渤海湾及其附近海域沉积物中Cu,Pb,Zn,Cd环境背景值的研究

根据渤海湾及其毗邻河口区10柱岩芯样细颗粒（＜0．063mm）（GF 1983－1985年采集）中重金属含量特点，结合^216Pb年代学编年资料，用未受人类影响沉积层中元素含量，藉统计学方法获得渤海湾岩芯样中Cu，Pb，Zn，Cd的分布类型，并根据各区重金属的含量水平，用t检验法获得了渤海湾Cu，Pb，Zn，Cd的环境背景值。     

闽江口段溶解态镉,铅和铜的收支平衡

利用潮输沙量的计算方法,估算了闽江口入海口内3个断面所包围区域溶解态镉、铅和铜的收支平衡,从而研究了这些重金属的河口行为。     

Microbial Biomass and Organic Nutrients in the Deep-Sea Sediments of the Central Indian Ocean Basin

In order to assess the impact of deep-sea mining on the in situ benthic life, we measured the microbial standing stock and concentration of organic nutrients in the deep-sea sediments of the Central Indian Ocean Basin in the Indian pioneer area. Sediments were collected using box core and grab samples during September 1996. The total bacterial numbers ranged from 10 10 -10 11 cells per g -1 dry weight sediment. There was a marginal decrease in the number of bacteria from surface to 30 cm depth, though the subsurface section registered a higher number than did the surface. The highest numbers were encountered at depths of 4-8 cm. The retrievable number of bacteria were two orders less in comparison with the direct total counts of bacteria. An almost homogeneous distribution of bacteria, total organic carbon, living biomass, and lipids throughout the depth of cores indicates active microbial and benthic processes in the deep sea sediments. On the other hand, a uniform distribution of total counts of bacteria, carbohydrates, and total organic carbon in all the cores indicates their stable nature and suggests that they can serve as useful parameters for long-term monitoring of the area after the benthic disturbance. Further studies on temporal variability in this region would not only verify the observed norms of distribution of these variables but would also help to understand restabilization processes after the simulated benthic disturbance.     

沉积物镁铝含量比及其古气候意义

沉积物的镁铝含量比——m 值(m=100×MgO/Al_2O_3)与沉积水介质的盐度、pH 水温关系密切。当水温处在冰点以下时,沉积物的m 值随水温降低而增大。当水温处在冰点以上时,水介质的盐度、pH 和水温的增加,都有利于m 值增大。由于气候条件能直接或间接地影响沉积水介质的特征,因此,沉积物的m 值对古气候的变化具有一定的判别功能。通过对中国元古宙以来沉积物m 值的分析,发现古气候的热冷变化有1200Ma 的周期,其中还有次一级的热冷气候波动。第四纪的气候是处在热气候期后期的一个冷的气候波动阶段。     

Freshening of the Intermediate Waters in the Northern South China Sea over the PastSix Decades

The properties of salinity in the South China Sea (SCS), a significant marginal sea connecting the Pacific andIndian Oceans, are greatly influenced by the transport of fresh water flux between the two oceans. However, the long-termchanges in the intermediate water in the SCS have not been thoroughly studied due to limited data, particularly in relationto its thermodynamic variations. This study utilized reanalysis data products to identify a 60-year trend of freshening in theintermediate waters of the northern South China Sea (NSCS), accompanied by an expansion of low-salinity water. Thestudy also constructed salinity budget terms, including advection and entrainment processes, and conducted an analysis ofthe salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of theintermediate water in the NSCS. The analysis revealed that the freshening in the northwest Pacific Ocean and theintensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes inthe NSCS. Additionally, a weakened trend in the intensity of vertical entrainment also contributes to the freshening in theNSCS. This study offers new insights into the understanding of regional deep sea changes in response to variations in boththermodynamics and oceanic dynamic processes.     

