长江中下游抛刀岭大型中硫型浅成低温热液金矿床的厘定及其找矿启示

长江中下游是全球重要的斑岩-矽卡岩铜多金属矿床成矿带之一,近年来识别出一些大型明矾石矿床、中小规模高硫型和低硫型金±银矿床,但是否存在中硫型矿化蚀变系统还不清楚.抛刀岭是近年来在长江中下游成矿带新发现的大型独立金矿床,文章通过岩芯编录、短波红外光谱和矿物成分的研究,厘定该矿床矿体主要产于～140 Ma英安斑岩脉中,成矿...     

Geochemical and O-isotope constraints on the evolution of lithospheric mantle in the Ross Sea rift area (Antarctica)

Peridotite xenoliths found in Cenozoic alkali basalts of northern Victoria Land, Antarctica, vary from fertile spinel-lherzolite to harzburgite. They often contain glass-bearing pockets formed after primary pyroxenes and spinel. Few samples are composite and consist of depleted spinel lherzolite crosscut by amphibole veins and/or lherzolite in contact with poikilitic wehrlite. Peridotite xenoliths are characterized by negative Al₂O₃–Mg# and TiO₂–Mg# covariations of clino- and orthopyroxenes, low to intermediate HREE concentrations in clinopyroxene, negative Cr–Al trend in spinel, suggesting variable degrees of partial melting. Metasomatic overprint is evidenced by trace element enrichment in clinopyroxene and sporadic increase of Ti–Fe_tot. Preferential Nb, Zr, Sr enrichments in clinopyroxene associated with high Ti–Fe_tot contents constrain the metasomatic agent to be an alkaline basic melt. In composite xenoliths, clinopyroxene REE contents increase next to the veins suggesting metasomatic diffusion of incompatible element. Oxygen isotope data indicate disequilibrium conditions among clinopyroxene, olivine and orthopyroxene. The highest δ¹⁸O values are observed in minerals of the amphibole-bearing xenolith. The δ¹⁸O_cpx correlations with clinopyroxene modal abundance and geochemical parameters (e.g. Mg# and Cr#) suggest a possible influence of partial melting on oxygen isotope composition. Thermobarometric estimates define a geotherm of 80°C/GPa for the refractory lithosphere of NVL, in a pressure range between 1 and 2.5 GPa. Clinopyroxene microlites of melt pockets provide P–T data close to the anhydrous peridotite solidus and confirm that they originated from heating and decompression during transport in the host magma. All these geothermometric data constrain the mantle potential temperature to values of 1250–1350°C, consistent with the occurrence of mantle decompressional melting in a transtensive tectonic regime for the Ross Sea region.     

Tertiary Mafic Lavas of Turkana, Kenya: Constraints on East African Plume Structure and the Occurrence of High-{micro} Volcanism in Africa

The East African Rift System is important to understanding plume-initiatedrifting as manifest in the geochemistry of mafic lavas eruptedalong the rift throughout its evolution. We present new datafrom high-MgO Tertiary lavas from Turkana, northern Kenya, toinvestigate regional melt source components, to identify thedepths and degrees of melting, and to characterize spatiallyand temporally the chemical structure of the underlying mantle.The Turkana area is a region of high lithospheric extensionthat sits between two topographic uplifts thought to be surfaceexpressions of one or more upwelling mantle plumes. Thinningof local crust is believed to be accompanied by widespread removalof the mantle lithosphere, causing the asthenosphere to be inclose contact with the overlying crust. New geochemical dataon basanites, picrites and basalts (MgO >7 wt %) tightlyconstrain the primary melt source regions of Tertiary volcanism.Initial isotopic signatures (¹⁴³Nd/¹⁴⁴Nd = 0·51267–0·51283,⁸⁷Sr/⁸⁶Sr = 0·7031–0·7036) and trace elementabundances (Ce/Pb 30, La/Nb = 0·6–0·8 andBa/Nb = 3–10) in these lavas are consistent with derivationfrom sub-lithospheric sources. Basalts and picrites eruptedbetween 23 and 20 Ma have Sr–Nd–Pb–He isotopiccharacteristics indicative of high-µ influence, recordhigh depths and degrees of partial melting, and are associatedwith rift propagation to the north and south. Accordingly, theselavas sample a source region that is geochemically distinctfrom that reflected both in Oligocene Ethiopian flood basaltsand in the modern Afar region. The geochemical data supportnumerical and theoretical models as well as tomographic resultsproviding for a complex thermal structure in the mantle beneathEast Africa and are interpreted to reflect isotopically distinctplume heads beneath Tanzania and Afar that are derived fromthe chemically heterogeneous South African superplume. KEY WORDS: East African Rift System; mantle plumes; HIMU; geochemistry; Afar     

