Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen

In mine soil, quantification of soil organic carbon (OC) derived recently from biomass decomposition is complicated by the presence of fossil (geogenic) C derived from coal, oil shale, or similar material in the overburden. The only reliable method for such measurement is ¹⁴C analysis (i.e. radiocarbon dating) using instrumentation such as accelerator mass spectrometry, which is too expensive for routine laboratory analysis. We tested two previously used and two new methods for recent C quantification and compared them with ¹⁴C AMS radiocarbon dating as a reference using a set of soil samples (n = 14) from Sokolov, Czech Republic: (i) ¹³C isotope ratio composition, (ii) cross polarization magic angle spinning ¹³C nuclear magnetic resonance (CPMAS ¹³C NMR) spectroscopy, (iii) near infrared spectroscopy (NIRS) coupled with partial least squares regression and (iv) Rock–Eval pyrolysis. Conventional methods for OC determination (dry combustion, wet dichromate oxidation, loss-on-ignition) were also compared to quantify any bias connected with their use. All the methods provided acceptable recent carbon estimates in the presence of mostly aliphatic fossil C from kerogen. However, the most accurate predictions were obtained with two approaches using Rock–Eval pyrolysis parameters as predictors, namely (i) S₂ curve components and (ii) oxygen index (OI). The S₂ curve approach is based on the lower thermal stability of recent vs. fossil organic matter. The OI approach corresponded well with ¹³C NMR spectra, which showed that samples rich in recent C were richer in carboxyl C and O-alkyl C. These two methods showed the greatest potential as routine methods for recent C quantification.     

南秦岭主要类型热水沉积岩的REE地球化学

南秦岭泥盆纪沉积柱中产有多种类型海底热水沉积岩．它们的ΣＲＥＥ偏低（平均６３．０９×１０－６），ＲＥＥ配分曲线平缓右倾，Ｌａ／Ｙｂ＝２～８，Ｃｅ亏损，总体上与海水相似。产于Ｓｅｄｅｘ含矿层中的热水沉积岩具有正Ｅｕ异常，与现代海底热液及红海热液沉积物可比；而产在Ｓｅｄｅｘ含矿层以下地层中的热水沉积岩Ｅｕ亏损，与ＥＰＲ热液沉积物相似。ＲＥＥ地球化学研究和岩石学研究结果一致，支持热水沉积岩ＲＥＥ来源于海水及部分下伏沉积柱（包括基底），含矿热水沉积岩是盆地热演化到一定阶段具有一定深度和规模的循环对流体系在海底的化学沉积，而Ｓｅｄｅｘ含矿层以下地层中的热水沉积岩则是浅部热水对流循环的海底显示．成岩和变质作用对岩石的ＲＥＥ未造成影响。     

河南卢氏—西峡地区小寨组的沉积相

石界河群小寨组主要为砂、泥质碎屑沉积,按岩性可分为四个组合,下部黑云母石英片岩与变质杂砂岩组合及变质副砾岩与变质杂砂岩组合为浊流及碎屑流沉积,上部的变质砾岩与变质含砾砂岩组合及变质杂砂岩、千枚岩组合为扇三角洲沉积。综合上述沉积相组合,提出小寨组并非大洋或深海盆地,而应为靠近陆源地的断陷盆地中的碎屑沉积。     

Organic carbon and nitrogen stable isotopes in the intertidal sediments from the Yangtze Estuary, China

The natural isotopic compositions and C/N elemental ratios of sedimentary organic matter were determined in the intertidal flat of the Yangtze Estuary. The results showed that the ratios of carbon and nitrogen stable isotopes were respectively −29.8‰ to − 26.0‰ and 1.6‰–5.5‰ in the flood season (July), while they were −27.3‰ to − 25.6‰ and 1.7‰–7.8‰ in the dry season (February), respectively. The δ¹³C signatures were remarkably higher in July than in February, and gradually increased from the freshwater areas to the brackish areas. In contrast, there were relatively complex seasonal and spatial changes in stable nitrogen isotopes. It was also reflected that δ¹⁵N and C/N compositions had been obviously modified by organic matter diagenesis and biological processing, and could not be used to trace the sources of organic matter at the study area. In addition, it was considered that the mixing inputs of terrigenous and marine materials generally dominated sedimentary organic matter in the intertidal flat. The contribution of terrigenous inputs to sedimentary organic matter was roughly estimated according to the mixing balance model of stable carbon isotopes.     

