Implications of Analcime Hydrothermally Formed from Na-alumino-borosilicate Glasses Containing Cs and Sr for the Stability of High-level Radioactive Waste Form

Abstract. In order to know the behaviors of radioactive elements such as cesium and strontium during a hydrothermal alteration of borosilicate glass of radioactive waste, some alumino-borosilicate glasses belonging to the systems Na₂O-Al₂O₃-B₂O₃-SiO₂-SrO, Na₂O-Al₂O₃-B₂O₃-SiO₂-Cs₂O and Na₂O-Al₂-O₃-B₂O₃-SiO₂-SrO-Cs₂O have been treated hydrothermally at 200C under a vapor pressure of 1.54 MPa. The result shows that all glasses are changed into crystalline phases with running time up to 60 days, and that analcime-type zeolite is formed as a major product. The formed zeolite is shown to contain cesium and/or strontium. Considering the fact that natural zeolite occurs in wide physicochemical conditions including hydrothermal one, the analcime-type zeolite is expected to fix stably the radioactive elements in the disposal site. Since aluminum is necessary for the formation of the analcime-type zeolite, the waste glass should have aluminum as one of major components.     

灰色预测模型在径流长期预报中的应用

基于灰色系统的建模理论，利用河西地区有关河流的径流观测资料，建立了一个ＧＭ（１，１）残差序列周期修正径流预测模型，并用于春旱缺水期３～６月河流来水量的长期预报，经生产部门验证，准确率在８０％以上     

斜向坡变形破坏机制的数值模拟研究

本文讨论了斜向坡的旋转式变形和破坏机制，用有限元法计算了此种斜坡中的剩余下滑力的分布方式，并以此来解释在滑动过程中发生一定旋转的原因；论文还运用离散元法，模拟了此种滑坡的滑动过程。     

Seepage driving effect on deformations of San Fernando dams

In the process of flow deformation of an earth dam, the seepage force inside the dam plays a role as a driving force. The seepage force acts just like the gravitational force in terms of pushing soils away from their original locations after liquefaction is triggered. This paper draws attention to this seepage driving effect by presenting a set of fully coupled finite element analyses on the well-known San Fernando dams, with the objective of evaluating the impact of this seepage effect. The results indicate that while this effect is always there, its practical significance depends on a number of factors. In the case of the upper San Fernando dam, which experienced a significant, but restricted, downstream movement during the 1971 earthquake, the seepage driving effect was indeed significant. On the contrary, for the lower dam, which failed and slid into the upstream reservoir during the same earthquake, this seepage effect was relatively less pronounced. The detailed results of the analyses reveal the likely mechanisms of failure and deformation of the two dams and the likely cause behind the difference between their responses during the earthquake.     

Strain accumulation in sand due to cyclic loading: drained triaxial tests

Our aim is the prediction of the accumulation of strain and/or stress under cyclic loading with many (thousands to millions) cycles and relatively small amplitudes. A high-cycle constitutive model is used for this purpose. Its formulas are based on numerous cyclic tests. This paper describes drained tests with triaxial compression and uniaxial stress cycles. The influence of the strain amplitude, the average stress, the density, the cyclic preloading history and the grain size distribution on the direction and the intensity of strain accumulation is discussed.     

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.     

Modelling load–displacement response of driven piles in cohesionless soils under tensile loading

A new methodology for deriving the uplift load–displacement response of long driven piles in cohesionless soils is proposed. This method accounts for the effects of the friction fatigue processes during pile driving and the existence of locked-in residual stresses at the end of pile driving before commencing the pile load test. A hyperbolic formulation is utilized to simulate the nonlinear load transfer curves (the so-called t–z curves). The utility of this technique is demonstrated for a field pullout load test on a driven pile in sand. Predicted and measured load–displacement curves showed good agreement, indicating that this approach yields reasonable results as long as representative input parameters are employed.     

Evidence for a shock-metamorphic breccia within a buried impact crater,Lake Raeside,Yilgarn Craton,Western Australia

Mineral exploration drilling 60 km west of Leonora in 2008 intersected >95 m of poorly consolidated granitoid-dominated breccia at the base of a Cenozoic paleochannel beneath Lake Raeside. The breccia, initially interpreted as a kimberlite, is composed of poorly consolidated fragments of granitic gneiss, felsite and metamorphosed mafic rock within a matrix of fine to medium-grained breccia. Microscopic examination revealed quartz grains displaying well-developed planar deformation features (PDFs) dominated by the ω? {1013} planar set, diaplectic silica glass and diaplectic plagioclase glass. These features constitute the diagnostic hallmarks of shock metamorphism owing to high-velocity impact of a large meteorite or asteroid. The PDFs in quartz grains of the breccia are distinctly different from metamorphic deformation lamellae produced tectonically or in diatremes. Airborne total magnetic intensity data suggest an outline of an 11 km-diameter crater, consistent with the significant thickness of the shock-metamorphosed breccia at >95 m, suggestive of the existence of a large impact structure.     

用卫星热红外信息研究关联断层活动的时空变化--以南北地震构造带为例

断层活动不是孤立的,一条断层的活动可能影响其他断层,并引起这些断层的活动,这些相互作用的断层称为关联断层.本文利用卫星热红外信息以南北地震构造带为例,分析了关联断层活动的时空变化,所使用的信息是经过处理的地表亮温残差低频分量TLOW.结果表明,在一定时段内研究区一些断层间除地震活动表现出相互呼应关系外,其地表亮温残差低频分量TLOW曲线相似,相关系数高,说明热红外信息与地震信息共同反映一个地区断层的关联活动.此外,也存在单独由地表亮温残差低频分量TLOW相关表现断层关联活动的情形,即断层间无地震活动的呼应关系,但也存在TLOW曲线的相关性,同样显示关联断层的相互作用.对TLOW的时空过程分析表明,关联活动组合可随时间发生变化.例如,1988～1994年间红河断裂与澜沧-耿马断裂、金沙江断裂等构成关联活动组合,1994～1998年又与小金河断裂、安宁河-小江断裂构成关联活动组合,这样的时空变化过程可能是地壳应力场重新分配的反映.本文的研究结果证明,卫星热红外信息有望成为研究断层相互作用的一个新的独立物理量,并将对地震动力学和构造物理学的发展有重要意义.