柴达木盆地西部第三系咸水湖相原油地球化学特征

在系统分析柴达木盆地西部各油田40余个原油样品碳同位素和饱和烃、芳烃组成的基础上,全面剖析了该地区第三系湖相原油的地球化学特征.研究结果表明,这些原油具有特殊的碳同位素组成和异常的生物标志物分布.其全油碳同位素偏重(-26‰～-24‰);正构烷烃系列单体烃碳同位素分布曲线呈水平状,表现出类同于海相有机质的碳同位素组成特征.它们的生物标志物中正烷烃系列兼具奇碳和偶碳优势双重碳数分布模式;呈强植烷优势,Pr/Ph值大多<0.6;伽玛蜡烷普遍异常丰富,C35藿烷含量高,表征高盐、厌氧的咸水湖相沉积环境性质.芳烃组份以萘、菲系列为主,而二苯并噻吩等含硫有机化合物相对含量较低,反映该地区咸水湖相原油源岩沉积相的特殊性.柴西各油田原油地球化学参数在区域上呈规律性变化趋势,与其源岩沉积相的时空变迁相一致.     

扎仓茶卡低品位固体硼矿矿物学与地球化学特征及可选性研究

西藏自治区扎仓茶卡盐湖是我国重要的超大型固体硼镁矿产地,经多年开采,高品位硼矿资源(B_2O_3≥28%)已采掘殆尽,但矿区内仍堆有大量低品位矿石,这不仅是对环境的威胁,也是对资源的浪费。在采集样品的基础上,开展了基于X射线衍射与扫描电镜的矿物组成的鉴定和化学组分分析,为低品位矿石的综合利用提供理论依据。研究结果表明,扎仓茶卡盐湖低品位硼矿的矿物种类有库水硼镁石、柱硼镁石、石英、钠长石、微斜长石、方解石、白云母、文石、水菱镁矿、石膏和锰热臭石共11种,其中仅有库水硼镁石和柱硼镁石两种硼矿物,平均含量分别为21.14%与8.99%,且硼矿样品中B_2O_3平均含量高达13.50%,有巨大的经济利用价值。考虑到扎仓茶卡有着丰富的卤水资源,且低品位硼矿主要为库水硼镁石,可利用卤水及矿物的密度差来进行重选,该库水硼镁石为易选型。这种方法不仅能实现矿区内低品位矿的回收利用,而且生产成本低廉、绿色环保,将进一步促进区域经济发展。     

处置库污泥工程特性测试研究

对某填埋场污泥库中取样的污泥进行了岩土工程特性测试,包括有机质含量、含水率、界限含水率、颗粒级配、渗透系数、压缩固结特性及抗剪强度等。试验结果表明,与常规淤泥相比,污泥库中经一段时间降解后污泥有机质含量及含水率较高,平均值分别为45%和520%;污泥在历时2 a的生物降解作用下,污泥含水率、有机质含量沿深度呈较为明显的减少趋势;污泥具有极高的压缩性,压缩系数a100-200高达7 MPa-1;污泥的固结表现为非线性大变形特性,其固结系数在10-5～10-6 cm2/s,比淤泥低1～2个数量级,固结系数随压力的增加而显著减少;污泥的抗剪强度参数较小,其黏聚力为0,内摩擦角为14.7°。有机质含量高是污泥高含水率、高液塑性指数、高压缩性,低渗透性、低固结系数及低抗剪强度的本质原因。以上成果可为污泥库的固化处置、稳定分析等提供必要的参数。     

Impacts of domestic sewage effluent on phytoplankton from Bedford Basin, eastern Canada

The impact of domestic sewage effluent (SE) on the dynamics of phytoplankton assemblages from Bedford Basin was evaluated in the laboratory. Phytoplankton production and chlorophyll a increased proportionally with SE enrichment. Phytoplankton species composition also changed. The potentially harmful diatoms, Pseudonitzschia spp., present initially in small numbers (600 cells 1⁻¹) in Bedford Basin seawater, and became dominant (3–5×10⁶ cells 1⁻¹) when the seawater was enriched with 0.5–5% untreated SE. With higher proportions of SE, other harmful species such as Fragilaria spp. and Euglena spp. became dominant (7−15×10⁶ and 2.2×10⁴ cells 1⁻¹, respectively). Treatment of SE with UV light or activated charcoal seems to favour growth of benign species, such as Chaetoceros socialis, Skeletonema costatum and Thalassiosira spp., but not harmful species such as Pseudonitzschia spp. Further research on UV treatment of domestic sewage is recommended.     

