Characterization of chromophoric dissolved organic matter (CDOM) in the Baltic Sea by excitation emission matrix fluorescence spectroscopy

Chromophoric dissolved organic matter (CDOM) is the major light absorber in the Baltic Sea. In this study, excitation emission matrix (EEM) fluorescence spectra and UV–visible absorption spectra of CDOM are reported as a function of salinity. Samples from different locations and over different seasons were collected during four cruises in 2002 and 2003 in the Baltic Sea in both Pomeranian Bay and the Gulf of Gdansk. Absorption by CDOM decreased with increased distance from the riverine source and reached a relatively stable absorption background in the open sea. Regression analysis showed that fluorescence intensity was linearly related to absorption by CDOM at 375 nm and a_CDOM(375) absorption coefficients were inversely related to salinity. Analysis of CDOM-EEM spectra indicated that a change in composition of CDOM occurred along the salinity gradient in the Baltic Sea. Analysis of percent contribution of respective fluorophore groups to the total intensity of EEM spectra indicated that the fluorescence peaks associated with terrestrial humic components of the CDOM and total integrated fluorescence decreased with decreasing CDOM absorption. In contrast, the protein-like fraction of CDOM decreased to a lesser degree than the others. Analysis of the percent contribution of fluorescence peak intensities to the total fluorescence along the salinity gradient showed that the contribution of protein-like fluorophores increased from 2.6% to 5.1% in the high-salinity region of the transect. Fluorescence and absorption changes observed in the Baltic Sea were similar to those observed in similar transects that have been sampled elsewhere, e.g. in European estuaries, Gulf of Mexico, Mid-Atlantic Bight and the Cape Fear River plume in the South Atlantic Bight, although the changes in the Baltic Sea occurred over a much smaller salinity gradient.     

Circulation on the north central Chukchi Sea shelf

Mooring and shipboard data collected between 1992 and 1995 delineate the circulation over the north central Chukchi shelf. Previous studies indicated that Pacific waters crossed the Chukchi shelf through Herald Valley (in the west) and Barrow Canyon (in the east). We find a third branch (through the Central Channel) onto the outer shelf. The Central Channel transport varies seasonally in phase with Bering Strait transport, and is 0.2 Sv on average, although some of this might include water entrained from the outflow through Herald Valley. A portion of the Central Channel outflow moves eastward and converges with the Alaskan Coastal Current at the head of Barrow Canyon. The remainder appears to continue northeastward over the central outer shelf toward the shelfbreak, joined by outflow from Herald Valley. The mean flow opposes the prevailing winds and is primarily forced by the sea-level slope between the Pacific and Arctic oceans. Current variations are mainly wind forced, but baroclinic forcing, associated with upstream dense-water formation in coastal polynyas might occasionally be important.Winter water-mass modification depends crucially on the fall and winter winds, which control seasonal ice development. An extensive fall ice cover delays cooling, limits new ice formation, and results in little salinization. In such years, Bering shelf waters cross the Chukchi shelf with little modification. In contrast, extensive open water in fall leads to early and rapid cooling, and if accompanied by vigorous ice production within coastal polynyas, results in the production of high-salinity (>33) shelf waters. Such interannual variability likely affects slope processes and the transport of Pacific waters into the Arctic Ocean interior.     

渤海的平均余环流

利用72个渤海石油平台、站点测流资料,阐明了渤海的平均余环流特征,并用已有的数值计算结果阐明了其形成机制。观测表明在黄河三角洲近海存在一支北-东北向的流动,可抵达秦皇岛附近水域,数值计算表明该支流动主要是潮生的;在辽东湾北部存在一顺时针向的涡旋运动,在冬半年该涡旋是风生的;在渤海湾北部存在潮生的逆时针向的余环流。     

Development of fouling communities on vertical structures in the Baltic Sea

The pillars of the bridge connecting the Island of Öland with the Swedish mainland were rebuilt between 1990 and 2000. The renovation produced pristine vertical concrete substrates, which became submerged in known years and seasons. The fouling communities on the pillars were examined in 2001 to determine whether the community structure could be explained in terms of either orderly successional development or of seasonal variation in the settlement of benthic organisms. As well, the communities on the pillars were compared to communities on the vertical surfaces of boulders in the area. The results indicated that an annual species composition is the final stage in the succession on the observed, vertical constructions. The few perennial species add to the variation between pillars as they increase in biomass (Polysiphonia fucoides) or become out-competed (Balanus improvisus). Also, observed seasonal differences in the biomass of these perennial species indicated that the time of year free space becomes available might be an important determinant of the future structure of the community. Comparison between the pillar and boulder communities showed that the artificial structures were not surrogates for the natural hard substrate: pillar communities differed in that they lacked most perennial algal species and had a high biomass of B. improvisus.     

东、黄海典型海区分粒级浮游植物叶绿素a的周日波动及影响因子

本文分析了东、黄海典型海区3个测站在2000~2003年间4个航次的叶绿素a周日变动特征,结果表明由于地理环境、水文特征以及季节差异,各海区叶绿素a表现出各自不同的变动特点.在东海陆架区,日变化上表层各粒级主要以半日周期为主,受黑潮入侵程度不同而略有变化;长江口由于受到潮汐的影响,各粒级的日变化同潮汐的涨落相对应,主要为半日周期;黄海中部海区叶绿素a尤其是NANO级浮游植物在周日变化上以全日周期为主,受黄海冷水团强弱不同而不同.本文进一步应用渐近回归初步分析了多种环境因子对叶绿素a周日变化的影响.     

