油气勘探开发各个环节得到广泛应用。非常规油气的兴起使得测井地质学正面临多重挑战和全新探索,亟需建立针对非常规油气的测井地质学综合方法理论体系。本文以《测井地质学·第二版》出版为契机,系统归纳了测井地质学的起源及发展历程、主要研究内容和研究方法流程。然后总结了测井资料与地震、地质信息的匹配性,并分析了不同探测特性测井方法纵向分辨率区间特征。在此基础上评述了测井地质学在井旁构造解析、沉积学特征研究、层序地层划分、地应力方向判别及大小计算、井壁裂缝识别与评价、烃源岩评价以及非常规油气“七性关系”综合评价当中的应用。但由于测井资料的负载能力有限性、测井与地质信息属性不对应性以及测井资料本身的多解性,使得测井地质学在测井—地质转换、非常规油气测井评价及其与人工智能融合方面还存在一定的问题。因此加强基础岩石物理研究,挖掘测井曲线中包含的地质信息,并与人工智能相结合,将拓展测井地质学研究的精度和广度,从而使其未来可更好地应用至非常规油气测井评价等实践工作中。     

全风化花岗岩地层中高固相离析浆液灌浆机理研究

全风化花岗岩地层稳定性差、遇水易发生崩解,工程上使用常规材料防渗加固注浆时效果较差。针对这一情况,依托湖南省郴州市莽山水库防渗加固灌浆项目,通过自主设计的全风化花岗岩地层注浆室内模拟试验装置,进行模拟注浆试验,实现了浆液在整个注浆过程中的扩散情况模拟,对不同注浆压力、不同位置点所取试样开展单轴抗压、抗剪强度及渗透率测试试验,对不同注浆压力下完整结石体取样观察,研究以全风化花岗岩颗粒为配方主体材料的高固相离析浆液在全风化花岗岩地层的防渗加固效果及浆液扩散模式。结果表明:该浆液在全风化花岗岩地层扩散过程中经历了渗透扩散、挤密压缩、劈裂扩展三个阶段,是一种复合注浆形式;以全风化花岗岩颗粒为主体的高固相离析浆液在全风化花岗岩地层注浆中效果显著,随着注浆压力提升,单轴抗压强度显著提升为原土体的3.25～13.67倍,抗剪强度在不同法向压力情况下提升为原土体的1.63～2.69倍,渗透系数从10?4 cm/s下降至10?5 cm/s甚至10?6 cm/s。     

CINRAD-SA双偏振雷达资料在降水估测中的应用初探

对基于水平反射率ZH和差分传播相移率K_(DP)的降水估测综合法R(C)进行了改进,并对广州S波段双偏振雷达2016年2次飑线和2次台风降水过程的Φ_(DP)使用小波分析进行滤波处理,在此基础上使用变距最小二乘法拟合得到K_(DP)的值。分别使用R(C)和R(Z_H)法对2次飑线和2次台风降水过程进行降水估算,将估算结果和雨量计小时雨量进行了对比,并将两种方法的评估结果进行了对比。结果表明:(1)对于飑线类型降水,R(C)法对5 mm·h~(-1)以上的降水估测精度要好于R(Z_H)法,且降水率越大,R(C)法优势越明显,当降水率≥20 mm·h~(-1)时,两次过程R(C)法比R(Z_H)法的平均相对误差(RE)降低了17. 2%,平均绝对误差(AE)减少了1.89 mm,平均均方根误差(RMSE)减少了1.66 mm;(2)对于台风类型降水,R(C)法对5 mm·h~(-1)以上的降水估测精度也好于R(Z_H)法,当降水率≥20 mm·h~(-1)时,两次过程R(C)法比R(Z_H)法的平均RE降低了33. 19%,平均AE减少了3. 95 mm,平均RMSE减少了4.05 mm;(3)对于飑线和台风两种类型降水R(C)法都明显改善了降水率较大时的R(Z_H)法低估问题,但R(C)法在降水率10 mm·h~(-1)时也存在低估,可能是由雨滴谱资料观测误差导致拟合的系数偏小或雷达硬件造成的观测偏差等造成的。     

基于脑电信号评价情绪状态及听觉激励对改善情绪的研究

如何从脑活动数据中发现具有生物学意义的知识及规律,正成为当今神经信息学理论与实践研究的热点与难点.基于脑电的情绪识别和情绪及其脑机制的关联研究已经成为神经工程和生物医学工程领域的热门课题.本研究基于脑电信号评价情绪状态,尝试借助脑电耳机来监测"毫无头绪"的脑电波,重点开展了听觉激励对改善焦虑情绪状态的实验研究.借助特定中国古风纯音乐产生听觉信号激励,激发出被试者平静放松的情绪状态,从而改善焦虑,发现音乐和情绪之间可能存在的关系.将来在BCI技术研究的基础之上,情绪识别可以进一步满足患有特定疾病（ALS症、脑瘫、脑干中风、脊髓损伤等）的患者人群的某些更高级的需求,即通过脑电分析出其对事物的喜好度,比如音乐的选择,从而设计出更加友善和智能的BCI系统,在医疗康复领域具有很好的应用前景.