Water balance in the playa-lakes of an arid environment,Monegros, NE Spain

The playa-lakes of the Monegros desert in north-east Spain are saline wetlands in an arid environment, a rare phenomenon in Europe. These extremely valuable habitats are threatened by changes associated with agricultural expansion and incorporation of new irrigated areas. An understanding of the present hydrologic regime will enable changes to be identified, particularly those brought about by flooding and pollution caused by irrigation surplus. This study sets out to show the results of applying a daily water balance in three selected playa-lakes. The balance was in two parts and consisted of: (1) the average balance for all the endorheic basin using the BALAN_11 program, and (2) the water balance in some playa-lakes, applying discharge flows obtained from the previous balance. The resulting volumes of water were converted to water depths and contrasted with reference volumes taken from field and Landsat images. The model was calibrated by applying various hypotheses of function which enabled the results to be adjusted. The proposed balance is an acceptable reproduction of field water measurements during this period, and underlines the consistency of the conceptual model. The methodology used is appropriate for understanding the playa-lakes function and for monitoring them for conservation purposes.     

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

     

Evaluation of distributed recharge in an upland semi-arid karst system: the West Bank Mountain Aquifer,Middle East

Assessment of recharge in a structurally complex upland karst limestone aquifer situated in a semi-arid environment is difficult. Resort to surrogate indicators such as measurement of spring outflow and borehole discharge, is a common alternative, and attempts to apply conventional soil moisture deficit analysis may not adequately account for the intermittent spate conditions that arise in such environments. A modelling approach has been made using the West Bank Mountain Aquifer system in the Middle East as a trial. The model uses object oriented software which allows various objects to be switched on and off. Each of the main recharge processes identified in the West Bank is incorporated. The model allows either conventional soil moisture deficit analysis calculations or wetting threshold calculations to be made as appropriate, and accommodates both direct recharge and secondary recharge. Daily time steps enable recharge and runoff routing to be calculated for each node. Model runs have enabled a series of simulations for each of the three aquifer basins in the West Bank and for the whole of the West Bank. These provide recharge estimates comparable to those prepared by earlier workers by conventional means. The model is adaptable and has been successfully used in other environments.     

Groundwater resources in the Jabal Al Hass region,northwest Syria: an assessment of past use and future potential

In many cases, the development of groundwater resources to boost agricultural production in dry areas has led to a continuous decline in groundwater levels; this has called into question the sustainability of such exploitation. In developing countries, limited budgets and scarce hydrological data often do not allow groundwater resources to be assessed through groundwater modeling. A case study is presented of a low-cost water-balance approach to groundwater resource assessments in a 1,550 km² semi-arid region in northwestern Syria. The past development of irrigated agriculture and its effect on the groundwater system were studied by analysis of Landsat images and long-term groundwater level changes, respectively. All components of the groundwater balance were determined. Groundwater recharge was estimated using the chloride mass balance method. Over the past three decades, groundwater levels have declined, on average, 23 m, coinciding with a two-fold increase in the groundwater-irrigated area. Groundwater resources are currently depleted by a value that lies between 9.5×10⁶ and 118×10⁶ m³ year^?1, which is larger than can be compensated for by a future decrease in natural discharge or changes in boundary conditions. However, groundwater resources are likely to be sufficient to supply domestic and livestock needs in the area.     

SOME NEW UNDERSTANDINGS OF LAND-SURFACE PROCESSES IN ARID AREA FROM THE HEIFE*

The survey for the HEIFE(Atmosphere-Land Surface Processes Experiment at Heihe River Basin,Western China) is given in the paper.The following basic subjects for land-surface processes in arid areas are studied:(1) the general characteristics of the energy budget on ground surface in arid areas;(2) the parameterization of the land surface processes;(3) the interaction between oasis and its desert circumstances,a special phenomenon in arid areas.The analysis shows that the sensible heat flux in the surface energy budget is in the majority,and the latent heat flux may be neglected.The influence of atmospheric stratification stability on the turbulent transfer of energy and substance must be considered in parameterization of land surface processes in arid areas.The "cold island effect" phenomenon in oasis and the "humidity inversion" phenomenon in desert near oasis are the result of the interaction between them.The results would improve the understanding of land surface processes in arid areas.