A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

Variation in Water Masses on Shelf of Northern Bering Sea in September 2016-2018

Abstract

Based on hydrological data obtained during the 7th to 9th Chinese National Arctic Research Expeditions in the summers of 2016–2018, the main water structure on the shelf of the northern Bering Sea and the volume and heat fluxes of the Bering Strait throughflow were analyzed. Distinct variability was identified in the three Pacific water masses feeding the strait - Anadyr Water (AW), Bering Shelf Water (BSW) and Alaskan coastal water (ACW). Overall, the temperature and salinity of the entire section increased each year, with 2018 showing significant anomalies, i.e., a temperature anomaly of up to 1?°C and a maximum salinity anomaly of 2. From 2016 to 2018, the extent of the ACW gradually narrowed in the eastern part of this section, while the AW expanded eastward each year. The net volume transport through each of the three sections increased poleward from 1.65?Sv to 2.76?Sv, with the AW increasing from 0?Sv to 1.03?Sv, the BSW varying between 0.52–1.65?Sv, and the ACW gradually decreasing from 1.04?Sv to disappearing completely. The net heat fluxes were also poleward, varying between 25.77 TW and 61.50 TW, and showing a significant increase. Significant variations in magnitude and extent were observed in each water mass of the Bering Strait throughflow, which could produce widespread effects in the Arctic Ocean and the global ocean beyond.     

台湾海峡海流结构及海水通量

主要根据台湾海峡的实测海流资料，以夏、冬为代表季节，分析了台湾海峡２—３个纬向断面的海流结构，计算出各断面的海水通量。结果表明：夏季，台湾海峡中、北部海域各层的海流一般偏Ｎ向流动，Ｎ向的海水净通量为３．３２×１０６ｍ３·ｓ－１；冬季，高温高盐的黑潮水和南海水由南向北经南部断面进入台湾海峡，其海水通量分别为１．６９×１０６ｍ３·ｓ－１和０．５９×１０６ｍ３·ｓ－１；而东海水由北向南通过北部断面进入台湾海峡，其海水通量为１．０２×１０６ｍ３·ｓ－１，其中，有０．４０×１０６ｍ３·ｓ－１的海水沿着福建和广东近岸流进南海，其余０．６２×１０６ｍ３·ｓ－１的海水在台湾海峡北部混合后随同黑潮水和南海水流入东海。总之，流经台湾海峡的Ｎ向海水净通量为１．７４×１０６ｍ３·ｓ－１。     

Variations of the Kuroshio Axis South of Kyushu in Relation to the Large Meander of the Kuroshio

The characteristics of the Kuroshio axis south of Kyushu, which meanders almost sinusoidally, are clarified in relation to the large meander of the Kuroshio by analyzing water temperature data during 1961–95 and sea level during 1984–95. The shape of the Kuroshio axis south of Kyushu is classified into three categories of small, medium, and large amplitude of meander. The small amplitude category occupies more than a half of the large-meander (LM) period, while the medium amplitude category takes up more than a half of the non-large-meander (NLM) period. Therefore, the amplitude and, in turn, the curvature of the Kuroshio axis is smaller on average during the LM period than the NLM period. The mean Kuroshio axis during the LM period is located farther north at every longitude south of Kyushu than during the NLM period, with a slight difference west of the Tokara Islands and a large difference to the east. A northward shift of the Kuroshio axis in particular east of the Tokara Islands induces small amplitude and curvature of the meandering shape during the LM period. During the NLM period, the meandering shape and position south of Kyushu change little with Kuroshio volume transport. In the LM formation stage, the variation of the Kuroshio axis is small west of the Tokara Islands but large to the east due to a small meander of the Kuroshio. In the LM decay stage, the Kuroshio meanders greatly south of Kyushu and is located stably near the coast southeast of Kyushu. This revised version was published online in July 2006 with corrections to the Cover Date.     

