碎屑金红石:沉积物源的一种指针

近年来,碎屑金红石的研究已成为沉积物源区分析的一个新前沿。金红石的地球化学组成,尤其是Cr,Nb,Zr等微量元素的含量,对其母岩的形成条件和所经历的地质过程都具有重要的指示意义,同时,碎屑金红石在沉积、成岩过程中表现出极高的稳定性,因而是物源分析的理想指针矿物。首先介绍金红石的矿物学和地球化学基本性质,分析不同来源的金红石典型特征,重点阐述碎屑金红石在物源分析中运用的5个方面:①金红石重矿物比值;②金红石矿物化学成分Cr-Nb判别图解;③金红石Zr含量温度计;④金红石的U-Pb和(U-Th)/He定年;⑤金红石Lu-Hf同位素。综合上述5个方面的物源分析研究,可以获取金红石的母岩类型、形成温度及后期所经历的热演化史等信息。碎屑金红石的物源研究处于起步和探索阶段,仍存在一些亟需解决的问题。     

评花岗岩的哈克图解

哈克图解是研究岩浆岩地球化学必用的图件,许多结论就是根据哈克图解做出的。哈克图解只是一个逻辑推理的工具,它所推出的结论是否正确,不是由图解本身决定的,而是由实践决定的。岩浆演化的理论是对的,岩浆演化的理论是从研究层状侵入体得来的,它仅适用于玄武质岩浆,而不适用于花岗质岩浆。实践是检验真理的唯一标准,由哈克图解得出的结论没有经过实践的检验是不能成为真理的,这是最基本、最简单的道理。     

基于Excel的Q=f（S）及q=f（S）曲线判别

鉴于传统的手工方法或CAD绘制抽水试验过程中Q=f（S）及q=f（S）曲线中出现的效率低、精度不高的问题,利用Excel的计算、图表功能．以内蒙古鄂尔多斯某井田203孔8煤至17煤抽水试验资料为例,详细阐述了图表法和数值法绘制Q=f（S）及q=f（S）曲线的具体步骤及判别啦线是否正常的方法,为野外水文地质技术人员提供了一个很好的参考范本。     

Transmission and visualization of large geographical maps

Transmission and visualization of large geographical maps have become a challenging research issue in GIS applications. This paper presents an efficient and robust way to simplify large geographical maps using frame buffers and Voronoi diagrams. The topological relationships are kept during the simplification by removing the Voronoi diagram’s self-overlapped regions. With the simplified vector maps, we establish different levels of detail (LOD) models of these maps. Then we introduce a client/server architecture which integrates our out-of-core algorithm, progressive transmission and rendering scheme based on computer graphics hardware. The architecture allows the viewers to view different regions interactively at different LODs on the network. Experimental results show that our proposed scheme provides an effective way for powerful transmission and manipulation of large maps.     

增/删点后的Voronoi图构造法研究

论述了在原Voronoi图的基础上增加点和删去点后生成新Voronoi图的算法.在增点过程中,针对新增加点后不满足Delaunay三角网特性的情况,利用最大最小角规则进行局部优化,根据优化后的三角网生成新Voronoi图;在删点过程中,针对删点的不同位置情况,修改相应Voronoi域,生成新Voronoi图.     

基于Voronoi的海洋底质区域划界方法研究

在对Voronoi特性进行分析的基础上,运用Delaunay规则实现了海洋底质数据点的三角网化,从而间接生成了Voronoi图,再经过邻近区域的合并处理得到理想的底质划界区域。     

Pyrite–anhydrite–magnetite–pyroxene-type deposits and coexisting hydrothermal fluids in Mesozoic volcanic basins, Yangtze River Valley, China

