The chemical changes of DOM from black waters to coastal marine waters by HPLC combined with ultrahigh resolution mass spectrometry

How dissolved organic matter (DOM) undergoes chemical changes during its transit from river to ocean remains a challenge due to its complex structure. In this study, DOM along a river transect from black waters to marine waters is characterized using an offline combination of reversed-phase high performance liquid chromatography (RP-HPLC) coupled to electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS), as well as tandem ESI-FTICR-MS. In addition, a water extract from degraded wood that mainly consists of lignins is used for comparison to the DOM from this transect. The HPLC chromatograms of all DOM samples and the wood extract show two major well-separated components; one is hydrophilic and the other is hydrophobic, based on their elution order from the C₁₈ column. From the FTICR-MS analysis of the HPLC fractions, the hydrophilic components mainly contain low molecular weight compounds (less than 400 Da), while the hydrophobic fractions contain the vast majority of compounds of the bulk C₁₈ extracted DOM. The wood extract and the DOM samples from the transect of black waters to coastal marine waters show strikingly similar HPLC chromatograms, and the FTICR-MS analysis further indicates that a large fraction of molecular formulas from these samples are the same, existing as lignin-like compounds. Tandem mass spectrometry experiments show that several representative molecules from the lignin-like compounds have similar functional group losses and fragmentation patterns, consistent with modified lignin structural entities in the wood extract and these DOM samples. Taken together, these data suggest that lignin-derived compounds may survive the transit from the river to the coastal ocean and can accumulate there because of their refractory nature.     

青岛近海浒苔暴发期大型底栖动物群落的生态研究

利用2008年7月3日至25日在青岛附近海域浒苔[Enteromorpha prolifera (Muell.)J.Ag]暴发期间进行的大型底栖动物定量分析资料,研究了该海域大型底栖动物群落在物种组成、生物量和丰度以及物种多样性方面的动态变化,以了解浒苔暴发对大型底栖动物的生态学影响.结果表明,本项目调查共采集到大型底...     

Surface energy and water vapor fluxes observed in a desert plantation in central Iran

Summertime observations of surface radiation budget, energy balance and atmospheric surface layer meteorology were made on an arid valley floor planted with Haloxylon aphyllum to combat desertification in central Iran. The surface microclimate is characterized and compared with other arid regions and the role of ‘desert greening’ on surface fluxes is considered. A high surface albedo (0.265) and large longwave radiation loss produced relatively low net radiation. Energy partitioning was dominated by sensible and ground heat fluxes with opposing diurnal asymmetry governed by strong diurnal variability in eddy diffusivity. The Bowen ratio was 2.53, which fell inside the range of other vegetated arid surfaces. Surface temperature gradients were strong both in the atmospheric surface layer and in the substrate, with consistent lapse conditions by day and inversions at night. The wind regime included a moderate daytime regional wind which displayed Coriolis turning and weaker nocturnal slope flows. Actual evapotranspiration (1 mm dy⁻¹) was only a small fraction of potential evapotranspiration. The diurnal pattern of AET indicates strong stomatal control. The desert greening effect of Haloxylon plantations provided atmospheric water and reduced sensible heat flux by up to 40%.     

基于GIS的区域经济统计分析模型研究及应用——以江西省为例

针对当前GIS软件不能有效满足区域经济统计分析的问题,提出了利用GIS技术重新构建区域经济统计分析模型的新思路。对该模型进行了具体建模和编程实现,并将该模型集成到区域经济统计分析系统中,最后利用该系统对江西省各地区经济进行了统计分析的应用实践。研究表明,该区域经济统计分析模型能够有效地应用于区域的经济统计分析,方便政府部门制定与经济相关的各种决策,具有广泛的应用推广价值。     

地理经纬双向过渡带和复杂地形下气候的过渡性和特异性 ——以宜昌市为例

宜昌处在我国地形第二、第三级阶梯的过渡地带,又位于我国南北过渡带秦巴山地南麓的中低纬度过渡带,长江中上游结合部,山地河谷平原并存,地形复杂,垂直高差大。气候资料分析和文献调研表明,宜昌天气气候因特殊地理环境具有过渡性和特异性：（1）年平均气温主要随地形高度递减,年总降水量主要随纬度升高减小。（2）年暴雨日数、连阴雨天数,在中西部随纬度升高而递减,等值线近似纬向排列;东部随地形升高而递增,等值线近似经向排列。（3）山地平原过渡带地形的阻挡滞留、辐合抬升等对极端短时强降水有明显加强作用,这种作用在秦岭与黄淮过渡带、太行山与华北平原过渡带有相似的天气气候效应。（4）宜昌位于江淮梅雨的西界、华西秋雨的东界,具有天气气候“分水岭”特征。（5）宜昌是暴雨雨团、西南涡移动的主要通道之一。     