淮河流域5～6月降水的年际及年代际变化

对淮河流域降水异常进行分析对于预测黄海绿潮具有重要意义。选取淮河流域10个站,长江流域15个站,通过对国家气象信息中心1951~2011年的逐月降水数据进行分析,研究淮河流域和长江流域5~6月平均降水异常。2000~2010年,淮河流域5~6月降水呈现增加趋势,与长江流域降水呈反位相变化。分别对淮河流域5~6月平均降水异常与印度洋偶极子指数(Dipole Mode Index,DMI),以及太平洋年代际振荡(the Pacific Decadal Oscillation,PDO)指数做相关性分析,结果表明:淮河流域5~6月平均降水异常与6个月前的DMI指数达到最大正相关,与20个月前的北太平洋(20°N以北)SST呈现明显的负相关,与PDO指数达到最大负相关。这表明,PDO、DMI指数对淮河流域5~6月降水异常的年代际、年际变化具有明显的指示作用。     

2003年江淮流域强降水过程与30—70d天低频振荡的联系

利用NCEP／NCAR再分析和地面观测站的逐日降水资料,研究了2003年夏季江淮流域强降水过程与低频振荡的联系。结果显示,主周期为30～70d的低频振荡对2003年江淮流域暴雨的形成具有重要贡献：低频涡旋在江淮地区降水期的对流层高、低层呈负、正配置,具有斜压结构,利于降水发生;850hPa上正涡度系统的传播具有明显的北传和西传特征;存在于西太平洋、西北太平洋及其以东地区的低频波列（P—J）的活动过程影响了我国2003年江淮低频强降水的形成;整层低频水汽通量显示来自副热带高压外围的西南季风对水汽输送的贡献较显著,且2003年江淮地区30-70d时间尺度上降水的水汽来源为南海而非孟加拉湾或西太平洋。     

Limiting hydrochemical factors for sustainability of water resources: The Cisjordanian experience

In Cisjordan, surface- and groundwater flow are either towards the Jordan Valley-Dead Sea-Arava Valley (the Rift) or the Mediterranean Sea. Due to upstream exploitation by riparians to the Jordan River, the historical annual flow, which fluctuated between 250 and 1100 Mm³, has declined to a mere 100-200 Mm³. The remaining flow south of Lake Kinneret is highly polluted and heavily loaded with salts. Lake Kinneret (Sea of Galilee) is one of the major water resources in the area. Annually, between 200 and 700 Mm³ reach the Lake as surface and groundwater flow. The relatively high salinity of the Lake is caused by thermomineral water discharging from springs and seepages located onshore and on the bottom of the Lake. The main factors causing deterioration of the groundwater quality in the Rift are of geogenic character. These are different types of brines, whose outflow and penetration into freshwater aquifers was triggered by overpumpage. Contemporary encroachment of seawater caused by intensive water exploitation in the Coastal Plain is manageable and reversible. However, due to lack of hydrogeological evidence, no such statement can be made about the circulation of seawater beneath the Coastal Plain and into the deep-seated Yarkon-Taninim aquifer or the upflow of brines in the Rift.The flow regimes of the different brine bodies could not be elucidated. Whether each such brine-body flows by its particular hydrological regime or whether the movement of the different bodies is intradependent or interdependent with the regional movement of fresh groundwater, remain open questions. Therefore, sustainable development of groundwater resources is clearly dependent on the elucidation of the relationship between changes in the pressure of the brine with depth and its relationship to the overlying freshwater.The average total annual recharge of all water sources in Cisjordan is 1820 Mm³, which means that the total production of water must be managed within the limits of this annual volume. During drought years, total groundwater extraction exceeds the safe yield, causing drastic lowering of water levels and upflow of saline waters from greater depths.Because of the structural complexity of aquifers and hydrochemical variability of the numerous groundwater bodies, new hydrochemical methods have been developed for the identification of groundwater bodies and for the elucidation of their origins. These methods combine macrochemical, microchemical, and isotopic evidences. By combining distribution patterns of rare earths, yttrium and stable isotopes, a complete picture of catchment lithology and the altitude and latitude of precipitation could be obtained.The area west of the Jordan River is characterized by the occurrence of transboundary surface- and groundwater basins in which fresh and saline water and brines flow across political borders between Israel and the Palestinian Authority. It is very difficult to assess separately the annual safe yield of water resources for each of the two national entities. Neither country may dispose independently of its waters and is usually at the mercy of the other riparian. There is as yet no general multilateral international treaty in force allocating the water resources of international watercourses. At present there are two rules for the management of the waters of an international drainage basin—the rule of Equitable Distribution, and the obligation Not to Cause Significant Harm. The rules of equitable distribution have tended to focus on the issue of quantities of water rather than on quality of water, which is really relevant to the issue of equitable distribution. Future negotiations on the uses of the basin will need to deal with issues of characteristic salinities and geochemical features and on their impact on equitable sharing of water resources.     

