Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.     

台湾海峡西部柱状沉积物粘土矿物的分析

根据台湾海峡西部10个柱102个样品的X 射线衍射等分析,鉴定了该区粘土矿物组合与含量变化,分析了其与沉积环境的关系.结果表明,该区粘土矿物组合大多数站位以伊利石含量占首位,绿泥石和高岭石次之,且含少量蒙脱石;伊利石含量随距岸、水深的增加而递增,高岭石则反之;蒙脱石含量与火山活动密切相关,绿泥石含量呈斑块状分布;775和819号站有典型的陆相层,为早玉木冰期的“台湾陆桥”或“东山陆桥”提供有力证据.     

海沧邻近海域表层沉积物中重矿物研究

对厦门海沧邻近海域表层沉积物中的重矿物(0．063～0．125mm粒级)进行了分析和研究，结果表明该粒级的重矿物共计49种，其优势和特征矿物为磁铁矿、赤铁矿、褐铁矿、绿帘石、铁铁矿、角闪石、锆石、红柱石等；重矿物的平均质量分数为9．56％；根据重矿物的分布和含量，并结合主要标志矿物的颗粒百分含量和分布特征，将该海域划分为5个矿物组合区，根据各区的矿物组合类型分析了该海域的物质来源及影响重矿物分布和组合的因素，进而探讨了九龙江河口湾和厦门西港海湾的沉积环境。     

大亚湾海域锥状斯氏藻赤潮及其与孢囊的关系

用沉积物捕捉器取样，研究了大亚湾海域２０００年６～９月孢囊（Ｃｙｓｔ）种群动态，同时 分析了浮游植物种群动态。研究期间（８～９月）该海域发生了一起大规模的锥状斯氏藻赤潮。 赤潮前一个月，锥状斯氏藻孢囊的平均日形成率为２．０５× １０５ｃｙｓｔｓ／（ｍ２·ｄ），丰度为５０．２２％， 该时期以有性生殖产生的静止期孢囊为主；在赤潮盛期的８，９月初，孢囊的平均日形成率达到 ２．０１ ×１０６ｃｙｓｔｓ／（ｍ２·ｄ），丰度为９６．９７％，此时期的孢囊多为营养细胞所形成的暂时性孢囊； 赤潮结束后，由于环境条件的恶化，暂时性孢囊的形成达到高峰，平均日形成率为１．２４×ｌ０７ ｃｙｓｔｓ／（ ｍ２·ｄ），丰度为９９.５３％。结果表明大亚湾丰富的孢囊是潜在的种源（Ｓｅｅｄ　ｂｅｄ），２０００年 的夏季、秋李持续高温（＞２５℃），台风减少及风力减弱等有利锥状斯氏藻的环境条件诱发孢 囊萌发，开始了该种类的赤潮。     

冰心中的气候环境记录与全球变化研究

冰心是高分辨地记录全球变化的主要信息载体之一。本文总结了冰心中提取古气候和古环境信息的系列记录，包括同位素、微量气体、阴阳离子、微粒、生物和有机质等。着重讨论了由这些记录提取的古气候和古环境变化方面的研究进展，并提出了今后的研究重点。     

菊花岛海区沉积物类型及矿物特征初探

本文对菊花岛海区沉积物类型，重矿物和粘土矿物组合分区及其分布特征进行了分析，同时对测区沉积物来源进行探讨。     

薛家岛湾沉积动力学特征及海港开发研究

于１９９０年秋对胶州湾内的薛家岛湾进行海洋水动力条件及积动力学特征,泥沙运动规律研究,为开发建设港口提供科学依据。结果表明,湾内深大于１ｍ的海底泥沙发生“全面移动”的时间,一年内仅有１－２ｄ,其余处于稳定状态或“表面移动”状态。湾内泥沙来源很少,预计建港后,港池和航道年平均回淤量分别小于１６ｃｍ,１０ｃｍ对于开发中小型港口十分有利。     

Nitrogen forms and decomposition of organic carbon in the southern Bohai Sea core sediments

Study on form characteristics of nitrogen in marine sediments is the primary method to research its biogeochemical cycling and nitrogen form characteristics in core sediments can reflect the process and results of early diagenesis in a certain degree. In this paper, Sequential extraction process in natural grain size was used for studying the existent forms of nitrogen in five core sediments of the southern Bohai Sea for the first time. Nitrogen was divided into two parts -transferable and fixed based on whether it could be extracted by the reagent. Distributions and early diagenesis of transferable nitrogen forms in the southern Bohai Sea were researched integratedly. Results indicate that IEF - N and OSF-N are predominant forms in transferable part in the studied core sediments. Contents of different nitrogen forms vary differently with depth, and have different diagenesis process. Decomposition constant of organic nitrogen (ON) and OC are about 15.51 × 10~(-3)a~(-1)and 4.79× 10~(-3)a~(-1) respective     

Evaluation of the Risk of Marine Slope Instability: A Pseudo-3D Approach for Application to Large Areas

This article presents a methodology developed to evaluate the instability of submarine slopes that extend over a large area. Special attention was paid to (1) the complex geometry (bathymetry) and the expanse of the slope, (2) the heterogeneity of the sediment, and (3) the distribution of the pore pressure. The safety factor was considered as a spatially varying quantity. The General Formulation (GLE, Fredlund and Krahn 1977), which fully satisfies equilibrium conditions, was used for evaluating the stability of the marine slope. The submarine slope failure, which occurred on 16 October 1979 during the construction of the new Nice airport, was studied in order to test the developed model. Geotechnical parameters were taken from experimental tests carried out by IFREMER on 19 cores extracted at different depths (from 27 m to 1300 m) (Cochonat, Bourillet, and Savoye, 1993; Mulder et al., 1994). Many scenarios were proposed in order to explain the cause of the Nice slope failure (Habib, 1994). In this article, two of those scenarios were tested. Simulation results are presented and discussed.     

南海东部海域柱样沉积物浊流沉积探讨

利用1998年南海东部陆坡69号柱样、深海盆149号柱样、南部岛礁323号柱样沉积物的粒度、化学、古生物、矿物等鉴定分析测试资料,分析了南海东部海域发生浊流沉积的地质背景、产生浊流沉积的条件和诱发因素,进而发现南海东部浊流沉积发育,在南北陆坡及中部深海盆地均有浊流沉积层。从其出现层位看,为氧同位素2—4期,即晚更新世中晚期。从浊流沉积出现层数分析,具有自北向南浊流发生频次减弱的趋势。从浊流沉积物成分看,南海东部浊流沉积物具有多样性,北部陆坡以陆源为主,中部深海盆以陆源及火山源为主,南部岛礁以生物源为主。