苯和甲苯在盐水溶液中活度系数及其盐效应的研究

采用紫外分光光度法测定了24.0℃时苯和甲苯在CH3COONa,(NH4)2SO4,MgSO4,Na2SO4和Na2CO3水溶液中的活度系数(f),它们的lgf-Cs关系符合Setschenow盐效应公式,计算了苯和甲苯在上述5种盐水溶液中的盐析系数。     

Weathering characteristics of arctic islands in northern Norway

The arctic islands of the Lofoten-Vesterålen archipelago in northern Norway have a wide distribution of weathered land surfaces commonly located above 250 m with several apparent similarities. In order to investigate the characteristics of (deep) weathering in this region, northern Langøya and Hadseløya were chosen for in-depth analyses. Eight weathering profiles were excavated from various surfaces, and the stratigraphies were logged in detail. Material was collected throughout the weathering horizons, and all samples were subsequently analysed for clay mineralogy (< 63 μm fraction) and grain size distribution. The sampling strategy was complemented by samples from additional saprolites and other landforms such as moraines and rock glaciers. The XRD results indicate that the presence of secondary minerals, such as gibbsite (Al(OH)₃) and kaolinite (Al₂Si₂O₅(OH)₄), are very common throughout the profiles. Gibbsite is an extreme end product of silicate weathering and usually associated with a warmer and more humid climate, as found in Scandinavia during the Tertiary. The grain size analyses (< 63 μm) show that the finer silt fractions (< 8 μm) tend to be high in the profiles (20–40%), with significant amounts of clay (5–15%) demonstrating that the regolith itself is susceptible to frost sorting mechanisms.¹⁰Be exposure dates from in situ quartz knobs on tors and boulders of local origin suggest > 40,000 years of subaerial conditions. Considering the steady surface erosion, this figure should be viewed as an absolute minimum age estimate. Mapping of the superficial sediments and geomorphological features of the study areas has revealed several common morphological features, which indicate dominance of glacial and periglacial processes in the areas lying below the lower boundary of blockfields (c. 250 m). The weathering mantles are not a periglacial end product, but rather a relict tertiary landform that were modulated by permafrost processes as well as biological processes at later stages. The regolith cover constrain the vertical extension of warm-based Quaternary ice sheets challenging the notion of a parabolic ice mass consuming every mountain top of Lofoten and Vesterålen.     

利用钻孔超声成像的图像特征进行岩石风化程度分类

钻孔超声成像方法能精确地反映井壁的光滑情况, 进而判断岩石的风化发育程度, 确定风化层的厚度。阐述了钻孔超声成像的走时和振幅图像特征, 给出了1个在香港地区的应用实例。     

The effect of rock moisture on Schmidt hammer rebound: tests on rock samples from Marion Island and South Africa

In an assessment of the influence of internal rock moisture content on Schmidt hammer readings, rebound (R) values are found to decrease with increasing moisture content. For samples of basalt, sandstone and dolerite the maximum decrease in R‐values is found between oven dry values and saturated rock rebound values, the magnitude of which varies from 2 to 10 points on the R‐scale. A quartzite block has the greatest decline of 6 points at 60 per cent saturation. For certain rock types under differing site‐to‐site field moisture conditions the moisture effect can be a significant factor in the interpretation of the relative state of weathering from rebound values. Copyright © 2002 John Wiley & Sons, Ltd.     

湘桂黔滇藏红色岩溶风化壳发育模式

基于对湘，桂、黔，滇，藏等地岩溶区红色风化壳的野外和室内研究，从表生地貌学，粘土矿物学和地球化学角度分析红色石灰土性质与地貌演化的关系，提出红色岩溶风化壳发育的二阶段模式；1）地貌夷平-风化物质积累阶段，在地貌演化过程中溶蚀残余物质不断积累，最后在夷平面上形成厚层连续的泥质风化壳，夷平面的地貌水文条件有利于粘粒的形成和保存，但限制了富铝化作用的有效进行，造就了岩溶风化壳粘粒含量高，富铝化程度低的特点，这与研究区23个红色岩溶风化壳剖面化学，粒度特征和粘土矿物组合特点一致。2）地貌切割-风化壳淋溶阶段，原始夷平面上的风化壳大多呈灰色，只有在构造隆升和地表微切割导致地下水位降低，淋溶条件开始改善的情况下，风化壳才有可能枞根本上转为红色。     

灌淤土壤可溶性盐分空间变异性与棉花生长关系研究

运用地统计学方法，在灌淤土壤上进行了棉田土壤可溶性盐分的空间变异规律与棉花生长关系系统研究。传统统计学分析表明土壤盐分测试数据基本符合正态分布；在一定取样间距下，土壤可溶性盐分的田间合理取样数目为27。半方差分析显示：土壤可溶性盐分具中等的水平变异性，但随着聚样深度的增加未表现出明显的垂直变异特性；随着棉花的生长发育，土壤可溶性盐分呈现出逐渐减弱的时间变异规律，采用直线或曲线拟合方程估计了可溶性盐分的半方差图及其参数，并绘制了其相应的等值线图。土壤可溶性盐分与棉花产量之间的相关分析表明：可溶性盐分含量与棉花产量之间呈显著负相关关系，且花铃期的相关性较播前显著。研究结果为提高田间试验有效性以及盐渍化土壤改良提供了科学依据与基础资料。     

模拟酸雨对福建四种山地土壤的淋溶与风化作用

在不同pH值 (2 .0、3.5、5 .0、6 .0及蒸馏水 )的模拟酸雨作用下 ,对福建四种类型山地土壤进行了为期 12 0d的淋溶试验。结果表明 ,盐基离子的淋溶量随模拟酸雨pH值的降低而增加 ,尤其当pH≤ 3.5时 ,增加最明显。 4种类型土壤中各离子淋失量大小均为 :Ca2 >Mg2 >K >Na ,这与原土壤中交换性盐基含量一致。在pH≥ 3.5的酸雨作用下 ,土壤中铝的淋失较少 ,而当酸雨pH =2 .0时 ,铝的淋失骤然升高。pH2 .0的模拟酸雨不仅增加了土壤铝离子的释放 ,而且加速了矿物的风化。在pH2 .0的模拟酸雨淋溶下 ,红壤、黄壤、山地草甸土和紫色土中由矿物风化输入的 5种阳离子总量分别为 2 .94、4 .33、4 .35和 6 .0 4 (cmol kg)土 ,显著大于其它酸雨处理。土壤对酸沉降的缓冲作用由阳离子交换、氢氧化铝水解以及原生矿物风化缓冲作用三部分组成 ,其相对重要性不仅决定于土壤酸度、盐基饱和度和矿物组成 ,而且与酸雨的pH值密切相关     

青海省盐湖钾、镁、锂盐资源开发利用探讨

论述了青海省盐湖资源中钾、镁、锂盐工业的资源状况、生产现状以及开发利用的迫切性 ,并对钾、镁、锂盐资源的综合利用进行了探讨