Comparison of Fry strain ellipse and AMS ellipsoid trends to tectonic fabric trends in very low-strain sandstone of the Appalachian fold–thrust belt

In moderately to highly strained sandstones, both the long axis of the bedding-parallel finite-strain ellipse, as calculated by the normalized Fry method, and the projection of the long axis of the AMS ellipsoid on the plane of bedding, align well with local “structural grain” (trends of cleavage, folds, and faults). This relationship implies that results of both 2D Fry and AMS analyses represent the local layer-parallel tectonic strain component. Do both methods provide comparable results for very low-strain sandstone (e.g., <5%)? To address this question, Fry and AMS analyses were conducted in very low-strain sandstone from two localities in the Appalachian foreland fold–thrust belt: near Rosendale in New York and the Lackawanna synclinorium of Pennsylvania. We compared the map projections of both bedding-parallel Fry ellipses and AMS ellipsoids to the local structural grain. In both study areas, projections of the long axis of Fry strain ellipses do not cluster in a direction parallel to structural grain, whereas the projection of the long axes of AMS ellipsoids do cluster closely to structural grain. This observation implies that in very low-strain sandstone, AMS analysis provides a more sensitive “quick” indicator of tectonic fabric than does normalized Fry analysis.     

Using a fluvial archive to place extreme flood sediment (dis)connectivity dynamics in context of a longer-term record

The aim of this study was to establish the source and provenance of sediments deposited in a large floodplain sink during extreme floods in the Lockyer Creek catchment, Australia, in 2011 and 2013. We place the sediment source patterns in context of the longer-term record to determine whether coarse-grained sediment sources (i.e., very fine sand to very coarse sand) and the spatio-temporal pattern of (dis)connectivity have changed over time. We do this by matching the geochemical properties and age structure of a sediment profile located in a downstream floodplain sink to the elemental composition of source sediments. One hundred and fifty-seven sediment samples from 20 sites across the catchment are analysed using X-ray fluorescence (XRF) spectrometry to compare the elemental ratio composition of the downstream floodplain sink to its source materials. We use Optically Stimulated Luminescence (OSL) dating to determine the age structure of the sediments in the floodplain sink. The northern tributaries and parts of the Lockyer River trunk stream are the primary sources of coarse sediment. These areas are connected (coupled) to the lower trunk stream and floodplain sediment sink. Southern tributaries are largely disconnected (decoupled) and supply little sediment to the floodplain sediment sink. This pattern of sediment source contribution has remained similar over the last 6.8 ka at least. Sediment sources as observed in the 2011 flood have predominated over the mid-late Holocene whilst those in the 2013 flood are rare.     

Lithologic Hydrocarbon Deposits in Rift Lake Basins in Eastern China

The rift lake basins in the eastern China have abundant hydrocarbon resources of lithologic deposits, which resulted from excellent source rocks and multi-type sandbodies developed during strong rifting. Vertically, the lithologic deposits are mainly distributed in the lowstand, lacustrine invasion and early highstand systems of third-order sequence corresponding to a secondary tectonic episode of strong rifting, and laterally they are closely related to various fans and turbidite sandbodies controlled by syn-sedimentary faults. A variety of lithologic traps have been developed in the rift lake basins, and they generally have favorable conditions of source-reservoir-seal assemblage and hydrocarbon accumulation dynamics, indicating that there is a great exploration potential of lithologic deposits in the rift lake basins. In order to obtain satisfactory effects of lithologic deposit exploration, it is required to combine new theories with advanced technical methods.     

Sedimentary and drainage evolution of the Condamine Valley Transition Zone (eastern Australia)

The basal succession of the Condamine Valley, which overlays the boundary between the Surat and Clarence-Moreton basins (eastern Australia), contains a clay-rich horizon ‘the Transition Zone’ that marks a pronounced unconformity between the Jurassic Walloon Coal Measures and the Quaternary Condamine Alluvium. This paper provides insights into the tectonic and drainage evolution of the Condamine Valley through integrated analysis of U–Pb ages of detrital zircon from three samples (494 concordant analyses), stable oxygen isotope analysis on eight authigenic clay samples, X-ray fluorescence of primary and trace elements, and hyperspectral mineral analysis from two drill cores (Lone Pine 17 and Daandine 164). The Transition Zone is interpreted to consist of both weathered Jurassic sediments and Cenozoic clay deposits. Two sequential cycles of erosion, deposition and pedogenesis, related to geomorphological and climatic conditions are recognised. Distinctive oxygen isotope signatures of the two weathering fronts demonstrated an initial Early Cretaceous phase (δ¹⁸O?=?11.9–15.7‰ VSMOW) associated with laterisation and possible uplift, followed by Paleogene (δ¹⁸O?=?16.4–17.3‰ VSMOW) silcretisation of reworked Jurassic sediments. Detrital zircon geochronology yielded Jurassic maximum constraints for the age of deposition of three samples that are indistinguishable within error, the oldest of which (163?±?8?Ma from the lateritic profile) corresponds to the age of the underlying Walloon Coal Measures. The two overlaying samples from a silcrete profile and granular alluvium yielded overlapping yet younger ages of 150?±?6?Ma and 156?±?9?Ma, respectively. Vitrinite reflectance used as a proxy for the thermal condition of the coal strata enabled an estimated 2–3?km of burial and subsequent (likely Early Cretaceous) uplift. Geochemical insights from the Condamine Valley correspond to broad-scale climatic and tectonic conditions, suggesting that ‘transition zone equivalents’ and corresponding groundwater dynamics may occur in similar sedimentary settings throughout eastern Australia.