时空间行为视角下交通与社会排斥研究进展

新型城镇化背景下,建设具有包容性和公平正义的城市,成为社会可持续发展的重要内容。交通相关的社会排斥研究主要包括理论研究、社会空间分析、交通与社会排斥的比较研究等,形成了基于空间和基于人群的2种研究范式。但关于不同地理环境和不同社会群体的交通与社会排斥研究,仍然缺乏对空间与行为互动的内在因果关系的有效论证,迫切需要从地理空间和不同社会群体的时空间行为入手,厘清交通与社会排斥的概念内涵和作用机理。论文梳理了交通与社会排斥的概念内涵、研究范式与测度方法,重点从时空间行为视角阐述了交通维度的社会排斥研究的内在逻辑和实证结果,并结合中国实际,试图构建时空间和行为互动的交通与社会排斥研究框架,为消除交通维度的社会排斥障碍、建构多尺度社会融合路径、建设更为包容和公平正义的城市提供实践基础和理论支持。     

Numerical study of soil heterogeneity effects on contaminant transport in unsaturated soil (model development and validation)

The movement of chemicals through soil to groundwater is a major cause of degradation of water resources. In many cases, serious human and stock health implications are associated with this form of pollution. The study of the effects of different factors involved in transport phenomena can provide valuable information to find the best remediation approaches. Numerical models are increasingly being used for predicting or analyzing solute transport processes in soils and groundwater. This article presents the development of a stochastic finite element model for the simulation of contaminant transport through soils with the main focus being on the incorporation of the effects of soil heterogeneity in the model. The governing equations of contaminant transport are presented. The mathematical framework and the numerical implementation of the model are described. The comparison of the results obtained from the developed stochastic model with those obtained from a deterministic method and some experimental results shows that the stochastic model is capable of predicting the transport of solutes in unsaturated soil with higher accuracy than deterministic one. The importance of the consideration of the effects of soil heterogeneity on contaminant fate is highlighted through a sensitivity analysis regarding the variance of saturated hydraulic conductivity as an index of soil heterogeneity. Copyright © 2011 John Wiley & Sons, Ltd.     

Distributed discharge and sediment concentration predictions in the sub‐humid Ethiopian highlands: the Debre Mawi watershed

Experimental research in the Ethiopian highlands found that saturation excess induced runoff and erosion are common in the sub‐humid conditions. Because most erosion simulation models applied in the highlands are based on infiltration excess, we, as an alternative, developed the Parameter Efficient Distributed (PED) model, which can simulate water and sediment fluxes in landscapes with saturation excess runoff. The PED model has previously only been tested at the outlet of a watershed and not for distributed runoff and sediment concentration within the watershed. In this study, we compare the distributed storm runoff and sediment concentration of the PED model against collected data in the 95‐ha Debre Mawi watershed and three of its nested sub‐watersheds for the 2010 and 2011 rainy seasons. In the PED model framework, the hydrology of the watershed is divided between infiltrating and runoff zones, with erosion only taking place from two surface runoff zones. Daily storm runoff and sediment concentration values, ranging from 0.5 to over 30 mm and from 0.1 to 35 g l^?1, respectively, were well simulated. The Nash Sutcliffe efficiency values for the daily storm runoff for outlet and sub‐watersheds ranged from 0.66 to 0.82, and the Nash–Sutcliffe efficiency for daily sediment concentrations were greater than 0.78. Furthermore, the model uses realistic fractional areas for surface and subsurface flow contributions, for example between saturated areas (15%), degraded areas (30%) and permeable areas (55%) at the main outlet, while close similarity was found for the remaining hydrology and erosion parameter values. One exception occurred for the distinctly greater transport limited parameter at the actively gullying lower part of the watershed. The results suggest that the model based on saturation excess provides a good representation of the observed spatially distributed runoff and sediment concentrations within a watershed by modelling the bottom lands (as opposed to the uplands) as the dominant contributor of the runoff and sediment load. Copyright © 2014 John Wiley & Sons, Ltd.     