Late Pleistocene sea-level oscillations (MIS 10–2) recorded in shallow marine and coastal plain sediments of the southern Wanganui Basin, New Zealand

The northern Wanganui Basin, New Zealand, is one of the key global sites for understanding marine cyclic sedimentation during the Quaternary. This paper presents the first evidence of marine cyclic sedimentation from its central-southern parts. Sedimentological, micropalaeontological and palynological analyses on a 280-m-deep borehole encountered units dating back to MIS 10. The sequence includes four marine cycles spanning MIS 9–5, which are overlain by terrestrial fluvial aggradation surfaces dating from MIS 4–2. Each marine unit represents a progressively shallowing depositional environment from the mid-shelf to coastal plain. This is overlain by a terrestrial sequence of lowstand fluvial terraces. Localized fault movements appear to have influenced the sedimentary character of the sequence during MIS 7a and 5e producing basement highs which provided protection to the shoreline. The cyclothems described in this paper now extend the already extensive, previously described record from MIS 17–10 to produce a combined eustatic record of Quaternary sea level change within the basin to MIS 5. They also provide an excellent example of the sedimentary response of a coastal basin to a progressive loss of sedimentation accommodation space.     

Stratigraphy, depositional environments and level reconstruction of the last interglacial Lake Samra in the Dead Sea basin

In this paper we describe the stratigraphy and sediments deposited in Lake Samra that occupied the Dead Sea basin between ∼ 135 and 75 ka. This information is combined with U/Th dating of primary aragonites in order to estimate a relative lake-level curve that serves as a regional paleohydrological monitor. The lake stood at an elevation of ∼ 340 m below mean sea level (MSL) during most of the last interglacial. This level is relatively higher than the average Holocene Dead Sea (∼ 400 ± 30 m below MSL). At ∼ 120 and ∼ 85 ka, Lake Samra rose to ∼ 320 m below MSL while it dropped to levels lower than ∼ 380 m below MSL at ∼ 135 and ∼ 75 ka, reflecting arid conditions in the drainage area. Lowstands are correlated with warm intervals in the Northern Hemisphere, while minor lake rises are probably related to cold episodes during MIS 5b and MIS 5d. Similar climate relationships are documented for the last glacial highstand Lake Lisan and the lowstand Holocene Dead Sea. Yet, the dominance of detrital calcites and precipitation of travertines in the Dead Sea basin during the last interglacial interval suggest intense pluvial conditions and possible contribution of southern sources of wetness to the region.     

中东地区阿普特阶Shuaiba组碳酸盐岩沉积体系特征及模式探究

中东地区主力产油层系Shuaiba组的勘探及研究逐渐以地层岩性圈闭为主,笔者通过总结Bab盆地阿普特阶Shuaiba组沉积相类型,多油田地层格架及空间展布特征的对比,为系统恢复Shuaiba组沉积演化过程及模式提供地质依据。研究表明,阿普特阶Shuaiba组共发育开阔台地、台地边缘、台缘斜坡及盆地相4种沉积相单元和6种亚相类型,各相带单元受控于四个三级层序且沿Bab盆地周缘呈带状展布。开阔台地一侧,主要沉积了第二个三级层序对应的Lower Shuaiba地层;台地边缘往Bab台内盆地区域,则以第三和第四个三级层序对应的Upper Shuaiba地层为主。Shuaiba组生物礁、滩建造集中发育在第二个三级层序的高位域阶段,滩间海、缓坡及盆地相受控于海进和低位体系域。阿普特阶Shuaiba台地边缘生物建隆、台内浅滩在空间上相互叠置并成带展布,符合弱镶边型缓坡台地沉积模式,该类型台地具备深水陆棚性质的非常宽缓的斜坡,且缓坡往盆地一侧发育一个镶边台地边缘。     

盆地沉降史研究的新方法—波动分析

波动分析方法为前苏联学者提出，认为沉积地的演化过程受不同的周期波所控制。介绍了该方法的产生过程，基本原理，工作方法和所能解决的南持问题，最后对该方法进行了评价。     

东秦岭的泥盆系及构造演化

本文简述了有关秦岭构造演化的不同解释;从沉积、古地理、古构造等方面讨论了北带泥盆系与与中、南带泥盆系的明显差异及它们的分界位置;论述了秦岭属印支带及其东延的主要证据;提出了秦岭构造演化模式。     

渤海南部油气开发区浅层工程地质特性及其与沉积相的关系

根据渤海南部两个钻孔的实际材料,用成因土质学的观点和方法研究沉积物的沉积环境同其物理,力学性质的内在联系,探讨了本区浅层工程地质特性在时空上与环境的相互关系。