工业废水和城市综合污水的环境风险管理

综述了国内外工业废水与城市综合废水的监控和环境风险管理进展。与发达国家比较,化学监测法是目前我国工业废水和城市综合污水监控的唯一手段,而且主要有赖于COD等极少参数,并不能有效监控复合有毒有机污染物的排放。采用生态毒性检测法,可弥补这一缺陷,满足环境风险管理要求。毒性鉴别评价鉴别出导致废水/污水生态毒性的关键有机毒物,是降低其环境风险的核心。还对生态毒性检测法应用于我国废水/污水排放的监控和环境风险管理前景做了评述。     

基于MapObjects的城市污水管网信息系统

以地理信息系统为技术支持,结合在线监测技术,在VB环境下利用MapObjects控件进行二次开发建立了污水管网信息系统。该系统能对污染源排污状况及污水管网运行状况进行实时监控,是城市污水管网运行管理强有力的工具。     

中山市河涌水体及污水处理厂中 合成麝香的分布规律

对中山市5个区域的48条主要河涌水体与2间污水处理厂各工艺流程水体进行样品采集,运用固相微萃取进行前处理并结合气相色谱—质谱联用技术,检测各样品中佳乐麝香、吐纳麝香和酮麝香这3种合成麝香的含量,并分析其分布特征以及探讨污水处理厂处理工艺中合成麝香的浓度变化规律。结果表明：1）合成麝香已经普遍存在于中山市的河涌水体中。中山市西部地区和南部地区的河涌水体中合成麝香总含量相对其他区域最低,中部地区河涌水体中合成麝香含量亦较低。2）中山市雁企涌和魁魁涌等28条河涌水体中的主要合成麝香为佳乐麝香,一埒涌和乌沙涌等13条河涌水体的主要合成麝香为酮麝香,仅有苏埒涌和石军涌等7条河涌水体的主要合成麝香为佳乐麝香和酮麝香这2种合成麝香。3）氧化沟和A2/O工艺均能对合成麝香产生一定的去除效果。污水处理厂A对佳乐麝香、吐纳麝香和酮麝香的去除率分别为86.94%、72.15%和89.36%;而污水处理厂B对以上3种合成麝香的去除率分别为82.09%、85.73%和87.90%。4）2间污水处理厂的二沉池以及污水处理厂A的紫外消毒亦可对合成麝香产生进一步的去除效果;2间污水处理厂均能对酮麝香产生比佳乐麝香和吐纳麝香更高的去除率。     

柴达木盐湖化工科学研究联合基金实施概况

对2014~2017年国家自然科学基金委员会—青海省人民政府柴达木盐湖化工科学研究联合基金申报与资助项目进行分析,重点研究联合基金实施概况,指出实施成效及存在的问题,并提出解决相关问题的发展建议,通过对联合基金资助和实施结果进行探讨,不断总结经验,优化模式,更好地为柴达木盐湖化工科学研究联合基金创新发展提供制度保障和参考依据。     

The effectiveness of artificial recharge in combating seawater intrusion in Salalah coastal aquifer, Oman

The Salalah central sewage treatment plant has been designed to treat 20,000 m³/day at the first stage and two further stages to double the initial capacity. The plant currently (2005) treats more than 15,000 m³/day effluents to a tertiary level, and after chlorination phase, the effluents are recharged into tube wells in a line parallel to the coast. The process aims to help stabilize the seawater interface and a part to be recovered from hand-dug wells/boreholes further inland and downstream. A three-dimensional flow and solute advection transport model was developed to assess the effectiveness of the proposed recharge scheme and to track the solute transport with respect to the design system. The advection transport model predicted that in 2020 the maximum pathlines of the injection fluids would reach the abstraction wells that are located 600 m, southward of the injection bores in about 1-year travel time in the case of the no-management interference and more than that southward under management interference. The developed flow predicted the wedge of the saline intrusion in 2019 is tracked up to 2.7 and 3.4 km from the shoreline with the injection and without the injection, respectively under constant underflow. The injection scheme is effective in pushing back the saline zone front by 700 m. This study argues that the treated wastewater would help to increase the water levels at the vicinity of the injection line and to reduce the influence of saline inflows from the coast. The reclaimed sewage recharge scheme is examined in the case of the Salalah coastal aquifer using groundwater simulation, which can also be applied to other regions with similar conditions.     

Regional search, selection and geological characterization of a large anticlinal structure, as a candidate site for CO2-storage in northern Germany

This paper reports on the regional screening, selection and geological characterisation of a potential on-shore CO₂ storage site (saline aquifer) in north-eastern Germany. The main objective of this study was to identify and investigate a candidate storage site, capable to accommodate the total amount of approximately 400 million tons of CO₂. Such a volume is produced by a modern, lignite-fired power plant within its operation lifetime of approximately 40 years. Within north-eastern Germany, several saline aquifers of Triassic, Jurassic and Cretaceous age have been evaluated with respect to their regional occurrence, storage potential and basic reservoir properties. Subsequent to a ranking, considering different criteria, the anticlinal structure Schweinrich holding suitable saline aquifers of the uppermost Triassic and lowest Jurassic has been selected from a number of identified candidate sites. According to results of the geological site characterisation, including structural geological investigations and 3D reservoir modelling, the structure Schweinrich seems to be a suitable site for industrial large scale CO₂ storage. Further data acquisition (new wells and 3D seismics) and research (more detailed and comprehensive modelling) is needed in order to prove the structural integrity of the storage site and assure long-term safety.