Evolution of scouring process downstream of grade‐control structures under steady and unsteady flows

For many incised channels, one of the most common strategies is to install some hard structures, such as grade‐control structures (GCSs), in the riverbed to resist further incision. In this study, a series of experiments, including both steady and unsteady flow conditions, were conducted to investigate the scouring process downstream of a GCS. Three distinct phases, including the initial, developing and equilibrium phases, during the evolution of scour holes were identified. In addition, a semi‐empirical method was proposed to predict the equilibrium scour‐hole profile for the scour countermeasure design. In general, the comparisons between the experimental and simulated results are reasonably consistent. As the studies on temporal variation of the scour depth at GCSs caused by floods are limited, the effect of flood hydrograph shapes on the scour downstream of GCSs without upstream sediment supply was also investigated experimentally in this study. Based on the dimensional analysis and the concept of superposition, a methodology is proposed to simulate the time evolution of the maximum scour depth downstream of a GCS for steady flows. Moreover, the proposed scheme predicts reasonably well the temporal variations of the maximum scour depth for unsteady flows with both single and multiple peak. Copyright © 2012 John Wiley & Sons, Ltd.     

Groundwater dating with 3H and SF6 in relation to mixing patterns,transport modelling and hydrochemistry

A comprehensive study of a sandy aquifer of deltaic origin in southern Poland included water chemistry, isotopes, dissolved trace gases and transport modelling. Tritium, sulphur hexafluoride (SF₆) and freons (F‐11, F‐12 and F‐113) showed the presence of modern waters in the recharge areas and shallow confined parts of the aquifer. The presence of older Holocene waters farther from the recharge areas was indicated by lack of ³H, SF₆ contents ≤0·02 fmol l⁻¹ and relatively low ¹⁴C values. The discharge from the system is by upward seepage in the valley of a major river. Pre‐Holocene waters of a cooler climate, identified on the basis of δ¹⁸O, δ²H, ¹⁴C, Ne and Ar data, were found in some distant wells. Concentrations of N₂, Ne and Ar determined by gas chromatography were used for calculating the noble gas temperatures, air excess needed for correction of SF₆, and nitrogen content released by denitrification process. The time series of ³H content available for some wells supplied quantitative information on age distributions and the total mean ages of flow through the unsaturated and saturated zones. The derived ³H age distributions turned out to be very wide, with mean values in the range of about 30 to 160 years. For each well with determined ³H age, the SF₆ data showed either a lower age range or the possibility of a lower age as expected due to shorter travel times of SF₆ through the unsaturated zone, which most probably also resulted in different types of age distributions of these tracers. Freons appeared to be of little use for individual age determinations. A quantitative estimation of two‐component mixing from SF₆ ³H relations is not possible unless the travel time of ³H through the unsaturated zone is comparable to that of SF₆. The ratio of integrals of the response function over the age range with tracer and the whole response function yields the ratio of water with tracer to total flow of water. That ratio is a tracer‐dependent function of time. Transport modelling of SF₆ tracer done with MT3D code yielded initially large discrepancies between calculated and measured tracer concentrations. Some discrepancies remained even after calibration of the transport model with SF₆. Simulation of tritium contents with a calibrated transport model yielded reasonable agreement with measured contents in some wells and indicated a need for further investigations, particularly in the eastern part of the aquifer. The existence of distinct hydrochemical zones is consistent with the tracer data; young waters with measurable ³H and SF₆ contents are aerobic and of HCO₃ Ca or HCO₃ SO₄ Ca types. Slightly elevated Na and Cl contents, as well as the highest concentrations of SO₄ and NO₃ within this zone are due to anthropogenic influences. Anaerobic conditions prevail in the far field, under the confining cover, where pre‐bomb era Holocene waters dominate. In that zone, dissolved oxygen, NO₃ and U contents are reduced, and Fe, Mn and NH₄ contents increase. In the third zone, early Holocene and glacial waters occur. They are of HCO₃ Ca Na or HCO₃ Na types, with TDS values higher than 1 g l⁻¹ and Na content higher than 200 mg l⁻¹, due to either small admixtures of ascending or diffusing older water or freshening of marine sediments, a process that is probably occurring till the present time. Copyright © 2005 John Wiley & Sons, Ltd.     

Peat porewater chloride concentration profiles in the Everglades during wet/dry cycles from January 1996 to June 1998: field measurements and theoretical analysis

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.     

