凹凸棒石粘土处理城市废水的实验

目前的城市废水处理方法有活性污泥法及粉末活性炭投料－活性污泥性,但两者皆存在不足之处。凹凸棒石具独特的结构和良好的吸附、脱色、净化和过滤性能。通过实验对其用于城市废水处理作了技术可行性研究,并进行了相应的经济可行性分析,认为凹凸棒石粘土可替代粉末活性炭处理城市废水且成本很低。     

快速堆肥对污泥中重金属的影响

对上海曲阳污水厂污泥及其快速堆肥产物中的Zn．Cu，Ni．Cd，Pb，Cr等六种重金属进行了含量及化学形态分析。分析结果表明堆肥过程不会改变污泥中各重金属元素的含量．堆肥前后重金属主要以稳定的形态存在，但堆肥过程进一步提高了重金属元素稳定形态的比例。变化最为显著的是污泥中含量较高的Zn，其不稳定形态的比例由37％降为16％．使得Zn的活性与毒性大大降低。经过快速堆肥．考察的六种重金属元素的稳定性得到了提高，减小了污泥土地利用时重金属的环境危害。     

巴丹吉林沙漠盐湖面积变化对湖泊边缘表层沉积物盐类矿物组合影响

选择巴丹吉林沙漠17个代表性盐湖,采集了2013年春季和秋季湖泊边缘表层沉积物样品,通过X衍射分析其盐类矿物组成和百分含量;应用Landsat 8遥感数据提取了上述两时段湖泊面积。结果发现,自春季到秋季13个面积减小的湖泊中,碳酸盐类矿物百分含量均较低,变化不明显;氯化物矿物和总盐类矿物百分含量均有增加,其增加幅度与湖泊面积变化有关。面积减少超过10%的湖泊,氯化物矿物或硫酸盐矿物百分含量总体明显增加;其余面积减少的湖泊,氯化物矿物百分含量均较春季有一定的增加,盐类矿物总百分含量也有一定程度的增加,但与湖泊面积减小程度相比没有更为明显的规律。4个面积增大的湖泊中沉积物的总盐类矿物百分含量和各盐类矿物的百分含量并未呈现显著相关性,表明在该区域湖泊面积的变化过程中,湖泊边缘表层沉积物中的盐类矿物百分含量对盐湖萎缩的指示意义相对高于湖泊扩张时期,氯化物矿物百分含量变化对湖泊面积萎缩变化响应更为敏感。     

海岸动力环境下射流运动研究综述

开展海岸动力环境下射流运动规律和扩散机理研究,对于丰富复杂动力条件下的射流基本理论、指导沿海地区污水有序向海排放有着重要的理论和现实意义。系统回顾和总结了国内外在这一领域的研究内容和相关研究成果,评述了潮流(水流)、波浪和波流环境下射流运动规律的研究进展,指出了进一步开展波流相互作用下射流运动研究的可行性和必要性,并提出了利用物理实验和大涡数值模拟手段对波流共同作用下射流特性进行综合研究的思路和方法。     

河道污染治理技术-- 生物接触氧化填料研究

选择不同填料对生物接触氧化法处理生活污水进行了进一步的研究与应用,探讨了温度、接触氧化停留时间等因素对其处理效果的影响。实验研究结果表明,在水温为18℃~20℃,水力负荷为70m l/m in时,采用鹅卵石和沸石的复合填料挂膜,进行生物接触氧化法处理生活污水,在降解NH3-N和氨氮等方面取得良好效果,COD、NH3-N去除率都高达80%以上。     

Exploitation of gold in a historic sewage sludge stockpile, Werribee, Australia: resource evaluation, chemical extraction and subsequent utilisation of sludge