Skarn development from limestone adjacent to the Glenrock Granodiorite,Marulan Batholith,New South Wales,Australia

Skarns are developed over two temperature‐time intervals in calcite limestone adjacent to the southern extension of the Glenrock Granodiorite, a pluton of the Marulan Batholith, Southern Highlands, New South Wales. The initial volumetrically‐dominant prograde phase of skarn formation produced a suite comprising bimetasomatic skarn, including pyroxene endoskarn, potassic endoskarn and wollastonite‐bearing exoskarn, together with mineralogically‐zoned vein skarn, massive garnet‐pyroxene skarn and calcite‐vesuvianite skarn. Retrograde replacement is manifested by the development of hydrous silicate minerals, carbonate and cross‐cutting sulphide veinlets.

A genetic model is proposed to account for the development of bimetasomatic skarn in the deposit. Exoskarn geochemistry indicates addition of many components relative to an essentially pure limestone precursor, including Si, Al, Fe, Zr, Zn, S, Mn and Cu, negligible transfer of K, Na and Rb and loss of CO₂. Strontium and Ca loss from the parent limestone is indicated by mass balance calculations at constant volume.

Garnet and pyroxene compositions in the massive garnet‐pyroxene skarn range from Gr₃₀ to Gr₆₆ and Hd₆₁ to Hd₈₇, respectively. Compositions from Gr₆₇ to Gr₉₅ are typical of the vein skarn garnets. Chemical zonation patterns in garnet, pyroxene and vesuvianite are generally characterized by rim Fe depletion relative to cores of grains.

Prograde skarn probably formed at T = 500–580°C; P < 220 MPa. The massive garnet‐pyroxene skarn evolved under conditions of log fO₂ = ‐18.9 to ‐22.9 (assuming a constant fCO₂ of 20 MPa) within the fS₂ stability field of pyrrhotite. Retrograde skarn formed at T < 400°C, possibly under conditions of X_H2O < 0.01.

Vesuvianite plus wollastonite assemblages, present in exoskarn, probably attest to very water‐rich conditions. The marble wall rocks, isolated from the source of skarn‐forming fluids, probably evolved under conditions of minimum X_co2 >0.2. Low temperature CO₂ ‐rich fluid inclusions and prehnite (stable at X_co2 <0.01), present in the marble and skarn, respectively, suggest that substantial differences in X_co2: X_H2O were maintained during cooling.

Observed mineralogical and chemical zonation within the skarn reflects the complex interaction of T, P, fO₂, Xco₂ and other chemical variables such as a_SiO2 and a_Al2O3 throughout the skarn system. No single variable can account adequately for the mineralogical diversity observed in the skarn deposit.     

莒县土地整治和占补平衡工作的探讨

通过对低效利用、不合理利用、未利用土地进行田、水、路、林、村整治挖潜,切实提高土地利用效率;通过农村建设用地挖潜利用规划,出台了专门的规范性文件,建立了专门的土地整治资金筹措机制;充分尊重群众意见,对安置区新房建设实行因地制宜、统一配套等手段,使土地综合整治在基层扎扎实实开展起来,有效地服务了新农村建设,增加了建设用地指标,保障地方经济社会发展,保护了有限的耕地资源,统筹了城乡土地配置,确保了全县耕地总量动态平衡。     

巨厚松散层裸孔施工技术措施

针对巨厚松散层在钻孔施工中易出现钻孔孔壁坍塌、掉块、缩径,造成埋钻、粘钻、卡钻,找不到原孔而形成岔孔等钻孔事故,简述了在巨厚松散层钻孔裸孔安全施工的要点和注意事项。     

陕北三叠纪煤田蟠龙至高家屯勘查区5号煤层顶板工程地质特征

研究区5号煤层位于三叠系瓦窑堡组第四段上部,煤层直接顶以泥岩、砂质泥岩为主,老顶以粉砂岩、泥岩和细粒砂岩为主,从岩性分布来看,总体呈现出向上变粗的沉积层序,对应的顶板类型为下软上硬型.进一步分析其岩石力学性质、测井曲线与岩体质量指标,参考岩层厚度、层理及裂隙等,综合分析确定该区5号煤层顶板属基本稳定型.该研究为煤矿的安全生产提供了技术支持.     

化探中痕量银的测定

对电感耦合等离子体质谱法与一米光栅发射光谱法在化探样品中的痕量银测定进行对比,实验表明,两种方法都具有高精密度和准确度,检出限也符合区域化探的要求,但是在大批量的化探测定及多元素同时测定方面,质谱法操作简单、快速、准确、成本低,优于一米光栅发射光谱法,更适合应用于批量化探样品中银的测定。