溶解无机态营养盐在渤海沉积物-海水界面交换通量研究

了解无机态营养严在渤海沉积物-海水界面交换速率、通量基控制因素,于2002-08-06~08-24,应用船基沉积物培养方法,现场测定了硅酸盐(SiO3-Si)、磷酸盐(PO4-P)和溶解无机氮(DIN)在沉积物-海水界面上的交换速率(νN)和交换通量(FN)。结果显示,νSiO3-Si变化范围为2 220~4 317μmol.m-2.d-1,平均为3 466μmol.m-2.d-1,νPO4-P为0.4~77μmol.m-2.d-1,平均为39μmol.m-2.d-1,νDIN为667~2 167μmol.m-2.d-1,平均为1 308μmol.m-2.d-1,其中NH4-N和NO3-N的贡献分别为48%和47%左右。进一步分析表明,νSiO3-Si主要由溶解和扩散2个过程控制,前者决定于沉积物黏土矿物含量和含水率,后者决定于营养盐浓度和温度。νPO4-P主要由在以黏土为主的细颗粒和氢氧化铁上的吸附-解吸和扩散过程控制,前者分别决定于沉积物粒度和上覆水中DO浓度,而后者决定于间隙水与上覆水之间的浓度差。结果表明,FSiO3为2.59×1013mmol,FPO4为2.95×1011mmol,FDIN/SE为8.62×1012mmol。这样,为维持夏季渤海初级生产力,沉积物交换过程可提供大约65%的SiO3-Si、12%的PO4-P和22%的DIN,远远高于以河流径流为主的陆源排放。     

秋季巴伦支海海温异常对冬季我国渤海冰情的可能影响

本文利用美国NCEP/NCAR逐月的再分析资料、HadISST海温、中国160台站气温和反映渤海冰情轻重的渤海冰情等级资料,研究了前秋巴伦支海海温异常对后期渤海冰情和东亚冬季风的影响,并对相关的物理过程进行分析。结果表明,前秋巴伦支海关键区海温与该区域海冰密集度呈显著的负相关,且具有较好的持续性,通过调节随后冬季向大气释放的热通量,引起后期环流变化。偏高(偏低)年冬季亚洲纬向环流偏弱(偏强),东亚大槽加深(减弱),东亚冬季风加强(减弱),我国东北、华北及西北地区地区显著偏冷(偏暖),这与冬季渤海海冰异常的强度和范围都偏大(小)及与之相联系的环流异常相一致。进一步的分析揭示了联系上游关键区海温变化与后期东亚地区气候异常的重要途径,前秋巴伦支海海温偏高会导致200 hPa高度场形成一个自西向东的波列形式,在东亚局地Hadley环流异常的作用下,加强了我国北方地区地表的北风异常。因此,前秋巴伦支海海温异常可以作为冬季渤海冰情的预报因子。     

利用被动示踪物模拟对黑潮入侵南海的数值研究

由于缺少观测数据和对黑潮水准确定义,很难识别出从太平洋入侵到南海的黑潮水团。本文基于一个经过观测验证的三维模式MITgcm,利用被动示踪物标记黑潮水,研究了入侵南海的黑潮水的时空变化。研究表明,在冬季,黑潮水入侵的范围最广,几乎占据了18°N-23°N和114°E-121°E的区域;并有一个分支进入台湾海峡;黑潮入侵的范围随深度增加逐渐减小。在夏季,黑潮水被限制在118°E以东,且没有分支进入台湾海峡;入侵的范围从海面到约205米是增大的,之后随深度增加逐渐减小。通过分析从2003年到2012年黑潮入侵的年际变化,与厄尔尼诺年和正常年相比,冬季黑潮入侵后向台湾海峡的分支在拉尼娜年是最弱的,这可能与中国大陆东南方向的风应力旋度有关。通过吕宋海峡的黑潮入侵通量（KIT）是西向的,其年平均值约为-3.86×10⁶ m³/s,大于吕宋海峡通量（LST,约-3.15×10⁶ m³/s）。250米以上的KIT约占了全深度通量的60-80%。此外,从2003年到2012年KIT与Niño 3.4指数的相关系数到达0.41,小于LST与Niño 3.4指数的相关系数0.78。     

南海周边相对海平面变化特征及2004年苏门答腊地震影响分析

利用南海周边1989-2014年的潮汐资料和GPS长期观测资料,分析了南海周边相对海平面变化特征,以及2004年苏门答腊地震对该区域相对海平面变化的影响。研究结果表明,南海周边的相对海平面变化以上升为主,平均上升速率（4.53±0.20） mm/a,高于全球平均速率,且2004年后上升趋势加剧;南海周边相对海平面呈现6类较典型的变化特征,并存在与板块构造相对应的分区聚集现象,形成了中国东南和越南沿海、马来半岛、加里曼丹岛北部、菲律宾群岛等4个变化特征区。受2004年苏门答腊大地震的影响,马来半岛、南沙和西沙海域的地壳形变由上升趋势转为下沉,加剧了相对海平面的上升;中国东南沿海和菲律宾群岛受地震影响较小;越南沿海和加里曼丹岛北部区域的地震影响还有待进一步研究。