台风“灿鸿”对长江口外海域悬浮体分布的影响

台风作为事件性的强动力因素,其对河口海域沉积环境的影响目前研究较少,开展典型台风事件对长江口外海域悬浮体分布的影响研究对于深入理解长江径流挟带陆源物质向东海陆架扩散机制等具有重要意义。利用2015年09号台风"灿鸿"过境前后长江口外海域现场调查数据,分析台风前后长江口外水体结构和悬浮体粒度分布变化,结合同期环境观测数据与开源数据,阐明台风对河口外海域悬浮体分布的影响机制。结果表明:长江口外海域悬浮体中细颗粒组分(≤ 128μm)主要为无机矿物颗粒,而粗颗粒组分(>128μm)主要是生源有机颗粒。生源有机粗颗粒主要分布于中上层水体,而无机细颗粒主要分布于底层水体,使得长江口外海域悬浮体平均粒径分布呈双层结构。台风前后悬浮体粒度分布变化反映了台风对长江口外海域物理和生物过程的双重影响,其中物理过程主要影响无机细颗粒分布变化,生物过程主要影响有机粗颗粒。台风期间强烈的偏北风使得长江冲淡水在口门外海域由东北输运转为往东输运,与长江冲淡水输运方向一致的表层无机细颗粒在台风后输运方向同样往东。另外,台风作用在河口区产生的下降流将12250-4站位底部再悬浮的泥质沉积物向东搬运至12300-4站,导致12300-4站底层悬浮体浓度增加、粒度变细。台风过境还造成长江口外海域初级生产力提高,而浮游植物生长对悬浮体中有机粗颗粒的形成有促进作用,使得口门外海域上层水体中有机粗颗粒体积浓度升高。长江口外海域由于台风过境导致悬浮体中无机细颗粒和生源有机颗粒含量均增加,使得其平均粒径整体变化不大。     

基于非充分掺混模式的流域来水组成模型

针对如何减小数值求解对流输运方程耗散误差的问题,引进断面计算浓度的概念来计算河段平均浓度,提出了非充分掺混模式的有限控制体积法离散对流输运方程的新算法,据此构建了模拟流域内的水源组成以及不同水源在流域内的时空变化情况的流域来水组成模型。通过数值试验与具体实例验证,结果表明所提出的非充分掺混模式的新算法可有效地提高流域来水模型的计算精度。     

The Creation of a National Agricultural Land Use Dataset: Combining Pycnophylactic Interpolation with Dasymetric Mapping Techniques

Agricultural Census data is summarised over spatially coarse reporting units for reasons of farm confidentiality. This is problematic for research at a local level. This article describes an approach combining dasymetric and volume preserving techniques to create a national land use dataset at 1 km² resolution. The results for an English county are compared with contemporaneous aggregated habitat data. The results show that the accurate estimates of local agricultural land use (Arable and Grass) patterns can be estimated when individual 1 km squares are combined into blocks of > 9 squares, thereby providing local estimates of agricultural land use. This in turn allows more detailed modelling of land uses related to specific livestock and cropping activities. The dataset created by this work has been subject to extensive external validation through its incorporation into a number of other national models: nitrate leaching (e.g. MAGPIE, NEAP‐N), waste, and pathogen modelling related to agricultural activity.     

Numerical simulation of a stratigraphic model

A multi-lithology diffusive stratigraphic model is considered, which simulates at large scales in space and time the infill of sedimentary basins governed by the interaction between tectonics displacements, eustatic variations, sediment supply, and sediment transport laws. The model accounts for the mass conservation of each sediment lithology resulting in a mixed parabolic, hyperbolic system of partial differential equations (PDEs) for the lithology concentrations and the sediment thickness. It also takes into account a limit on the rock alteration velocity modeled as a unilaterality constraint. To obtain a robust, fast, and accurate simulation, fully and semi-implicit finite volume discre tization schemes are derived for which the existence of stable solutions is proved. Then, the set of nonlinear equations is solved using a Newton algorithm adapted to the unilaterality constraint, and preconditioning strategies are defined for the solution of the linear system at each Newton iteration. They are based on an algebraic approximate decoupling of the sediment thickness and the concentration variables as well as on a proper preconditioning of each variable. These algorithms are studied and compared in terms of robustness, scalability, and efficiency on two real basin test cases.     

Application of FLATModel, a 2D finite volume code, to debris flows in the northeastern part of the Iberian Peninsula

FLATModel is a two-dimensional shallow-water approximation code with corrections and modifications that create a simulation tool adapted to debris-flows behaviour. FLATModel uses the finite volume method with the numerical implementation of the Godunov scheme and includes correction terms regarding the effect of flow over high slopes and curvature. Additionally, the stop-and-go phenomenon, the basal entrainment and a correction regarding the front inclination of the final deposit are incorporated into FLATModel. In addition, different flow resistance laws were integrated in the numerical code including Bingham, Herschel–Bulkley and Voellmy fluid model. Firstly, our numerical model was validated using analytical solutions of a dam-break scenario and published data on a laboratory experiment. Secondly, three real events, which occurred in the northeastern part of the Iberian Peninsula, were back-calculated. Although field observations of the three events are not very detailed, the back-analyses revealed interesting patterns on the flow dynamics, and the numerical results generally showed good agreement with field data. Comparing the different flow resistance laws, the Voellmy fluid model presents the best behaviour regarding both the flow behaviour and the deposit characteristics. Preliminary simulation runs incorporating the effect of basal entrainment offered satisfactory results, although the final volume is rather sensitive on the selected friction angle of channel-bed material. The outcomes regarding the correction of the calculated front inclination of the final deposit showed that this implementation strongly improves the simulation results and better represents steep fronts of final deposits.