Using time‐domain reflectometry to characterize shallow solute transport in an oak woodland hillslope in northern California,USA

The natural heterogeneity of water and solute movement in hillslope soils makes it difficult to accurately characterize the transport of surface‐applied pollutants without first gathering spatially distributed hydrological data. This study examined the application of time‐domain reflectometry (TDR) to measure solute transport in hillslopes. Three different plot designs were used to examine the transport of a conservative tracer in the first 50 cm of a moderately sloping soil. In the first plot, which was designed to examine spatial variability in vertical transport in a 1·2 m² plot, a single probe per meter was found to adequately characterize vertical solute travel times. In addition, a dye and excavation study in this plot revealed lateral preferential flow in small macropores and a transport pattern where solute is focused vertically into preferential flow pathways. The bypass flow delivers solute deeper in the soil, where lateral flow occurs. The second plot, designed to capture both vertical and lateral flow, provided additional evidence confirming the flow patterns identified in the excavation of the first plot. The third plot was designed to examine lateral flow and once again preferential flow of the tracer was observed. In one instance rapid solute transport in this plot was estimated to occur in as little as 3% of the available pore space. Finally, it was demonstrated that the soil anisotropy, although partially responsible for lateral subsurface transport, may also homogenize the transport response across the hillslope by decreasing vertical solute spreading. Copyright © 2002 John Wiley & Sons, Ltd.     

Transfort of oxygen,nutrients and carbonates by the Kuroshio Current

Measured concentrations of dissolved oxygen, phosphate, silicate, total alkalinity and calculated total CO₂ in a section between 121° E and 125° E across the Kuroshio near 22° N off Taiwan and the geostrophic velocity were used to estimate the gross transport of oxygen, nutrients and carbonates. The flux of dissolved oxygen is 6.7×10⁶ mol/s northward and 0.9×10⁶ mol/s southward. The net flux equals 5.8×10⁶ mol/s down-stream. The northward flux of phosphate is 22.6×10³ mol/s; the southward flux is 1.4×10³ mol/s. The net phosphate flux is 21.2×10³ mol/s northward. The flux of silicate is 967×10³ northward and 59×10³ mol/s southward; the net transport is 908×10³ mol/s down-stream. The flux of alkalinity is 75.5×10⁶ mol/s northward, and 10.8×10⁶ mol/s southward, the net flux is 64.7×10⁶ mol/s northward. For total CO₂ the transport is 73.4×10⁶ mol/s northward and 10.8×10⁶ mol/s southward, or a net transport of 62.6×10⁶ mol/s horthward.     

Kinematic wave solutions for pollutant transport over an infiltrating plane with finite‐period mixing and mixing zone

Kinematic wave solutions are derived for transport of a conservative non‐point‐source pollutant during a rainfall‐runoff event over an infiltrating plane for two cases: (i) finite‐period mixing and (ii) soil‐mixing zone. Rainfall is assumed to be steady, uniform and finite in duration, and it is assumed to have zero concentration of pollutants. Infiltration is assumed constant in time and space. Prior to the start of rainfall, the pollutant is distributed uniformly over the plane. In the first case, when rainfall occurs, the mixing of pollutant in the runoff water occurs in a finite period of time. In the second case, the chemical concentration is assumed to be a linearly decreasing function of rainfall intensity and overland flow. The solute concentration and discharge are found to depend on the flow characteristics as well as the solute concentration parameters. The characteristics of solute concentration and discharge graphs seem to be similar to those reported in the literature and observed in laboratory experiments. Copyright © 2002 John Wiley & Sons, Ltd.     

Near-infrared spectral monitoring of Triton with IRTF/SpeX I: establishing a baseline for rotational variability

We present eight new 0.8 to 2.4 μm spectral observations of Neptune's satellite Triton, obtained at IRTF/SpeX during 2002 July 15-22 UT. Our objective was to determine how Triton's near-infrared spectrum varies as Triton rotates, and to establish an accurate baseline for comparison with past and future observations. The most striking spectral change detected was in Triton's nitrogen ice absorption band at 2.15 μm; its strength varies by about a factor of two as Triton rotates. Maximum N₂ absorption approximately coincides with Triton's Neptune-facing hemisphere, which is also the longitude where the polar cap extends nearest Triton's equator. More subtle rotational variations are reported for Triton's CH₄ and H₂O ice absorption bands. Unlike the other ices, Triton's CO₂ ice absorption bands remain nearly constant as Triton rotates. Triton's H₂O ice is shown to be crystalline, rather than amorphous. Triton's N₂ ice is confirmed to be the warmer, hexagonal, β N₂ phase, and its CH₄ is confirmed to be highly diluted in N₂ ice.