Anhydrite–pyrite–magnetite–pyroxene–type deposits occur in the Mesozoic volcanic areas of the Middle–Lower Yangtze Valley in China. These deposits are hosted in alkaline basaltic rocks, and are generally accompanied by melanocratic and leucocratic alteration zones, both of which are characterized by a distinct vertical zonation pattern. Investigation of these zones indicates that the chemical compositions of solid solutions and polymorphs of various minerals vary spatially in the alteration profile, upwards from the lowest level, and outwards from the center.Here we report a case study on the Luohe deposit. In the melanocratic-alteration zone, the composition of magnetite (including trace elements Ti, V, Mg, Mn), pyroxene (Mg, Fe²⁺, Fe³⁺, Al₂O₃), plagioclase (An_xAb_{1 − x}), pyrite (Co, Ni) and apatite (F, CeO₂ + Y₂O₃ + La₂O₃) changes with depth. The isotherms of hydrothermal fluids determined from fluid inclusion data, including homogenization temperature and salinity, also vary with depth.Activity diagrams were constructed from mineral and isotherm analysis to estimate the chemical constraints on the alteration-mineral assemblages and the coexisting hydrothermal solutions for the Na₂O–K₂O–CaO–MgO–FeO–Fe₂O₃–A1₂O₃–SiO₂–H₂SO₄–H₂S–HCI–H₂O system at 350 to 600 °C and 500 bars (50 MPa), assuming that the major alteration mineral assemblages along the profile reflect the nature of the coexisting hydrothermal solutions. The activity diagrams adopted the major minerals as buffers to fix the activities of the aqueous species in the system, simulating the physicochemical conditions of the magnetite–anhydrite–pyroxene equilibrium and of solid solutions of diopside–hedenbergite, grossular–andradite and anorthite–albite found in the profile.This study provides an approach to modeling the chemical constraints of coexisting fluids in ore-alteration zones based on field observations.     

库区陡峻土质岸坡路基塌岸预测

对山区顺直陡峻岸坡路基塌岸的预测,与普通图解法比较,采用考虑土体内聚力的图解法可有效避免解算难以收敛的问题,更为符合塌岸的真实形态。通过预测实例的分析发现：天然休止角的提高可大幅减小塌岸范围;水下磨蚀角的提高则可有效减小塌岸深度;合理调节运行水位变幅,对控制塌岸范围和深度较为理想;而通过小范围抬高公路线位来控制塌岸的效果并不明显。对塌岸影响因素的深入分析,为塌岸段路基的治理提供了合理的思路。     

The chemical changes of DOM from black waters to coastal marine waters by HPLC combined with ultrahigh resolution mass spectrometry

How dissolved organic matter (DOM) undergoes chemical changes during its transit from river to ocean remains a challenge due to its complex structure. In this study, DOM along a river transect from black waters to marine waters is characterized using an offline combination of reversed-phase high performance liquid chromatography (RP-HPLC) coupled to electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS), as well as tandem ESI-FTICR-MS. In addition, a water extract from degraded wood that mainly consists of lignins is used for comparison to the DOM from this transect. The HPLC chromatograms of all DOM samples and the wood extract show two major well-separated components; one is hydrophilic and the other is hydrophobic, based on their elution order from the C₁₈ column. From the FTICR-MS analysis of the HPLC fractions, the hydrophilic components mainly contain low molecular weight compounds (less than 400 Da), while the hydrophobic fractions contain the vast majority of compounds of the bulk C₁₈ extracted DOM. The wood extract and the DOM samples from the transect of black waters to coastal marine waters show strikingly similar HPLC chromatograms, and the FTICR-MS analysis further indicates that a large fraction of molecular formulas from these samples are the same, existing as lignin-like compounds. Tandem mass spectrometry experiments show that several representative molecules from the lignin-like compounds have similar functional group losses and fragmentation patterns, consistent with modified lignin structural entities in the wood extract and these DOM samples. Taken together, these data suggest that lignin-derived compounds may survive the transit from the river to the coastal ocean and can accumulate there because of their refractory nature.     

内蒙古浩尧尔忽洞高钾钙碱性花岗岩岩石成因及构造意义

浩尧尔忽洞金矿为低品位超大型中低温热液型金矿,矿区内华力西期花岗岩发育。SiO2含量为71．5％～73．07％,Na2O／K2O值为0．59～0．67,平均值为0．64,属于高钾钙碱性系列。哈克图解上各元素含量随SiO2变化成线性规律明显,具I型花岗岩特征。Mg^#为39～49,其平均值为43,与下地壳麻粒岩的平均值（45．36）相近。∑REE值变化范围为72．64×10^-6～132．6×10^-6总体上稀土含量较低。（La／Yb）Ⅳ值为12．99～34．13,显示轻重稀土有较大的分馏。在稀土元素蛛网图上表现为右倾。Ba／Th值为133．93～178．93,认为板片俯冲流体影响较小。OEu含量为0．52～0．96,平均值为0．75,具有中等到低的Eu亏损。根据其地球化学特征,认为该岩体为后碰撞期形成的高钾钙碱性I型花岗岩。