Sewage sludges are dewatered end products of human sewage waste and are recognised repositories of organic pollutants and heavy metals. They may be considered targets for economic extraction of Au because of the documented Au content of sewage sludges worldwide which are of the order of some ore deposits currently mined for Au. They are also highly nutrient enriched (nitrogen and phosphorus) and therefore amenable to use as agricultural fertiliser or as covers for mine wastes. The sewage of Melbourne, Australia, a city with a current population of 3.3 million, was stockpiled in large, closed, lagoonal tanks from 1898 until 1980. In 1995 Echidna Mining, an Australian gold exploration company, acquired the exploration rights to the ground surrounding the historic sludge reserves and commenced a program of resource evaluation, utilising RNAA, INAA, GFAAS, ICP–MS and FLAAS to determine 31 elements, including Au, Ag, Sb, As, Cd, Hg, Zn, Cu, and Pb. The study was initiated to determine Au, Ag and other metal variations in both space and time and to investigate the economics of chemical extraction of the precious metals. A total of 149 samples from over 50 hand-auger drillholes to a depth up to 4 m have been analysed from the stockpiles, with Au assays yielding remarkably consistent results. Average grades of 0.77 g/t Au and 18.8 g/t Ag have been documented for a measured resource of 770,000 m³ (of an estimated 1.6–2.5 million m³ contained) at a density of 1.0 g/cm³ and an average moisture content of around 40%. Laboratory-based extractive metallurgy of the Werribee sludges has demonstrated that Au, Ag and Zn can be removed with relative ease by heap-leaching using modified conventional technology, albeit with prohibitive reagent consumption. The extraction of the precious metals also results in the variable removal of contaminant metals such as Cd, As, Sb, Hg and Cr which may render the sludges fit for sale as agricultural fertiliser, provided organic pollutants and pathogenic organisms are below governmental environmental protection limits, an area beyond the scope of this paper. Another potential avenue of the exploitation of sewage sludges is discussed: that of the utilisation of sludges to extract contaminant metals from waste water and contaminated mine waters, which we demonstrate on pure aqueous synthetic samples. This paper presents a study of the exploitation of an historic sludge resource for its contained Au and residue post-metal extraction.     

世界咸水湖的物理与化学特性

本文根据近年来有关咸水湖的研究文献,介绍了咸水湖的概念、地理分布和湖盆的成因。进而从咸水湖的光学特性和热学特性两个方面阐述了湖泊的物理特性;从湖水盐度、蒸发和盐度、盐分来源,湖水的化学成分和类型以及盐湖的演化等方面说明咸水湖的化学特点;最后,从盐类沉积和古气候古环境关系的角度出发,指出咸水湖的古湖沼学研究在过去全球变化历史的重建中具有巨大的潜力,是全球研究体系中不可缺少的部分。     

A groundwater quality survey of an unsewered,semi‐rural area

A baseline groundwater quality survey of 120 household wells in an unsewered area at Yaldhurst, near Christchurch, was carried out between September and December, 1976. Ammonia‐N levels were below the detection limit (0.02 g m^‐3) in all samples. Nitrate‐N, conductivity, and chloride levels tended to vary according to well depth and location, being lower in the deeper wells and in wells located in an area of shallow, stony soils. Approximately 33% of the wells contained coliform bacteria, faecal coliform bacteria or faecal streptococci. A subset of 25 wells was sampled fortnightly from January to August 1977. From January to June, mean nitrate‐N and conductivity levels remained stable at approximately 1.5 g m^‐3 and 11.2 mS m^‐1 respectively. An increase in these levels to 3.3 g m^‐3 and 15.8 mS m^‐1 in July‐August corresponded with a rise in the water table. Leaching losses from soils probably accounted for most of the nitrate entering the Yaldhurst aquifers, the contribution by septic tank systems being estimated at 20–30%. No direct evidence of contamination of the wells by septic tank effluent was found, although 23 of the 25 wells exhibited intermittent contamination by indicator bacteria throughout the 8 month sampling programme. Although a localised health hazard may exist, septic tank systems in the area were not considered likely to constitute a health threat to the confined aquifers underlying Christchurch city.     

天津入海排污口微塑料分布特征

近年来微塑料 （Microplastics,MPs） 污染受到全球关注。MPs 在海洋环境中广泛存在,在海水、沉积物和生物体中都有检出 MPs。陆源污染被认为是海洋 MPs 的主要来源,然而针对入海排污口中 MPs 分布的研究却很少。本文在天津海岸线的排污口采集微塑料样品,消解处理后用光学显微镜和显微红外光谱仪进行了检测。结果表明微塑料主要有纤维、碎片、薄膜三种形状,占比最多的是纤维状,占比为 75.6 %;粒径大小为 1 ~ 5 mm 占比较多,为 39.5 %;主要有黄色、白色、黑色、红色、蓝色、绿色 6 种颜色,其中黑色占比最多,占比为 33.0 %。MPs 主要成分有聚氯乙烯 （PVC）、聚酰胺 （PA）、聚对苯二甲酸乙二醇脂（PET）、纤维素塑料（CE）、丙烯腈-丁二烯-苯乙烯共聚合物（ABS）、环氧树脂（EP）、聚丙烯聚乙烯共混物（PP-PE）、聚甲基丙烯酸甲酯 （PMMA） 等 8 种组分。根据数据分析,天津入海排污口的 MPs 主要来源于居民污水、塑料包装业、服装纺织业、旅游业和渔业。研究结果对渤海 MPs 治理具有重要意义。